%nprocshared=12
%mem=22GB
#p scf=xqc b3lyp gen EmpiricalDispersion=GD3 scrf=(smd,solvent=dichloromethane)

geom1_sp

0 1
 C	-0.448978000	-1.689113000	 1.859830000
 C	-1.885314000	-1.623407000	 1.398329000
 C	-2.339245000	-1.911750000	 0.175077000
 C	-3.789427000	-1.885198000	-0.239683000
 C	-4.216493000	-3.244058000	-0.824565000
 H	-3.624145000	-3.491064000	-1.714878000
 H	-5.274859000	-3.238055000	-1.112820000
 H	-4.066713000	-4.042702000	-0.089952000
 H	-4.409098000	-1.664520000	 0.639643000
 C	-4.067292000	-0.787732000	-1.277242000
 H	-3.419321000	-0.891188000	-2.151259000
 H	-5.113006000	-0.820425000	-1.596787000
 O	-3.893193000	 0.521372000	-0.691437000
 C	-2.756757000	 1.203639000	-0.961820000
 O	-1.894022000	 0.800929000	-1.728843000
 C	-2.754422000	 2.480058000	-0.216279000
 C	-1.703687000	 3.309227000	-0.076757000
 C	-0.302205000	 3.145239000	-0.585812000
 H	-0.081474000	 3.986535000	-1.260104000
 H	-0.222135000	 2.233775000	-1.176550000
 C	 0.766247000	 3.151604000	 0.545225000
 C	 0.932012000	 4.541741000	 1.176379000
 H	 1.154825000	 5.299710000	 0.415026000
 H	 0.026495000	 4.857880000	 1.709507000
 H	 1.754741000	 4.542619000	 1.901932000
 H	 1.715822000	 2.888209000	 0.064861000
 C	 0.478886000	 2.101283000	 1.631412000
 H	-0.468592000	 2.350525000	 2.128192000
 H	 1.263349000	 2.158177000	 2.398963000
 C	 0.398098000	 0.647221000	 1.152966000
 H	-0.365517000	 0.555326000	 0.371272000
 C	 0.042844000	-0.295973000	 2.310640000
 H	 0.940888000	-0.397685000	 2.934228000
 H	-0.730407000	 0.166089000	 2.939721000
 O	 1.675027000	 0.252284000	 0.635320000
 Si	 2.179129000	-0.273208000	-0.870575000
 C	 2.683845000	 1.185217000	-1.959545000
 H	 1.814914000	 1.792557000	-2.239790000
 H	 3.146632000	 0.829158000	-2.889533000
 H	 3.405086000	 1.841560000	-1.458479000
 C	 0.851433000	-1.258909000	-1.772912000
 H	 0.660020000	-2.227558000	-1.298001000
 H	-0.093366000	-0.707088000	-1.818968000
 H	 1.173153000	-1.451487000	-2.805125000
 C	 3.697360000	-1.367697000	-0.483266000
 C	 4.796961000	-0.518420000	 0.186337000
 H	 5.666355000	-1.143246000	 0.442553000
 H	 5.154446000	 0.281962000	-0.474105000
 H	 4.438771000	-0.053356000	 1.112997000
 C	 4.249963000	-1.983129000	-1.785035000
 H	 5.125966000	-2.614096000	-1.570828000
 H	 4.570833000	-1.214641000	-2.500059000
 H	 3.507039000	-2.617122000	-2.286048000
 C	 3.284338000	-2.501329000	 0.477554000
 H	 4.148260000	-3.141622000	 0.713014000
 H	 2.510407000	-3.146726000	 0.042378000
 H	 2.896516000	-2.105195000	 1.423165000
 H	-1.881958000	 4.206965000	 0.515516000
 H	-3.697180000	 2.727595000	 0.263768000
 H	-1.634562000	-2.202989000	-0.604527000
 H	-2.602280000	-1.325079000	 2.168716000
 C	-0.310615000	-2.709797000	 3.004118000
 H	-0.904424000	-2.404829000	 3.876185000
 H	-0.656968000	-3.702745000	 2.693365000
 H	 0.734987000	-2.796673000	 3.324690000
 H	 0.180884000	-2.022621000	 1.026140000

-Si -O -C -H 0
cc-pVTZ
****

