%nprocshared=20
%mem=40GB
#p b3lyp genecp EmpiricalDispersion=GD3 scrf=(smd,solvent=toluene)

F14

0 1
 Ru                -1.28684200   -0.92873700    0.14841900
 C                 -1.12565200   -2.80375500   -0.46519400
 N                 -1.94593200   -3.86828500   -0.27717100
 N                 -0.01461300   -3.24380800   -1.10480200
 C                 -1.42220300   -5.10014500   -0.90255600
 H                 -2.01273400   -5.34290500   -1.79413800
 H                 -1.48570900   -5.93869400   -0.20549100
 C                  0.02053900   -4.70981500   -1.24052900
 H                  0.31810200   -4.99576100   -2.25196700
 H                  0.74566600   -5.12556000   -0.53053200
 Cl                -0.35380700   -1.56802800    2.31675200
 Cl                -1.59275000    0.03045400   -2.02490000
 C                  1.03743300   -2.42962200   -1.64240500
 C                  2.16030300   -2.09807500   -0.86395000
 C                  0.94098700   -2.04262200   -2.99476900
 C                  3.14599600   -1.28969700   -1.44334700
 C                  1.95540100   -1.24641200   -3.52914500
 C                  3.05871300   -0.84657000   -2.76516800
 H                  4.00338900   -1.01045600   -0.83982500
 H                  1.88142600   -0.92789200   -4.56648400
 C                 -3.30641200   -3.83742400    0.16382700
 C                 -3.60798700   -4.27242400    1.46618500
 C                 -4.30859200   -3.40000200   -0.72157200
 C                 -4.94151600   -4.22478200    1.88371200
 C                 -5.62761000   -3.36499500   -0.25563800
 C                 -5.96245100   -3.76407100    1.04297600
 H                 -5.18758400   -4.54630600    2.89344800
 H                 -6.41106500   -3.01779400   -0.92568400
 C                 -0.20597100   -2.50475500   -3.85829500
 H                 -1.16779600   -2.34250900   -3.36823200
 H                 -0.21968000   -1.96268800   -4.80863900
 H                 -0.12046100   -3.57571000   -4.08998300
 C                  2.37483300   -2.63063000    0.53118700
 H                  1.49262300   -3.13318200    0.92644800
 H                  3.21778100   -3.33422100    0.53635100
 H                  2.62348400   -1.82260700    1.22658300
 C                  4.13193500    0.04264100   -3.34646800
 H                  5.12698300   -0.40489000   -3.22695300
 H                  3.97239700    0.22366400   -4.41457300
 H                  4.14749100    1.01042900   -2.83299900
 C                 -3.97136400   -2.96302300   -2.12510900
 H                 -4.87897800   -2.72059100   -2.68641000
 H                 -3.32735200   -2.07780300   -2.12371600
 H                 -3.44005000   -3.74861000   -2.67596100
 C                 -2.51321300   -4.71621200    2.40269000
 H                 -1.97413400   -5.59020900    2.01620000
 H                 -1.77461800   -3.91799000    2.54237000
 H                 -2.92149400   -4.98403400    3.38219600
 C                 -7.38656700   -3.67239300    1.53720200
 H                 -8.10521100   -3.76363900    0.71549300
 H                 -7.60866900   -4.45315600    2.27305200
 H                 -7.57012800   -2.70520900    2.02476500
 C                 -2.97597300   -0.99035700    0.85588700
 H                 -3.13797700   -1.75412300    1.62403000
 C                 -4.15587900   -0.04227600    0.78271500
 H                 -4.99920200   -0.65764800    1.13398900
 C                 -4.03707000    1.08234300    1.86037100
 H                 -5.02452700    1.55442800    1.92416700
 H                 -3.84910800    0.61838600    2.83840700
 C                 -2.98998800    2.20312800    1.68140000
 H                 -3.09649300    2.84299600    2.57143800
 C                 -1.55663400    1.67113900    1.66296500
 H                 -1.42275300    1.18086100    0.67345700
 H                 -1.47303500    0.91117500    2.44306400
 C                 -0.38475000    2.65729800    1.85540800
 H                  0.50061600    2.03675900    2.03364800
 H                 -0.94011300    4.09396500    0.32354900
 C                  0.36777800    2.66416700   -0.55765700
 H                 -0.40676200    2.38652000   -1.26831300
 C                  1.59428000    2.15913100   -0.79260300
 H                  1.76736800    1.53986600   -1.66723700
 C                 -0.05824600    3.51433700    0.60491400
 H                  0.74534700    4.20423600    0.87885200
 C                  2.76351400    2.39755000    0.07098400
 O                  3.90499400    1.99530300   -0.56324200
 O                  2.76264900    2.88257600    1.19020700
 C                  5.15790800    2.08628600    0.16655700
 H                  4.93773900    2.35080700    1.20296500
 C                  6.02708500    3.19516900   -0.47594300
 C                  7.36754000    3.23826500    0.22577900
 C                  7.86378200    4.26009100    0.92530800
 H                  7.95888900    2.32545000    0.14770500
 H                  8.83850200    4.19124600    1.40246800
 H                  7.33321200    5.20030400    1.05067100
 H                  6.20654800    2.88485900   -1.51763500
 C                 -0.57346300    3.54825700    3.08895800
 H                 -0.83955400    2.95188700    3.97101200
 H                  0.35572400    4.08361800    3.31486900
 H                 -1.35893100    4.29724900    2.93688100
 C                  5.28094600    4.53287000   -0.49334300
 H                  4.36630800    4.45365200   -1.08763100
 H                  4.99937800    4.84744900    0.51737000
 H                  5.90533100    5.31516300   -0.93783700
 C                  5.77606200    0.71509800    0.07923000
 H                  6.11148200    0.39702000   -0.90541000
 C                  5.86660200   -0.08801800    1.13618500
 H                  5.53320400    0.18686600    2.13177500
 I                  6.63609500   -2.04978800    1.04005600
 C                 -4.54724400    0.48988100   -0.59890900
 H                 -4.72679700   -0.33859300   -1.28986300
 H                 -5.47367900    1.07030500   -0.51146200
 H                 -3.77784800    1.12885600   -1.02226000
 O                 -3.22243100    2.97798600    0.50408600
 Si                -4.15073500    4.37004400    0.37310900
 C                 -3.40708000    5.73637800    1.44514800
 H                 -2.39175100    6.00483300    1.13103600
 H                 -4.02202200    6.64427200    1.40119400
 H                 -3.36022800    5.43312600    2.49852600
 C                 -4.09765100    4.84112900   -1.47588800
 C                 -5.92343100    4.07211400    0.95381500
 H                 -6.54673300    4.95602500    0.76393600
 H                 -6.38865000    3.22193300    0.44264600
 H                 -5.96250400    3.87786200    2.03332300
 C                 -4.98148700    3.88744500   -2.30594800
 H                 -4.95183400    4.17070400   -3.36878800
 H                 -4.64015200    2.84927400   -2.23576700
 H                 -6.03206400    3.92030500   -1.99042200
 C                 -2.64940900    4.76190800   -1.99938900
 H                 -2.25341700    3.74394100   -1.92544800
 H                 -2.60833800    5.06074700   -3.05759800
 H                 -1.97407500    5.42892000   -1.44812100
 C                 -4.62104300    6.28387100   -1.64575800
 H                 -4.63176000    6.56122700   -2.71016000
 H                 -5.64734900    6.40064500   -1.27243500
 H                 -3.99024700    7.01545300   -1.12589000

-Si -O -N -C -H -Cl 0
cc-pvTZ
****
Ru     0
S    9   1.00
    208.2500000              0.0005230
     18.8471000             -0.0449130
     11.7818000              0.2576260
      7.3619500             -0.2091300
      4.2777100             -0.5106620
      1.1910700              0.8032470
      0.5485680              0.4984140
      0.1386940              0.0337660
      0.0676510             -0.0120940
S    9   1.00
    208.2500000             -0.0001820
     18.8471000              0.0052730
     11.7818000             -0.0785570
      7.3619500             -0.0138970
      4.2777100              0.5479870
      1.1910700             -1.4980850
      0.5485680              0.4795000
      0.1386940              2.1402540
      0.0676510             -1.4545610
S    9   1.00
    208.2500000             -0.0006350
     18.8471000              0.0517470
     11.7818000             -0.3171890
      7.3619500              0.3298480
      4.2777100              0.6270530
      1.1910700             -3.4222090
      0.5485680              3.8479480
      0.1386940             -1.6239260
      0.0676510             -0.6032230
S    9   1.00
    208.2500000             -0.0001750
     18.8471000              0.0148030
     11.7818000             -0.0875270
      7.3619500              0.0842820
      4.2777100              0.1549110
      1.1910700             -0.3381410
      0.5485680             -0.3160050
      0.1386940              0.2835260
      0.0676510              0.6092730
S    1   1.00
      0.0301410              1.0000000
P    8   1.00
     22.7753000             -0.0015440
     14.2340000              0.0257710
      5.9875500             -0.1865980
      1.6392400              0.4427740
      0.8278800              0.4781510
      0.4090100              0.2083690
      0.1718770              0.0246350
      0.0712710             -0.0002190
P    8   1.00
     22.7753000             -0.0000630
     14.2340000             -0.0114610
      5.9875500              0.0999930
      1.6392400             -0.3036410
      0.8278800             -0.3638860
      0.4090100              0.1659350
      0.1718770              0.7005450
      0.0712710              0.3189430
P    8   1.00
     22.7753000             -0.0001480
     14.2340000             -0.0091740
      5.9875500              0.0813740
      1.6392400             -0.2361250
      0.8278800             -0.2943330
      0.4090100              0.0150980
      0.1718770              0.6560890
      0.0712710              0.4389440
P    8   1.00
     22.7753000              0.0011030
     14.2340000             -0.0225190
      5.9875500              0.1821610
      1.6392400             -0.7313300
      0.8278800             -0.4901170
      0.4090100              1.5235390
      0.1718770             -0.0391820
      0.0712710             -0.8661830
P    1   1.00
      0.0292260              1.0000000
D    7   1.00
     25.8838000              0.0015230
      7.5925500             -0.0181620
      2.7129300              0.1096910
      1.3970800              0.2915970
      0.6825650              0.3620440
      0.3193780              0.2975140
      0.1417810              0.1610370
D    7   1.00
     25.8838000              0.0026560
      7.5925500             -0.0337600
      2.7129300              0.2929230
      1.3970800              0.6173710
      0.6825650             -0.3625300
      0.3193780             -0.8031580
      0.1417810              0.3154610
D    7   1.00
     25.8838000             -0.0015510
      7.5925500              0.0190350
      2.7129300             -0.1257740
      1.3970800             -0.3632850
      0.6825650             -0.2793510
      0.3193780              0.2457120
      0.1417810              0.5472610
D    1   1.00
      0.0580170              1.0000000
F    1   1.00
      1.6965000              1.0000000
F    1   1.00
      0.4754000              1.0000000
G    1   1.00
      1.0311000              1.0000000
****
I     0
S    11   1.00
      5.546500D+03           1.560000D-04
      8.382140D+02           9.860000D-04
      1.821870D+02           2.792000D-03
      3.121230D+01          -4.325100D-02
      1.953140D+01           2.341340D-01
      8.240990D+00          -7.509430D-01
      2.194550D+00           8.829680D-01
      1.109110D+00           4.620610D-01
      3.746410D-01           2.228600D-02
      1.770800D-01          -4.353000D-03
      8.106100D-02           1.102000D-03
S    1   1.00
      3.746410D-01           1.000000D+00
S    1   1.00
      1.770800D-01           1.000000D+00
S    11   1.00
      5.546500D+03          -7.300000D-05
      8.382140D+02          -5.080000D-04
      1.821870D+02          -1.158000D-03
      3.121230D+01           1.219300D-02
      1.953140D+01          -8.785400D-02
      8.240990D+00           3.382000D-01
      2.194550D+00          -5.765500D-01
      1.109110D+00          -4.092980D-01
      3.746410D-01           5.674590D-01
      1.770800D-01           6.124890D-01
      8.106100D-02           1.432310D-01
S    1   1.00
      1.001000D-01           1.000000D+00
P    9   1.00
      1.889880D+02           5.850000D-04
      2.128680D+01           3.692300D-02
      1.003960D+01          -2.353240D-01
      3.451800D+00           3.414830D-01
      1.974560D+00           5.347880D-01
      1.024200D+00           2.651410D-01
      4.494370D-01           2.578700D-02
      1.866480D-01           5.220000D-04
      7.348100D-02           6.060000D-04
P    1   1.00
      5.981000D-01           1.000000D+00
P    9   1.00
      1.889880D+02          -2.560000D-04
      2.128680D+01          -1.168200D-02
      1.003960D+01           8.319200D-02
      3.451800D+00          -1.569700D-01
      1.974560D+00          -2.245180D-01
      1.024200D+00          -1.144510D-01
      4.494370D-01           3.753560D-01
      1.866480D-01           5.751360D-01
      7.348100D-02           2.459170D-01
P    1   1.00
      9.618000D-02           1.000000D+00
D    9   1.00
      1.326620D+02           5.720000D-04
      3.760540D+01           4.402000D-03
      1.038910D+01          -4.092200D-02
      6.490170D+00           9.966100D-02
      3.454510D+00           3.226630D-01
      1.844130D+00           4.003430D-01
      9.624780D-01           2.683060D-01
      4.728530D-01           8.484700D-02
      1.932000D-01           7.632000D-03
D    1   1.00
      4.728530D-01           1.000000D+00
D    1   1.00
      1.932000D-01           1.000000D+00
F    1   1.00
      4.064000D-01           1.000000D+00
****

RU     0
RU-ECP     4     28
g potential
  1
2      1.0000000              0.0000000
s-g potential
  2
2     11.50059000           209.78649300
2      5.06857500            30.21430700
p-g potential
  4
2     10.53263400            48.75124400
2     10.19201000            97.49652900
2      4.73489200             7.86018800
2      4.50906500            15.32975100
d-g potential
  4
2      8.87797700            26.96750600
2      8.76612200            40.43230300
2      3.17019600             3.34075800
2      3.22885100             5.25635200
f-g potential
  2
2      7.82024900            -8.84752500
2      7.83964700           -11.83551800
I     0
I-ECP     4     28
g potential
  1
2      1.00000000             0.00000000
s-g potential
  3
2     40.03337600            49.98964900
2     17.30057600           281.00655600
2      8.85172000            61.41673900
p-g potential
  4
2     15.72014100            67.41623900
2     15.20822200           134.80769600
2      8.29418600            14.56654800
2      7.75394900            28.96842200
d-g potential
  4
2     13.81775100            35.53875600
2     13.58780500            53.33975900
2      6.94763000             9.71646600
2      6.96009900            14.97750000
f-g potential
  4
2     18.52295000           -20.17661800
2     18.25103500           -26.08807700
2      7.55790100            -0.22043400
2      7.59740400            -0.22164600






