%chk=LO-int3b-trans-trans.chk
%nprocshared=8
%mem=22GB
#p opt freq=noraman b97d3/gen pseudo=read nosymm

LO-int3b-trans-trans

-1 1
 Al                -4.30543500    7.91467300   -0.56712000
 N                 -6.10692700    8.91556300   -0.14344300
 O                 -3.36120400    9.37476600   -0.10443600
 O                 -4.45145600    6.77815900    0.81075200
 O                 -2.28783000    7.36372200   -1.48772900
 O                 -4.92083500    7.36349200   -2.15559600
 C                 -3.70236800   10.61563100    0.27276000
 C                 -2.74929600   11.39829400    0.96979900
 C                 -3.06661400   12.72374300    1.27078000
 C                 -4.30627600   13.29925900    0.94463700
 C                 -5.25788600   12.48535000    0.32319400
 C                 -4.97353700   11.15561700   -0.01827800
 H                 -2.31396900   13.33244100    1.77160000
 H                 -6.24472700   12.88869600    0.09057000
 C                 -6.00823600    7.67031200   -2.87535300
 C                 -7.19244900    8.13510300   -2.26708800
 C                 -8.29196900    8.48553500   -3.06290400
 C                 -8.25658500    8.35850100   -4.45453800
 C                 -7.07600000    7.86452800   -5.03758400
 C                 -5.95419800    7.51535600   -4.28252200
 C                 -6.28983600    8.95642200    1.34579200
 H                 -9.19581200    8.85728100   -2.57751300
 H                 -7.02699000    7.75248700   -6.12202200
 C                 -5.42734000    6.60087800    1.72189700
 C                 -6.39456600    7.59749200    1.98423300
 C                 -7.41737800    7.34803000    2.91166100
 C                 -7.49161700    6.14573000    3.61748100
 C                 -6.50035800    5.18242700    3.36560500
 C                 -5.47504000    5.37696200    2.43707600
 C                 -6.01176900   10.30755200   -0.70207800
 H                 -8.16183100    8.12550200    3.09094800
 H                 -6.52938700    4.23663100    3.90892400
 C                 -7.26763000    8.19930200   -0.76785200
 H                 -7.27338400    7.19161400   -0.33371200
 H                 -8.19709100    8.69833700   -0.45069300
 H                 -6.99995300   10.78677700   -0.62242700
 H                 -5.42915300    9.50094000    1.74896600
 H                 -7.18787700    9.55252400    1.57190300
 H                 -5.79849000   10.19400900   -1.77340200
 C                 -1.68388600    8.51525600   -1.91891100
 O                 -0.63712000    8.95617600   -1.52362200
 Al                 1.24293200    4.09199400   -0.15306800
 N                  2.45385400    3.31543200    1.56236200
 O                  0.19977400    4.88637800    1.15708700
 O                  2.74747900    5.03506300   -0.62869500
 O                  0.20405000    4.53773000   -1.57846300
 O                  1.04240900    2.31672500   -0.59271400
 C                  0.04952300    4.81823200    2.47943800
 C                 -0.72393200    5.80956400    3.14828800
 C                 -0.90603800    5.71424300    4.53062800
 C                 -0.33231700    4.69284700    5.30377200
 C                  0.46975500    3.76032000    4.64006100
 C                  0.66445100    3.80465600    3.25382900
 H                 -1.51027900    6.47748800    5.02477500
 H                  0.96135700    2.97054500    5.21148300
 C                  1.53563800    1.13907600   -0.23907900
 C                  2.65648900    1.00340400    0.61250500
 C                  3.10785600   -0.27114600    0.97969000
 C                  2.49570300   -1.43582700    0.50654900
 C                  1.38918800   -1.28684600   -0.34889800
 C                  0.89816100   -0.03642600   -0.72563500
 C                  3.26114400    4.42648000    2.14680000
 H                  3.96542800   -0.34897700    1.65127500
 H                  0.88809600   -2.17974900   -0.72934900
 C                  3.96024200    5.25766900   -0.13304600
 C                  4.30653600    4.96129400    1.20707900
 C                  5.61252200    5.19208700    1.65960500
 C                  6.59904800    5.73260600    0.82951900
 C                  6.23999200    6.02688700   -0.49737100
 C                  4.95529800    5.80007800   -0.99295200
 C                  1.52035400    2.76268000    2.58813200
 H                  5.85814900    4.94201900    2.69369900
 H                  6.99253600    6.44125000   -1.17183800
 C                  3.37136200    2.23569900    1.09009300
 H                  3.97326900    2.67036300    0.28312500
 H                  4.06706200    1.97468100    1.90658300
 H                  2.10630000    2.22244900    3.35157900
 H                  2.55486400    5.21613400    2.42534000
 H                  3.73811000    4.07356800    3.07760800
 H                  0.90061000    2.01832700    2.07532900
 C                 -1.38379300    6.15543500   -1.08728400
 C                 -0.38590800    5.64344000   -2.17858300
 C                 -2.38899800    5.06717000   -0.75116200
 C                 -1.18119200    5.16654900   -3.41794500
 H                 -0.45638100    4.80181400   -4.15817900
 H                 -1.71168800    6.02340900   -3.86047100
 C                 -2.18129500    4.06404800   -3.05708100
 H                 -1.80859800    4.25380100   -0.31478200
 C                 -3.16735500    4.57518000   -1.99177000
 H                 -3.07974600    5.41766200    0.01363900
 O                 -2.48744000    9.00905400   -2.88503500
 C                 -2.32867800   10.30912700   -3.55619600
 C                 -1.22219000   10.24672500   -4.63672400
 C                 -2.24463300   11.53547100   -2.64346200
 H                 -3.28492000   10.34382100   -4.08375000
 C                  0.14695000   10.68845800   -4.14388300
 C                 -0.83942600   11.95041700   -2.16788600
 H                 -2.91361200   11.38351900   -1.79447200
 H                 -2.67225700   12.35053300   -3.23904400
 C                  0.13223700   12.01056700   -3.36805400
 H                  0.83204200   10.74008500   -4.99876300
 H                  0.50297500    9.88771300   -3.48111300
 H                 -0.14930000   12.83003800   -4.04201600
 H                  1.14129300   12.22578600   -2.99670200
 C                 -4.43562100    4.31883600    2.18027600
 H                 -4.48324500    3.97926300    1.13936700
 H                 -3.42319600    4.70483100    2.34675100
 H                 -4.58750500    3.45659200    2.83917500
 C                 -8.58877500    5.88475600    4.62419500
 H                 -9.16856200    4.98732900    4.36522600
 H                 -8.17960000    5.72449400    5.63201900
 H                 -9.28641700    6.72919800    4.67816400
 C                 -9.44332500    8.73278500   -5.31333500
 H                 -9.17591900    9.49544200   -6.05844800
 H                 -9.83052700    7.86423700   -5.86521700
 H                -10.26327300    9.13295300   -4.70501200
 C                 -4.58980900   14.74987000    1.26017000
 H                 -4.36324500   14.98557500    2.30898400
 H                 -3.97760500   15.41996800    0.63906300
 H                 -5.64234400   14.99875300    1.07882900
 C                 -1.44000400   10.77741900    1.37241500
 H                 -1.60431700    9.99029400    2.11969500
 H                 -0.94997000   10.28978200    0.52502000
 H                 -0.76708500   11.52991100    1.79511700
 C                 -4.69643400    6.96920700   -4.90464400
 H                 -3.81609700    7.48300700   -4.50660600
 H                 -4.56874300    5.90747800   -4.65385300
 H                 -4.71925600    7.06692800   -5.99626500
 C                 -1.31239300    6.95998400    2.37542700
 H                 -0.55066500    7.45165900    1.75763100
 H                 -2.11472400    6.64200700    1.70256500
 H                 -1.73838500    7.70471900    3.05794000
 C                  4.58353900    6.10637500   -2.41991100
 H                  4.15665900    5.22137600   -2.90925700
 H                  3.80546700    6.87929300   -2.46517100
 H                  5.45531000    6.44824700   -2.99143200
 C                 -0.57990200    4.60787300    6.79254900
 H                 -0.50512500    5.59411600    7.27139400
 H                 -1.58512600    4.21749400    7.01457300
 H                  0.14494300    3.94246600    7.27839300
 C                 -0.29623400    0.12399200   -1.62778400
 H                 -1.10250300    0.66158100   -1.11291200
 H                 -0.04375600    0.73558900   -2.50353700
 H                 -0.67603300   -0.84908100   -1.96308000
 C                  3.00131300   -2.80817800    0.89054600
 H                  2.20004300   -3.43341600    1.31100400
 H                  3.40907800   -3.34937400    0.02308900
 H                  3.79891200   -2.74012600    1.64087700
 C                  7.99877000    6.00252100    1.33357000
 H                  8.75963400    5.56497400    0.67116000
 H                  8.20802000    7.08152200    1.39479700
 H                  8.14713900    5.58159500    2.33587000
 Cl                -1.80917000   11.59871800   -5.92022500
 C                 -1.20560800    8.95027700   -5.42308200
 H                 -0.88854200    8.12855400   -4.77273000
 H                 -2.19798900    8.71376200   -5.81663900
 H                 -0.49793500    9.02740500   -6.25418900
 H                 -2.73452700    3.73593300   -3.95005600
 C                  0.70922100    6.63167400   -2.61160200
 H                  1.45158400    6.04732700   -3.16448900
 H                  0.34181100    7.43311200   -3.26095700
 H                  1.20272100    7.07696300   -1.74451100
 H                 -0.83171500    6.49326800   -0.21445500
 H                 -1.61543300    3.20877600   -2.67125100
 H                 -4.08732781    5.08211542   -2.29839633
 C                 -0.50469638   12.41851108   -0.73944489
 C                  0.37027982   11.71578294   -0.00586789
 C                 -1.16744425   13.65788816   -0.19374847
 H                  0.83175099   10.80845574   -0.39184889
 H                  0.64464308   12.02106427    1.00341484
 H                 -2.24447785   13.48971220   -0.05424235
 H                 -0.74083405   13.93583358    0.77664921
 H                 -1.05716013   14.51127334   -0.87800696
 H                 -1.06369059   12.93665131   -2.51709552
 C                 -3.63635072    3.25489609   -1.35263512
 C                 -4.91064648    2.82765144   -1.52641480
 H                 -5.59780243    3.40534833   -2.10863727
 H                 -5.23071102    1.90947154   -1.07986765
 C                 -2.65391111    2.41724242   -0.51314197
 H                 -1.75513621    2.25650858   -1.07105622
 H                 -2.42330578    2.93914718    0.39203017
 H                 -3.10068752    1.47406558   -0.27711591
   
C,H,O,N 0
6-311G**
****
Al     0 
S   2   1.00
      0.9615000             -0.5021546        
      0.1819000              1.2342547        
S   1   1.00
      0.0657000              1.0000000        
P   2   1.00
      1.9280000             -0.0712584        
      0.2013000              1.0162966        
P   1   1.00
      0.0580000              1.0000000        
****
Cl     0 
S   2   1.00
      2.2310000             -0.4900589        
      0.4720000              1.2542684        
S   1   1.00
      0.1631000              1.0000000        
P   2   1.00
      6.2960000             -0.0635641        
      0.6333000              1.0141355        
P   1   1.00
      0.1819000              1.0000000        
****

AL     0
AL-ECP     2     10
d   potential
  5
1    304.7291926            -10.0000000        
2     61.5299768            -63.8079837        
2     13.9259006            -22.8972174        
2      4.1463626             -8.0063232        
2      1.3715443             -0.8829345        
s-d potential
  5
0    467.8437756              3.0000000        
1     79.3992216             50.9705682        
2     25.4035967            143.8716460        
2      6.9954696             48.0055753        
2      1.7860129             14.0114180        
p-d potential
  6
0    776.2717190              5.0000000        
1    118.4992254             93.0595424        
2     34.4107276            266.7686329        
2      8.7859563             70.0725805        
2      2.3406228             17.2290839        
2      0.7398386              0.7105331        
CL     0
CL-ECP     2     10
d   potential
  5
1     94.8130000            -10.0000000        
2    165.6440000             66.2729170        
2     30.8317000            -28.9685950        
2     10.5841000            -12.8663370        
2      3.7704000             -1.7102170        
s-d potential
  5
0    128.8391000              3.0000000        
1    120.3786000             12.8528510        
2     63.5622000            275.6723980        
2     18.0695000            115.6777120        
2      3.8142000             35.0606090        
p-d potential
  6
0    216.5263000              5.0000000        
1     46.5723000              7.4794860        
2    147.4685000            613.0320000        
2     48.9869000            280.8006850        
2     13.2096000            107.8788240        
2      3.1831000             15.3439560        


