%nprocshared=24
%mem=124GB
#p opt=(calcfc,ts,noeigentest) freq b3lyp/genecp
scrf=(smd,solvent=dichloromethane) nosymm pop=full empiricaldispersion=gd3
gfinput gfprint iop(1/8=5) scf=(maxcyc=400,xqc)

TS1-+-t-2

1 3
 C                  0.66964285   -0.82135817    0.01075217
 C                  0.90445885   -1.78766017   -1.13694383
 C                  1.79818385   -0.97316017    1.02167417
 C                  0.66396085    0.57403283   -0.61214383
 C                 -0.35217215    1.49203283   -0.75527583
 H                 -1.37110615    1.52083983   -0.40481383
 C                  0.16150385   -2.83795117   -1.61846983
 H                 -0.76713315   -3.28379817   -1.30102283
 C                  1.89294585   -1.76885217    2.14456217
 H                  1.20259685   -2.43546317    2.63643117
 N                  3.14713185   -1.54853417    2.60779417
 N                  0.18836185    2.48683383   -1.50386383
 N                  0.85649885   -3.26876217   -2.70464783
 N                  1.73944485    1.06425983   -1.29218883
 N                  1.45367085    2.22467383   -1.83187983
 N                  1.95790085   -2.53873617   -2.90650083
 N                  1.98547385   -1.64615417   -1.95110883
 N                  2.99478585   -0.34502217    0.85675017
 N                  3.81097885   -0.69005117    1.82095617
 Cu                 3.38975485   -0.12516817   -1.55793283
 O                 -0.59799415   -1.14877317    0.53472917
 C                 -1.01047415   -0.47423517    1.73516417
 H                 -2.10210815   -0.43883817    1.70078417
 H                 -0.69829115   -1.02759817    2.62664717
 H                 -0.61776615    0.54577783    1.79624417
 C                  0.44181585   -4.24942617   -3.70730183
 H                  1.35253485   -4.54359617   -4.23630083
 H                  0.06042385   -5.12613817   -3.17811083
 C                 -0.48098615    3.67664683   -2.04937683
 H                 -1.34129115    3.86344283   -1.40160783
 H                  0.21311185    4.51245183   -1.94752483
 C                  3.76175585   -2.06738317    3.83771017
 H                  4.06823485   -1.20587017    4.43611417
 H                  2.95952085   -2.58115717    4.37530417
 C                 -0.59734315   -3.69201417   -4.66591383
 C                 -0.76143115   -2.31624517   -4.86605883
 C                 -1.38607815   -4.58874417   -5.39724783
 C                 -1.69459015   -1.84419817   -5.79297783
 H                 -0.16753715   -1.60460017   -4.30111883
 C                 -2.31698615   -4.11674317   -6.32469383
 H                 -1.26968415   -5.65869317   -5.24096183
 C                 -2.47343615   -2.74205217   -6.52631383
 H                 -1.80537215   -0.77322317   -5.94067483
 H                 -2.92316915   -4.82328117   -6.88524583
 H                 -3.19901615   -2.37488417   -7.24693283
 C                  4.93258785   -2.99600417    3.58996617
 C                  6.08504685   -2.87487917    4.37485817
 C                  4.86140685   -4.00792117    2.62510617
 C                  7.15150485   -3.76222917    4.20629617
 H                  6.14858485   -2.08444417    5.11924117
 C                  5.93191985   -4.88501917    2.44755517
 H                  3.98767985   -4.08772317    1.98764117
 C                  7.07687985   -4.76886817    3.24092317
 H                  8.04275685   -3.65767017    4.81940317
 H                  5.87447785   -5.65366617    1.68163617
 H                  7.91060385   -5.45085517    3.09780817
 C                 -0.89982015    3.48214583   -3.49387083
 C                 -1.67942915    2.38069383   -3.87344783
 C                 -0.52559715    4.42199283   -4.46001583
 C                 -2.08148315    2.22553683   -5.20074183
 H                 -1.97344715    1.64100883   -3.13294183
 C                 -0.93324015    4.27082383   -5.78881583
 H                  0.08621085    5.27353483   -4.17322283
 C                 -1.71087715    3.17219683   -6.16221583
 H                 -2.69077115    1.37092483   -5.48191883
 H                 -0.63582715    5.00707383   -6.53033283
 H                 -2.02546115    3.05199183   -7.19523483
 N                  5.09321685   -0.93001217   -1.54348383
 S                  5.27131085   -2.54923217   -1.22653883
 O                  4.23255285   -2.94468917   -0.24733483
 O                  5.37661985   -3.35552417   -2.46192683
 C                  6.85691485   -2.57123117   -0.40262283
 C                  7.00242785   -1.86008417    0.79534517
 C                  7.91711985   -3.28982917   -0.95223683
 C                  8.23402485   -1.87710517    1.43902117
 H                  6.16302685   -1.31688617    1.21731817
 C                  9.14262885   -3.30493817   -0.28230483
 H                  7.78231785   -3.82948517   -1.88368883
 C                  9.31950985   -2.60319617    0.91725917
 H                  8.35516785   -1.33420417    2.37249317
 H                  9.97114885   -3.87134017   -0.69967083
 C                 10.63010285   -2.63921917    1.66193417
 H                 10.51955585   -3.18556817    2.60804117
 H                 11.41492785   -3.13121417    1.07882317
 H                 10.97129185   -1.62797117    1.91437917
 C                  5.66131285    0.69246983   -3.93688383
 C                  6.13507685   -0.55534617   -3.67204983
 H                  5.62120285   -1.45535317   -3.98582183
 H                  6.28563185    1.54726983   -3.67966583
 C                  4.34033585    1.01814983   -4.46066583
 C                  3.35967585    0.03497683   -4.73028083
 C                  4.00685185    2.37124283   -4.68864183
 C                  2.10601885    0.39824483   -5.21329783
 H                  3.56986585   -1.01263617   -4.54137383
 C                  2.75145785    2.72892783   -5.17492983
 H                  4.74763385    3.13971783   -4.48064183
 C                  1.79486785    1.74407183   -5.43973683
 H                  1.36860285   -0.37189717   -5.41721183
 H                  2.51144985    3.77541383   -5.34005883
 H                  0.81312385    2.02409883   -5.80768783
 H                  7.13751385   -0.68789117   -3.27862883

-Cu 0
LANL2DZ
****
-N -C -H -O -Cl -S 0
6-31g*
****
-I     0
LANL2DZ
D   1   1.00
      0.2940000              1.0000000
****

-Cu -I 0
LANL2DZ







