%nprocshared=24
%mem=124GB
#p opt freq b3lyp/genecp scrf=(smd,solvent=dichloromethane) nosymm
pop=full empiricaldispersion=gd3 gfinput gfprint scf=(maxcyc=400,xqc)

Title Card Required

0 3
 C                 -1.72741678    1.57686210    0.00000000
 C                 -1.30518278    0.70757910   -1.16893900
 C                 -1.10787978    1.04348110    1.27788300
 C                 -1.21579578    2.97573010   -0.29352600
 C                 -1.00326578    3.55433510   -1.52914800
 H                 -1.15017178    3.20207110   -2.53770100
 C                 -2.04475978    0.18523710   -2.20267000
 H                 -3.10157678    0.17884010   -2.41421000
 C                 -1.69497978    0.47443510    2.38430100
 H                 -2.72212378    0.29364810    2.65834600
 N                 -0.65100978    0.13135010    3.17986800
 N                 -0.44265878    4.74940510   -1.24964900
 N                 -1.12243278   -0.36773290   -3.03215900
 N                 -0.79462678    3.84916310    0.66615200
 N                 -0.31942178    4.92094110    0.08655800
 N                  0.12008022   -0.19985090   -2.56542200
 N                  0.00980222    0.45339810   -1.43111200
 N                  0.24243722    1.00144110    1.45380200
 N                  0.52127522    0.44373210    2.60821900
 Cu                 1.55013222    1.18290210   -0.29404800
 O                 -3.14721578    1.47296010    0.06032000
 C                 -3.81814178    2.51600010    0.77230300
 H                 -3.80215178    3.45896510    0.21236200
 H                 -4.85201978    2.17977610    0.88306200
 H                 -3.38488878    2.68554410    1.76511800
 C                 -1.32470478   -0.87564090   -4.39355000
 H                 -0.42701178   -1.45099190   -4.63416000
 H                 -2.17960478   -1.55501690   -4.37700100
 C                  0.10612822    5.73178110   -2.18621200
 H                 -0.72193578    6.27355210   -2.65345100
 H                  0.66622422    6.44089910   -1.56942400
 C                 -0.68058878   -0.60640690    4.44807100
 H                  0.28183722   -0.41087590    4.92785200
 H                 -1.46914078   -0.17231490    5.06664200
 C                 -1.54197378    0.26796810   -5.36733800
 C                 -0.64479578    1.34622910   -5.40361800
 C                 -2.64251478    0.26086310   -6.23023200
 C                 -0.85091078    2.40236710   -6.29165100
 H                  0.21396922    1.36214210   -4.73692500
 C                 -2.84282978    1.31451310   -7.12768900
 H                 -3.34400778   -0.56955990   -6.20131900
 C                 -1.95085578    2.38838210   -7.15651400
 H                 -0.15084178    3.23266310   -6.30694900
 H                 -3.70030378    1.29787510   -7.79522100
 H                 -2.11020578    3.21095410   -7.84868500
 C                 -0.90500778   -2.08925590    4.22648300
 C                 -1.99100278   -2.73899790    4.82180700
 C                 -0.02307078   -2.82034490    3.41764100
 C                 -2.19215278   -4.10793490    4.61933400
 H                 -2.68013078   -2.17469890    5.44567700
 C                 -0.22744778   -4.18447490    3.20993600
 H                  0.81910822   -2.31645790    2.94929600
 C                 -1.31246378   -4.83175690    3.81200500
 H                 -3.03802778   -4.60401090    5.08778800
 H                  0.46047422   -4.74323290    2.58103200
 H                 -1.46991178   -5.89488090    3.65052600
 C                  0.98667422    5.08975010   -3.24348000
 C                  1.00840722    5.63454410   -4.53294000
 C                  1.78864222    3.97521210   -2.95796000
 C                  1.82518422    5.08118110   -5.52312800
 H                  0.38297122    6.49371210   -4.76432100
 C                  2.58716822    3.40629710   -3.95383800
 H                  1.79244622    3.53403310   -1.96428900
 C                  2.61024522    3.96078010   -5.23752000
 H                  1.83522422    5.51724510   -6.51868700
 H                  3.18709822    2.53377710   -3.71273900
 H                  3.23325522    3.51891510   -6.01052400
 N                  3.32236422    2.02552410   -0.27305700
 S                  4.55742122    1.19610310   -1.00618700
 O                  5.16051522    0.11156710   -0.20134400
 O                  3.98153522    0.82160910   -2.32147600
 C                  5.84872622    2.41459910   -1.28055600
 C                  7.18026822    2.07126410   -1.05022200
 C                  5.51045722    3.68238810   -1.76492000
 C                  8.18227522    3.00865410   -1.30974600
 H                  7.42600522    1.08676510   -0.66643900
 C                  6.52057822    4.60631310   -2.01587400
 H                  4.47098222    3.94329610   -1.92970800
 C                  7.87082822    4.28669110   -1.79207500
 H                  9.22062722    2.74187910   -1.12918700
 H                  6.25867022    5.59424910   -2.38748800
 C                  8.94932922    5.31327810   -2.03849500
 H                  8.79188322    5.83754210   -2.98841600
 H                  8.94906222    6.07499210   -1.24728000
 H                  9.94399822    4.85635710   -2.05926800
 Cl                 3.86634822    2.65137710    1.34419400

-Cu 0
LANL2DZ
****
-N -C -H -O -Cl -S 0
6-31g*
****
-I     0
LANL2DZ
D   1   1.00
      0.2940000              1.0000000
****

-Cu -I 0
LANL2DZ







