%nprocshared=8
%mem=20GB
#p PBEPBE/gen scrf=(smd,solvent=thf) nosymm scf=xqc EmpiricalDispersion=GD3BJ Int=Grid=UltraFine

HE radical cation

1 2
 C                  0.71008400    1.17781500    1.45846400
 C                  1.18211300    2.15090400    0.58303500
 C                 -1.17886800    2.43300400   -0.29541600
 C                 -1.59491700    1.43611800    0.58239900
 C                  2.60152800    2.59274800    0.46574100
 C                 -2.06862100    3.19630100   -1.21776000
 C                  1.48393000    0.39930800    2.47548900
 H                  2.23076100   -0.24600400    1.98615200
 H                  2.03550600    1.07396600    3.14669600
 H                  0.81217200   -0.23057200    3.07782200
 C                 -2.97658700    0.89217600    0.76541300
 H                 -3.67935900    1.69715400    1.02973500
 H                 -3.34317500    0.44089400   -0.16931700
 H                 -2.99649400    0.12967200    1.55834800
 O                 -3.33043500    2.72747300   -1.26868100
 O                  3.44727400    1.93322900    1.28131900
 O                  2.94016600    3.47709500   -0.32217400
 O                 -1.65617400    4.16104600   -1.86328900
 C                  4.85973400    2.32032700    1.18874100
 H                  5.19227900    2.14698500    0.15183300
 H                  4.93247200    3.39970900    1.40019800
 C                 -4.24999500    3.45099400   -2.15430300
 H                 -4.30693300    4.49479100   -1.80350600
 H                 -3.82125600    3.44780400   -3.16975500
 C                  5.62609500    1.48185100    2.18863300
 H                  6.69342100    1.75338400    2.13830500
 H                  5.27614000    1.66311100    3.21796700
 H                  5.53665200    0.40625400    1.96493300
 C                 -5.58745000    2.74558100   -2.09008000
 H                 -5.99644100    2.75048800   -1.06667200
 H                 -6.30062200    3.27169600   -2.74581700
 H                 -5.50866700    1.70290600   -2.43872400
 C                  0.24947700    2.84167100   -0.34621700
 H                  0.32631200    3.94418800   -0.20854900
 H                  0.63049400    2.74840100   -1.38935200
 N                 -0.63337100    0.88093100    1.39668100
 H                 -0.95865000    0.15550000    2.04629800

-C -P -O -H -N 0
6-311++g(d,p)
****

