%nprocshared=12
%mem=22GB
#p scf=xqc b3lyp gen EmpiricalDispersion=GD3 scrf=(smd,solvent=dichloromethane)

geom3_sp

0 1
 C	-1.553067000	 2.749989000	-1.607269000
 C	-0.090114000	 2.990469000	-1.311899000
 C	 0.914706000	 2.169141000	-1.628737000
 C	 2.383276000	 2.422781000	-1.386909000
 C	 3.163014000	 2.237047000	-2.702654000
 H	 3.084000000	 1.203551000	-3.060538000
 H	 4.226073000	 2.465432000	-2.586665000
 H	 2.749245000	 2.896568000	-3.473997000
 H	 2.522288000	 3.453532000	-1.031740000
 C	 2.916103000	 1.494164000	-0.276462000
 C	 4.431847000	 1.576108000	-0.027804000
 O	 5.168297000	 0.791199000	-0.957829000
 C	 5.575570000	-0.496178000	-0.467710000
 C	 4.433844000	-1.428981000	-0.133924000
 C	 3.682904000	-2.031942000	-1.149446000
 C	 2.576582000	-2.835621000	-0.863685000
 C	 2.200481000	-3.041530000	 0.472460000
 C	 2.947959000	-2.450000000	 1.501194000
 C	 4.046396000	-1.654332000	 1.195778000
 H	 4.612499000	-1.195596000	 2.003334000
 H	 2.642439000	-2.618653000	 2.529492000
 O	 1.137773000	-3.796258000	 0.871157000
 C	 0.413754000	-4.524161000	-0.118633000
 H	-0.351958000	-5.082930000	 0.422843000
 H	 1.066828000	-5.226683000	-0.652912000
 H	-0.070280000	-3.856065000	-0.839616000
 H	 2.017497000	-3.285038000	-1.676201000
 H	 3.959635000	-1.865369000	-2.188374000
 H	 6.188614000	-0.908764000	-1.275686000
 H	 6.219871000	-0.365319000	 0.415040000
 H	 4.631256000	 1.255894000	 1.003063000
 H	 4.777394000	 2.612823000	-0.127113000
 H	 2.642451000	 0.460548000	-0.485340000
 O	 2.300746000	 1.898190000	 0.976207000
 C	 1.329297000	 1.114575000	 1.499302000
 O	 0.928087000	 0.091381000	 0.965746000
 C	 0.858762000	 1.689828000	 2.777431000
 C	-0.202933000	 1.263440000	 3.486698000
 C	-1.157345000	 0.152684000	 3.162077000
 H	-1.131388000	-0.573630000	 3.988276000
 H	-0.829052000	-0.368397000	 2.265846000
 C	-2.629232000	 0.628375000	 2.995052000
 C	-3.260989000	 1.027358000	 4.336712000
 H	-3.200368000	 0.207467000	 5.063253000
 H	-2.762969000	 1.901492000	 4.775248000
 H	-4.319709000	 1.284456000	 4.208125000
 H	-3.183124000	-0.234822000	 2.607387000
 C	-2.769350000	 1.773781000	 1.979042000
 H	-2.255573000	 2.661502000	 2.372392000
 H	-3.832245000	 2.038745000	 1.888217000
 C	-2.231288000	 1.505271000	 0.567841000
 H	-1.172667000	 1.235681000	 0.617918000
 C	-2.391484000	 2.754300000	-0.311682000
 H	-3.457830000	 2.845366000	-0.558473000
 H	-2.124813000	 3.645730000	 0.273170000
 O	-2.974063000	 0.430370000	-0.023653000
 Si	-2.541944000	-1.070118000	-0.626497000
 C	-2.290230000	-2.354652000	 0.738150000
 H	-3.019233000	-2.249505000	 1.549567000
 H	-1.284543000	-2.298103000	 1.169853000
 H	-2.405975000	-3.363961000	 0.322702000
 C	-0.972839000	-1.023023000	-1.667013000
 H	-1.063212000	-0.367381000	-2.539764000
 H	-0.122087000	-0.689807000	-1.064395000
 H	-0.746179000	-2.031629000	-2.035335000
 C	-4.053645000	-1.544187000	-1.697112000
 C	-4.308645000	-0.443056000	-2.746235000
 H	-5.178835000	-0.697390000	-3.370771000
 H	-4.509324000	 0.524680000	-2.272497000
 H	-3.451146000	-0.314541000	-3.419761000
 C	-5.299588000	-1.685464000	-0.799055000
 H	-5.516716000	-0.754024000	-0.262023000
 H	-5.176316000	-2.481244000	-0.052910000
 H	-6.186207000	-1.936497000	-1.401541000
 C	-3.795427000	-2.880489000	-2.422831000
 H	-3.611815000	-3.704191000	-1.720936000
 H	-2.933569000	-2.819467000	-3.099723000
 H	-4.668152000	-3.161925000	-3.031554000
 H	-0.416469000	 1.812276000	 4.404274000
 H	 1.435230000	 2.538861000	 3.134241000
 H	 0.690552000	 1.220244000	-2.115893000
 H	 0.135065000	 3.939797000	-0.817597000
 C	-2.073910000	 3.820218000	-2.584910000
 H	-2.004683000	 4.823112000	-2.142640000
 H	-1.492098000	 3.823190000	-3.514350000
 H	-3.125565000	 3.637704000	-2.839302000
 H	-1.662805000	 1.769408000	-2.085274000

-Si -O -C -H 0
cc-pVTZ
****

