%nprocshared=12
%mem=22GB
#p scf=xqc b3lyp gen EmpiricalDispersion=GD3 scrf=(smd,solvent=dichloromethane)

geom1_sp

0 1
 C	 1.463586000	 4.657334000	 1.570095000
 C	 1.957483000	 4.422401000	 0.352833000
 C	 1.465167000	 3.335420000	-0.569794000
 C	 1.091640000	 3.890282000	-1.955071000
 H	 0.263546000	 4.601736000	-1.863426000
 H	 1.929350000	 4.418108000	-2.425360000
 H	 0.774411000	 3.085030000	-2.627843000
 H	 0.563180000	 2.893764000	-0.132166000
 C	 2.469646000	 2.162311000	-0.684583000
 C	 3.872730000	 2.543269000	-1.153682000
 H	 4.426924000	 3.000138000	-0.320716000
 O	 4.616326000	 1.474205000	-1.726531000
 C	 5.189723000	 0.532195000	-0.823888000
 C	 4.332483000	-0.696734000	-0.582095000
 C	 4.535128000	-1.482654000	 0.562287000
 C	 3.749586000	-2.602407000	 0.813213000
 C	 2.722194000	-2.954185000	-0.076053000
 C	 2.526307000	-2.196076000	-1.235790000
 C	 3.337538000	-1.083897000	-1.480125000
 H	 3.167989000	-0.487818000	-2.371290000
 H	 1.731351000	-2.435432000	-1.931229000
 O	 1.960155000	-4.029779000	 0.284476000
 C	 0.789289000	-4.296532000	-0.483950000
 H	 0.271799000	-5.110913000	 0.028358000
 H	 1.040473000	-4.615618000	-1.504401000
 H	 0.135138000	-3.419062000	-0.532335000
 H	 3.886370000	-3.194846000	 1.713237000
 H	 5.301625000	-1.199700000	 1.281014000
 H	 5.430604000	 1.013349000	 0.135009000
 H	 6.142862000	 0.233438000	-1.282058000
 H	 3.790253000	 3.285934000	-1.952230000
 H	 2.055145000	 1.416056000	-1.365545000
 O	 2.622781000	 1.557493000	 0.625966000
 C	 1.695617000	 0.649567000	 1.006200000
 O	 0.781882000	 0.284795000	 0.280189000
 C	 1.935951000	 0.215853000	 2.396623000
 C	 1.359336000	-0.856331000	 2.969238000
 C	 0.400542000	-1.817239000	 2.330778000
 H	 0.638734000	-2.834844000	 2.669334000
 H	 0.530029000	-1.794044000	 1.250029000
 C	-1.085950000	-1.523208000	 2.671893000
 C	-1.408375000	-1.878827000	 4.128580000
 H	-1.285902000	-2.956149000	 4.305151000
 H	-2.443761000	-1.614526000	 4.376499000
 H	-0.751994000	-1.348713000	 4.829369000
 H	-1.258264000	-0.450831000	 2.535329000
 C	-2.002183000	-2.278085000	 1.692674000
 H	-1.626892000	-3.304083000	 1.572241000
 C	-2.141377000	-1.618294000	 0.311618000
 C	-2.849962000	-2.555664000	-0.675668000
 H	-2.409363000	-3.559974000	-0.606550000
 H	-3.893744000	-2.645064000	-0.346049000
 C	-2.809863000	-2.095641000	-2.149307000
 C	-1.457644000	-2.369316000	-2.762124000
 C	-0.633631000	-1.467596000	-3.302172000
 H	-0.876493000	-0.408259000	-3.325948000
 H	 0.314577000	-1.758276000	-3.749538000
 H	-1.164086000	-3.422288000	-2.765818000
 C	-3.902244000	-2.812025000	-2.965677000
 H	-4.896897000	-2.595913000	-2.556800000
 H	-3.886547000	-2.493245000	-4.014607000
 H	-3.759295000	-3.900633000	-2.942846000
 H	-3.007528000	-1.017877000	-2.181531000
 H	-1.153157000	-1.345273000	-0.078528000
 O	-2.945335000	-0.439981000	 0.458333000
 Si	-2.718114000	 1.192216000	 0.176053000
 C	-1.761006000	 1.537097000	-1.409387000
 H	-0.793712000	 1.027433000	-1.387040000
 H	-1.569996000	 2.613868000	-1.497753000
 H	-2.307657000	 1.221607000	-2.304733000
 C	-1.836412000	 2.042568000	 1.614035000
 H	-1.803033000	 3.127963000	 1.451277000
 H	-2.341223000	 1.864005000	 2.570911000
 H	-0.806493000	 1.684575000	 1.701436000
 C	-4.506619000	 1.856944000	 0.033114000
 C	-4.481229000	 3.367130000	-0.279865000
 H	-3.973790000	 3.580502000	-1.229570000
 H	-5.505692000	 3.761159000	-0.362180000
 H	-3.974941000	 3.942130000	 0.506229000
 C	-5.260278000	 1.624661000	 1.358371000
 H	-6.300275000	 1.977403000	 1.280032000
 H	-4.795638000	 2.164738000	 2.193217000
 H	-5.290054000	 0.560639000	 1.623208000
 C	-5.247494000	 1.118107000	-1.099606000
 H	-5.302894000	 0.040594000	-0.906258000
 H	-4.757396000	 1.259566000	-2.071551000
 H	-6.278073000	 1.492957000	-1.196739000
 H	-3.014372000	-2.357947000	 2.112092000
 H	 1.621924000	-1.053618000	 4.008268000
 H	 2.649395000	 0.816560000	 2.953515000
 H	 2.772445000	 5.042161000	-0.025932000
 H	 0.650339000	 4.058908000	 1.978765000
 H	 1.849752000	 5.453181000	 2.203553000

-Si -O -C -H 0
cc-pVTZ
****

