%nprocshared=20
%mem=40GB
#p scf=xqc b3lyp gen EmpiricalDispersion=GD3 scrf=(smd,solvent=toluene)

geom5_sp

0 1
 C	-0.677355000	 0.179926000	-0.019322000
 H	-0.724583000	 0.078732000	 1.077735000
 O	 0.696241000	 0.294853000	-0.429377000
 Si	 1.986857000	-0.077435000	 0.572957000
 C	 1.819709000	-1.844550000	 1.219020000
 H	 2.648486000	-2.106443000	 1.889194000
 H	 1.802986000	-2.578244000	 0.404501000
 H	 0.890972000	-1.966499000	 1.791388000
 C	 3.525290000	 0.128928000	-0.531204000
 C	 4.799828000	-0.197332000	 0.273727000
 H	 4.798996000	-1.230111000	 0.645721000
 H	 5.693223000	-0.080703000	-0.357707000
 H	 4.924447000	 0.469744000	 1.136631000
 C	 3.424152000	-0.827047000	-1.737490000
 H	 3.399905000	-1.879071000	-1.425453000
 H	 2.523383000	-0.632786000	-2.331228000
 H	 4.294462000	-0.704297000	-2.399659000
 C	 3.602474000	 1.581628000	-1.043892000
 H	 4.472172000	 1.710225000	-1.705825000
 H	 3.711388000	 2.300614000	-0.221818000
 H	 2.707069000	 1.856724000	-1.613445000
 C	 2.012710000	 1.106520000	 2.043598000
 H	 1.094180000	 1.015675000	 2.638023000
 H	 2.854470000	 0.897861000	 2.716180000
 H	 2.091722000	 2.150919000	 1.718888000
 C	-1.341404000	 1.513309000	-0.406041000
 C	-2.759116000	 1.789564000	 0.149748000
 H	-2.731780000	 1.574937000	 1.227933000
 C	-3.103684000	 3.278998000	-0.016995000
 H	-2.382826000	 3.915427000	 0.509525000
 H	-4.102694000	 3.499862000	 0.377853000
 H	-3.092064000	 3.566738000	-1.076584000
 C	-3.837171000	 0.934532000	-0.488741000
 C	-4.136193000	-0.327749000	-0.159917000
 C	-3.375321000	-1.139926000	 0.854056000
 H	-2.971841000	-0.481422000	 1.632431000
 H	-4.047062000	-1.843894000	 1.362789000
 C	-2.202427000	-1.942909000	 0.225958000
 H	-1.596209000	-2.320797000	 1.063429000
 C	-2.716908000	-3.152853000	-0.566824000
 H	-3.322293000	-3.815067000	 0.064513000
 H	-1.886189000	-3.743112000	-0.972823000
 H	-3.339908000	-2.834534000	-1.412200000
 H	-4.930880000	-0.836197000	-0.705169000
 H	-4.403532000	 1.413277000	-1.289337000
 H	-0.673115000	 2.303132000	-0.039334000
 H	-1.346262000	 1.592132000	-1.501732000
 C	-1.282098000	-1.087514000	-0.667173000
 H	-0.441806000	-1.718155000	-0.977469000
 H	-1.815669000	-0.810562000	-1.584380000

-Si -O -C -H 0
cc-pVTZ
****

