%nprocshared=8
%mem=24GB
#p opt freq b3lyp/genecp scrf=(smd,solvent=dichloromethane) nosymm
pop=full empiricaldispersion=gd3 gfinput gfprint scf=(maxcyc=400,xqc)

Title Card Required

0 1
 C                  0.85246421   -2.80745871    0.05564567
 C                  2.23048721   -2.89863471    0.26317367
 C                  3.03867621   -1.77268271    0.09695867
 C                  2.49185721   -0.53245371   -0.28116733
 C                  1.09936521   -0.45673771   -0.48325033
 C                  0.29205821   -1.57988871   -0.31752733
 H                  0.21924921   -3.68119671    0.18479567
 H                  2.67774621   -3.84534871    0.55508267
 H                  4.11113521   -1.85053971    0.26132267
 H                  0.64360821    0.48718429   -0.76818433
 H                 -0.77995179   -1.49901371   -0.47869433
 C                  3.39476521    0.62093929   -0.44541333
 C                  3.02686788    2.02511626   -0.90833400
 H                  3.78532888    2.79933626   -0.98945800
 H                  2.01292288    2.31366126   -1.17539600
 H                  4.37350985    0.24889807   -0.22508571
 S                  4.11086303    1.74740440   -3.29599868
 O                  5.49001003    1.74740440   -3.29599868
 O                  3.39118303    2.93222440   -3.29599868
 C                  3.49080003    0.63657240   -4.34659368
 C                  4.23032203   -0.49893660   -4.71042768
 C                  3.71542003   -1.43701560   -5.59721068
 C                  2.43815503   -1.26245860   -6.14611368
 C                  1.69244903   -0.12913560   -5.79334868
 C                  2.21425403    0.80291140   -4.90527868
 H                  5.24148103   -0.63913060   -4.28653268
 H                  4.31242303   -2.32031860   -5.87073668
 H                  0.69047803    0.02180040   -6.22306468
 H                  1.62341903    1.69767240   -4.63682968
 C                  1.87933303   -2.26853560   -7.07686468
 H                  1.14004303   -1.80449360   -7.77529068
 H                  2.68844303   -2.74756660   -7.68178668
 H                  1.35646303   -3.06984260   -6.49447168
 N                  3.67885655    1.09746792   -1.77446887

-Cu 0
LANL2DZ
****
-N -C -H -O -Cl -S 0
6-31g*
****
-I     0
LANL2DZ
D   1   1.00
      0.2940000              1.0000000
****

-Cu -I 0
LANL2DZ







