%nprocshared=24
%mem=124GB
#p opt freq b3lyp/genecp scrf=(smd,solvent=dichloromethane) nosymm
pop=full empiricaldispersion=gd3 gfinput gfprint scf=(maxcyc=400,xqc)

Title Card Required

0 3
 C                 -0.93497400   -0.14139900    0.09528500
 C                 -0.54344000   -0.94732800   -1.12392400
 C                  0.22190900   -0.07781700    1.07209200
 C                 -1.26716600    1.25479100   -0.40393700
 C                 -1.63713700    1.64500500   -1.67677400
 H                 -1.77287400    1.10599600   -2.60188200
 C                 -1.30563200   -1.78954600   -1.89818000
 H                 -2.30185100   -2.18465400   -1.78305900
 C                  0.35796900   -0.55411500    2.35596100
 H                 -0.31490600   -1.07353700    3.01929100
 N                  1.62674000   -0.22013500    2.70833200
 N                 -1.78215200    2.98416900   -1.58832000
 N                 -0.52352700   -2.05108900   -2.97838700
 N                 -1.20485800    2.36800000    0.38339000
 N                 -1.51026200    3.41568700   -0.33583000
 N                  0.64790000   -1.41911300   -2.90074900
 N                  0.63583500   -0.75022200   -1.77612500
 N                  1.40645100    0.49434600    0.72644000
 N                  2.26093300    0.41024000    1.71963300
 Cu                 2.23317300    0.50303200   -1.21548800
 O                 -2.03582500   -0.83456700    0.67485300
 C                 -2.87720400   -0.07291700    1.54647700
 H                 -3.47811400    0.65636000    0.99029800
 H                 -3.54080500   -0.79952400    2.02133300
 H                 -2.30565700    0.45473100    2.31882700
 C                 -0.92663200   -2.65083500   -4.25786500
 H                 -0.00039400   -2.93690800   -4.76159600
 H                 -1.50671700   -3.54966100   -4.04115000
 C                 -2.01168500    3.93849500   -2.67165500
 H                 -2.90955300    3.63292000   -3.21518400
 H                 -2.21939800    4.89491800   -2.18285500
 C                  2.34733900   -0.53544300    3.94301000
 H                  2.72753200    0.40456800    4.35196300
 H                  1.60129100   -0.92520500    4.64139400
 C                 -1.72458600   -1.64448900   -5.06756200
 C                 -1.17597600   -0.38442800   -5.35131600
 C                 -3.01664800   -1.94668800   -5.50877200
 C                 -1.91685100    0.56189700   -6.05987100
 H                 -0.16952400   -0.14466500   -5.02216500
 C                 -3.75528700   -1.00138100   -6.22822300
 H                 -3.44814900   -2.91995200   -5.28728300
 C                 -3.20942100    0.25522300   -6.49971400
 H                 -1.47981800    1.53449700   -6.26889900
 H                 -4.75851000   -1.24614600   -6.56672400
 H                 -3.78647900    0.99240000   -7.05182000
 C                  3.47936500   -1.52758000    3.73150900
 C                  4.45634500   -1.63750900    4.73009000
 C                  3.57094800   -2.33297600    2.59117900
 C                  5.50851800   -2.54453900    4.59319400
 H                  4.39692500   -1.00503500    5.61317800
 C                  4.62765800   -3.23649500    2.45378800
 H                  2.85168500   -2.24519300    1.78378300
 C                  5.59855500   -3.34624200    3.45057000
 H                  6.26277500   -2.61667600    5.37256400
 H                  4.69700000   -3.83525600    1.55077800
 H                  6.42506800   -4.04197700    3.33441900
 C                 -0.81882300    4.04033100   -3.60546600
 C                 -1.02640300    4.24669500   -4.97464900
 C                  0.49069000    3.96034000   -3.11319000
 C                  0.06156300    4.39392700   -5.83998500
 H                 -2.04074800    4.29549600   -5.36391800
 C                  1.57669100    4.09894800   -3.97872700
 H                  0.67305200    3.78432100   -2.05647300
 C                  1.36592400    4.32504900   -5.34232300
 H                 -0.11097500    4.55696000   -6.90052700
 H                  2.58287500    4.02550700   -3.57733100
 H                  2.21269400    4.43895200   -6.01384700
 N                  3.56355000   -0.46082900   -2.31243200
 S                  4.08260300   -1.83550400   -1.63354400
 O                  2.99434200   -2.30407300   -0.73804600
 O                  4.58553900   -2.78339600   -2.65783600
 C                  5.48606600   -1.47770800   -0.56006200
 C                  5.41595400   -0.39252000    0.31972900
 C                  6.57571700   -2.34795900   -0.52844300
 C                  6.44038400   -0.19426300    1.24077500
 H                  4.57293300    0.28895600    0.29189200
 C                  7.59326800   -2.13829400    0.40470400
 H                  6.61956700   -3.18155400   -1.22144700
 C                  7.53699000   -1.06887300    1.30853700
 H                  6.37964500    0.64366800    1.93104600
 H                  8.43908700   -2.82099300    0.43431500
 C                  8.60348900   -0.87306200    2.35729300
 H                  8.21951800   -1.14777200    3.34874300
 H                  9.48524000   -1.49080700    2.15796800
 H                  8.92293800    0.17419900    2.41422900
 Cl                 3.31977600    2.53600100   -0.99795400
 C                  3.66306500    0.85341100   -4.36484600
 C                  4.46312300    0.22289000   -3.26356000
 H                  5.16593400   -0.51202000   -3.68093200
 H                  3.56477100    1.93518000   -4.36191900
 C                  2.99464900    0.12821600   -5.38269900
 C                  3.03014600   -1.29672100   -5.46510500
 C                  2.25603000    0.82352600   -6.38675900
 C                  2.37445800   -1.96485100   -6.49222300
 H                  3.55397800   -1.86339200   -4.70283500
 C                  1.60796900    0.14311000   -7.40794100
 H                  2.20382700    1.90767400   -6.33855900
 C                  1.65977400   -1.25780700   -7.47149000
 H                  2.41473900   -3.05100700   -6.53259400
 H                  1.04970400    0.69988000   -8.15654300
 H                  1.14622800   -1.78993600   -8.26747800
 C                  5.28811247    1.30072003   -2.53604726
 H                  6.30305747    0.97369571   -2.44749366
 H                  5.25470942    2.21282377   -3.09448347
 H                  4.87977723    1.46452220   -1.56068518

-Cu -Co -Ag 0
LANL2DZ
****
-N -C -H -O -Cl -S -B -F -Br 0
6-31g*
****
-I     0
LANL2DZ
D   1   1.00
      0.2940000              1.0000000
****

-Cu -I -Ag -Co 0
LANL2DZ







