%nprocshared=12
%mem=24GB
#p opt freq b3lyp/genecp scrf=(smd,solvent=dichloromethane) nosymm
pop=full empiricaldispersion=gd3 gfinput gfprint scf=(maxcyc=400,xqc)

c3 Cl t

0 3
 C                  0.13636364   -1.54532209    0.02022936
 C                  0.89272064   -2.26448709   -1.07012364
 C                  0.81379964   -1.73956209    1.36224836
 C                  0.06332464   -0.07567409   -0.35008064
 C                 -0.12753536    0.48333191   -1.60129264
 H                 -0.17017536    0.06533191   -2.59509164
 C                  0.41461064   -2.85562509   -2.21831864
 H                 -0.58165036   -3.04707209   -2.58282764
 C                  0.27083764   -2.20964509    2.53631436
 H                 -0.71413836   -2.56164109    2.79700336
 N                  1.29291064   -2.16269309    3.42523836
 N                 -0.25316636    1.80668791   -1.36137764
 N                  1.53541364   -3.18321809   -2.91085464
 N                  0.04982764    0.92864891    0.57129236
 N                 -0.13424836    2.07114691   -0.04302364
 N                  2.63994864   -2.81949209   -2.25375764
 N                  2.25152464   -2.26526609   -1.13519564
 N                  2.12951864   -1.46370109    1.60220736
 N                  2.41508864   -1.71993409    2.85762436
 Cu                 3.71914564   -1.17198809    0.19272636
 O                 -1.15852536   -2.15794809    0.04910936
 C                 -2.23593236   -1.36761109    0.56022936
 H                 -2.54820936   -0.59946709   -0.15774064
 H                 -3.06098536   -2.06652909    0.71968136
 H                 -1.98683036   -0.88165009    1.51014836
 C                  1.65252964   -3.58816109   -4.31894164
 H                  2.58818364   -4.14473209   -4.40210264
 H                  0.81862464   -4.25594809   -4.54246164
 C                 -0.44581636    2.89825791   -2.32602564
 H                 -1.09683536    2.51698491   -3.11554464
 H                 -0.98223636    3.68068091   -1.78413864
 C                  1.32247564   -2.65485209    4.80857036
 H                  2.16105264   -2.14308809    5.28710436
 H                  0.39757964   -2.33496609    5.29281036
 C                  1.64377164   -2.35612209   -5.20373564
 C                  2.75670164   -1.50132609   -5.22489664
 C                  0.50367964   -2.02413109   -5.94411264
 C                  2.72132164   -0.33056209   -5.98432664
 H                  3.64038864   -1.74500709   -4.63908464
 C                  0.47093464   -0.85136309   -6.70502764
 H                 -0.36029036   -2.68453809   -5.92623164
 C                  1.57983464   -0.00247909   -6.72469364
 H                  3.58455364    0.32797591   -5.99883764
 H                 -0.41750636   -0.60453809   -7.28023264
 H                  1.55860364    0.90914991   -7.31615764
 C                  1.48475064   -4.16088709    4.85656736
 C                  0.53429264   -4.95579809    5.50528136
 C                  2.59274164   -4.76742809    4.24713236
 C                  0.68985564   -6.34462509    5.55237136
 H                 -0.32855436   -4.48887509    5.97449036
 C                  2.74378764   -6.15347709    4.28842936
 H                  3.33134564   -4.15354309    3.73687336
 C                  1.79327664   -6.94518109    4.94283336
 H                 -0.05332536   -6.95395609    6.05989336
 H                  3.60445664   -6.61556009    3.81245536
 H                  1.91340564   -8.02481409    4.97485036
 C                  0.85740464    3.41927391   -2.89448064
 C                  1.20951164    3.15610191   -4.22327464
 C                  1.72031064    4.17732891   -2.09073664
 C                  2.40114764    3.66239491   -4.75022364
 H                  0.55136564    2.55602991   -4.84715164
 C                  2.91273464    4.67697791   -2.61516164
 H                  1.45688464    4.36752791   -1.05337164
 C                  3.25148364    4.42647191   -3.94845864
 H                  2.66710764    3.45316391   -5.78288064
 H                  3.57972564    5.25714391   -1.98375364
 H                  4.18356264    4.81016591   -4.35343464
 N                  5.00684164   -1.14212709   -1.15459364
 S                  5.93321464   -2.36903209   -1.62641064
 O                  5.56461264   -3.72717609   -1.17210064
 O                  5.95349064   -2.11691309   -3.10119664
 C                  7.61496164   -2.08335909   -1.06019564
 C                  8.40804564   -3.14783109   -0.63766664
 C                  8.12436464   -0.78110009   -1.09216064
 C                  9.72503864   -2.90418509   -0.23909664
 H                  7.99439864   -4.15039109   -0.60964464
 C                  9.43721364   -0.55378609   -0.69221964
 H                  7.49015264    0.04096091   -1.40692364
 C                 10.25924464   -1.60961409   -0.25920164
 H                 10.34309564   -3.73342609    0.09665936
 H                  9.83346664    0.45925491   -0.70849964
 C                 11.67962764   -1.33956609    0.17469736
 H                 12.27336264   -0.92407709   -0.64980264
 H                 11.71093564   -0.60688009    0.99087336
 H                 12.17603564   -2.25205509    0.52048436
 Cl                 5.47239464   -1.57215709    1.64701736
 C                  3.53792064    1.11238891    0.54653736
 H                  2.65257464    0.98546491    1.16049036
 C                  3.42086664    1.34421391   -0.78078364
 H                  2.44724964    1.21464691   -1.24574964
 H                  4.48618464    1.22546091    1.06563136
 C                  4.52010164    1.67112291   -1.69089364
 C                  5.67903664    2.33821591   -1.25234864
 C                  4.42737364    1.29277691   -3.04116164
 C                  6.71773764    2.61021091   -2.13930964
 H                  5.75572064    2.65582991   -0.21661264
 C                  5.47616464    1.54721091   -3.92368864
 H                  3.53448364    0.78318491   -3.39003764
 C                  6.62316764    2.20755191   -3.47758764
 H                  7.60355664    3.13388091   -1.78936764
 H                  5.40095064    1.23124991   -4.96033864
 H                  7.43792564    2.41279891   -4.16679964

-Cu 0
LANL2DZ
****
-N -C -H -O -Cl -S 0
6-31g*
****
-I     0
LANL2DZ
D   1   1.00
      0.2940000              1.0000000
****

-Cu -I 0
LANL2DZ







