%nprocshared=12
%mem=24GB
#p opt freq b3lyp/genecp scrf=(smd,solvent=dichloromethane) nosymm
pop=full empiricaldispersion=gd3 gfinput gfprint scf=(maxcyc=400,xqc)

Title Card Required

1 1
 C                 -1.04545457   -1.43636361    0.00000000
 C                 -0.84556057   -2.27710661   -1.24261800
 C                  0.12547543   -1.60149361    0.94934600
 C                 -1.16810257    0.00484039   -0.46043100
 C                 -2.23352522    0.86499576   -0.27146255
 H                 -3.20527033    0.74098702    0.18099556
 C                 -1.71834857   -3.11554861   -1.89379700
 H                 -2.71644157   -3.45001261   -1.66286300
 C                  0.16300043   -2.09046561    2.23533600
 H                 -0.59671657   -2.47525261    2.89655200
 N                  1.46876543   -1.99771361    2.59409000
 N                 -1.83024518    2.02490339   -0.83011380
 N                 -1.05724957   -3.47858761   -3.02404100
 N                 -0.18252063    0.68170687   -1.11511175
 N                 -0.58774639    1.90507811   -1.34721481
 N                  0.14597743   -2.90863461   -3.09362200
 N                  0.27427443   -2.17426561   -2.01205900
 N                  1.39743743   -1.26445061    0.60046500
 N                  2.21143043   -1.49899061    1.60207300
 Cu                 2.07847543   -1.34721461   -1.47339200
 O                 -2.23452157   -1.94008261    0.60563100
 C                 -2.92004157   -1.05034961    1.49317100
 H                 -3.42006057   -0.24275161    0.94511400
 H                 -3.67161757   -1.66261861    1.99701500
 H                 -2.25038257   -0.61058061    2.24145900
 C                 -1.58136257   -4.21862461   -4.17724900
 H                 -0.70884257   -4.48061361   -4.78163300
 H                 -2.03669257   -5.14016961   -3.80832500
 C                 -2.60308460    3.26184358   -1.00060493
 H                 -2.95418663    3.57749427   -0.01508006
 H                 -1.89276730    4.00331602   -1.37259672
 C                  2.09337943   -2.38682261    3.86187200
 H                  2.53822643   -1.48990961    4.30174900
 H                  1.27643243   -2.70600061    4.51558800
 C                 -2.57880457   -3.38295761   -4.95900500
 C                 -2.32887257   -2.02776961   -5.21951900
 C                 -3.75374557   -3.96765861   -5.44235900
 C                 -3.24173457   -1.27127361   -5.95521300
 H                 -1.41870257   -1.56437461   -4.85134300
 C                 -4.66523357   -3.21098761   -6.18517200
 H                 -3.95809057   -5.01566461   -5.23663800
 C                 -4.41269057   -1.86160661   -6.44176700
 H                 -3.03382257   -0.22286561   -6.15065600
 H                 -5.57500057   -3.67590661   -6.55508400
 H                 -5.12399357   -1.27239461   -7.01406900
 C                  3.13417143   -3.48160461    3.70942500
 C                  4.10981143   -3.61631861    4.70611700
 C                  3.13807443   -4.36339761    2.62387800
 C                  5.07119643   -4.62526161    4.62230100
 H                  4.11990143   -2.92573661    5.54658200
 C                  4.10989743   -5.36278561    2.53344100
 H                  2.41697743   -4.25386561    1.82183100
 C                  5.07598743   -5.50029861    3.53168000
 H                  5.82508543   -4.71745961    5.39979400
 H                  4.11599643   -6.02239361    1.67027800
 H                  5.83535143   -6.27382261    3.45541200
 C                 -3.75941979    3.05908800   -1.95653371
 C                 -5.07247797    2.98984628   -1.47820352
 C                 -3.51763373    2.90678470   -3.32973520
 C                 -6.13640895    2.77815272   -2.36078917
 H                 -5.26370187    3.10626235   -0.41433907
 C                 -4.57904916    2.69919290   -4.21200542
 H                 -2.49681487    2.95708776   -3.70185975
 C                 -5.89123224    2.63490923   -3.72852101
 H                 -7.15308597    2.73057745   -1.98017019
 H                 -4.38488858    2.58979786   -5.27550703
 H                 -6.71659645    2.46960887   -4.41525873
 N                  4.04831943   -1.46202961   -1.36643500
 S                  4.42276943   -3.08478961   -1.16109200
 O                  3.23262843   -3.71431161   -0.54714800
 O                  4.97772743   -3.70739361   -2.38489900
 C                  5.73954343   -3.02163261    0.04754100
 C                  5.52973343   -2.35062061    1.25835100
 C                  6.93792943   -3.68555661   -0.21559700
 C                  6.54090543   -2.35980661    2.21251200
 H                  4.58922843   -1.84674761    1.44998100
 C                  7.93722043   -3.68726161    0.75916500
 H                  7.08260543   -4.19469761   -1.16229300
 C                  7.75401743   -3.03310961    1.98473900
 H                  6.38216843   -1.85011761    3.15899400
 H                  8.87034443   -4.20914761    0.56308800
 C                  8.81081443   -3.07749961    3.05931800
 H                  8.50904443   -3.76199361    3.86337700
 H                  9.77223043   -3.42548361    2.66842000
 H                  8.95906243   -2.09197461    3.51584900
 C                  3.22781343   -0.61239361   -3.23611200
 C                  4.56677343   -0.83364861   -2.59833500
 H                  5.23062943   -1.47514861   -3.18136500
 H                  2.74262843    0.32966439   -2.96575100
 C                  2.68019943   -1.30268461   -4.36758800
 C                  3.24432143   -2.48439361   -4.90898900
 C                  1.54201243   -0.73382261   -4.99437300
 C                  2.69822843   -3.04986261   -6.05333700
 H                  4.07849543   -2.96283361   -4.40833400
 C                  1.02794343   -1.28654961   -6.15840100
 H                  1.09042643    0.15536439   -4.56667600
 C                  1.59968043   -2.45042961   -6.68649700
 H                  3.12719543   -3.96026061   -6.46129700
 H                  0.17751443   -0.82245261   -6.64711500
 H                  1.18557243   -2.89525361   -7.58699400
 H                  5.07859143    0.10523339   -2.37035800

-Cu 0
LANL2DZ
****
-N -C -H -O -Cl -S 0
6-31g*
****
-I     0
LANL2DZ
D   1   1.00
      0.2940000              1.0000000
****

-Cu -I 0
LANL2DZ







