%chk=LO-int2a2-cis.chk
%nprocshared=8
%mem=22GB
#p opt freq=noraman b97d3/gen pseudo=read nosymm

LO-int2a2-cis

-1 1
 N                  1.49926358   11.98581866    0.21265188
 O                  3.70042558   10.25354566    0.36123588
 O                  0.74719758    9.29090166    0.35643888
 O                  2.02433558   10.73069466   -2.21620812
 C                  2.66091858   12.91856566    0.18863088
 H                  3.01740258   12.95517266   -0.84337012
 H                  2.31943458   13.93145866    0.44710788
 C                  3.79422658   12.52480766    1.10141188
 C                  4.25916658   11.18629666    1.08655888
 C                  5.36997458   10.89780366    1.91118388
 C                  5.99153658   11.85375166    2.69959488
 H                  6.83880558   11.58559366    3.31460788
 C                  5.49532058   13.14862566    2.68230788
 C                  4.40613758   13.49136066    1.89988188
 H                  4.03459158   14.50895166    1.90339188
 C                  0.99800458   11.84806366    1.60802088
 H                  1.81806758   11.43397366    2.19983088
 H                  0.77924558   12.84603166    2.01552688
 C                 -0.21856042   10.97105466    1.75291088
 C                 -0.22678842    9.70030166    1.12725588
 C                 -1.35212542    8.88482466    1.37939588
 C                 -2.40878642    9.28422066    2.18320488
 H                 -3.24996442    8.62527166    2.34473588
 C                 -2.35804942   10.54279566    2.76284988
 C                 -1.28117442   11.38751366    2.55457888
 H                 -1.26074042   12.36521066    3.02065588
 C                  0.40989658   12.50774766   -0.66012812
 H                 -0.38620342   11.75843866   -0.65330512
 H                 -0.00715742   13.42246466   -0.21396312
 C                  0.82713858   12.79286166   -2.08012512
 C                  1.59687458   11.83049166   -2.77781612
 C                  1.89600358   12.12361966   -4.12638812
 C                  1.47096858   13.28025766   -4.76059712
 H                  1.72272658   13.45900466   -5.79619812
 C                  0.72543958   14.19460766   -4.03161012
 C                  0.40539958   13.96668966   -2.70392412
 H                 -0.17723642   14.69594766   -2.15421012
 Al                 2.17614958    9.93164666   -0.58070212
 C                  2.28905758    7.48713266   -2.08913412
 O                  2.76759258    8.31174866   -1.22340312
 O                  2.84032858    6.49791066   -2.52660212
 O                  1.02113458    7.87103866   -2.48113112
 C                  0.22347958    7.16608666   -3.46015112
 C                  0.82741758    7.32285866   -4.87067512
 C                 -0.16151242    5.71653066   -3.10485512
 H                 -0.68812542    7.75848666   -3.41783912
 C                  1.71918658    6.19048766   -5.35296112
 C                  0.76526158    4.60514966   -3.62347812
 H                 -0.27400442    5.66015366   -2.01940412
 H                 -1.16037042    5.56161866   -3.53037812
 C                  1.11712958    4.80227166   -5.10526412
 H                  1.97071758    6.33320666   -6.40654012
 H                  2.64143258    6.28109566   -4.76976712
 H                  1.68215558    4.59478866   -3.03582012
 H                  0.22229958    4.67624966   -5.72701312
 H                  1.83309258    4.03765566   -5.42429412
 Cl                -0.65994658    7.55203334   -6.14194488
 C                  0.25387541   15.49238856   -4.71351331
 H                  1.02287032   15.85314941   -5.36420404
 H                 -0.63098553   15.29541880   -5.28195331
 H                  0.04209633   16.23030202   -3.96817221
 C                  2.73764764   11.11648673   -4.93194292
 H                  3.56170686   10.78331609   -4.33627210
 H                  2.12971103   10.27795500   -5.20060185
 H                  3.10630345   11.58842823   -5.81865827
 C                 -1.41682473    7.48585930    0.73884149
 H                 -1.64707377    7.58037461   -0.30180842
 H                 -0.47143698    6.99767480    0.85205763
 H                 -2.17691687    6.90752049    1.22121495
 C                 -3.52680611   11.00754180    3.65145488
 H                 -4.40643584   11.12155347    3.05299612
 H                 -3.70640102   10.27908945    4.41434598
 H                 -3.27963932   11.94489043    4.10442964
 C                  6.16809005   14.22173413    3.55833267
 H                  6.07467053   13.95061461    4.58919008
 H                  7.20417315   14.29406344    3.30103848
 H                  5.69286999   15.16612542    3.39343576
 C                  5.91652201    9.45833561    1.93977835
 H                  5.16034707    8.79696734    2.30814159
 H                  6.19692983    9.16356826    0.95014021
 H                  6.77203300    9.41432178    2.58092088
 C                  1.49253046    8.70596097   -4.99816180
 H                  0.85690396    9.44882563   -4.56338478
 H                  2.43283017    8.69797201   -4.48760071
 H                  1.64998094    8.93207152   -6.03207831
 C                  0.06312118    3.24806166   -3.43135566
 C                  0.66237213    2.10521416   -3.84531812
 H                  0.17123032    1.16427021   -3.71002509
 H                  1.62665336    2.14382131   -4.30745578
 C                 -1.32474973    3.18946289   -2.76653950
 H                 -1.25124937    3.53479605   -1.75646886
 H                 -2.00604162    3.81225262   -3.30771813
 H                 -1.68125771    2.18062523   -2.77351399
   
C,H,O,N 0
6-311G**
****
Al     0 
S   2   1.00
      0.9615000             -0.5021546        
      0.1819000              1.2342547        
S   1   1.00
      0.0657000              1.0000000        
P   2   1.00
      1.9280000             -0.0712584        
      0.2013000              1.0162966        
P   1   1.00
      0.0580000              1.0000000        
****
Cl     0 
S   2   1.00
      2.2310000             -0.4900589        
      0.4720000              1.2542684        
S   1   1.00
      0.1631000              1.0000000        
P   2   1.00
      6.2960000             -0.0635641        
      0.6333000              1.0141355        
P   1   1.00
      0.1819000              1.0000000        
****

AL     0
AL-ECP     2     10
d   potential
  5
1    304.7291926            -10.0000000        
2     61.5299768            -63.8079837        
2     13.9259006            -22.8972174        
2      4.1463626             -8.0063232        
2      1.3715443             -0.8829345        
s-d potential
  5
0    467.8437756              3.0000000        
1     79.3992216             50.9705682        
2     25.4035967            143.8716460        
2      6.9954696             48.0055753        
2      1.7860129             14.0114180        
p-d potential
  6
0    776.2717190              5.0000000        
1    118.4992254             93.0595424        
2     34.4107276            266.7686329        
2      8.7859563             70.0725805        
2      2.3406228             17.2290839        
2      0.7398386              0.7105331        
CL     0
CL-ECP     2     10
d   potential
  5
1     94.8130000            -10.0000000        
2    165.6440000             66.2729170        
2     30.8317000            -28.9685950        
2     10.5841000            -12.8663370        
2      3.7704000             -1.7102170        
s-d potential
  5
0    128.8391000              3.0000000        
1    120.3786000             12.8528510        
2     63.5622000            275.6723980        
2     18.0695000            115.6777120        
2      3.8142000             35.0606090        
p-d potential
  6
0    216.5263000              5.0000000        
1     46.5723000              7.4794860        
2    147.4685000            613.0320000        
2     48.9869000            280.8006850        
2     13.2096000            107.8788240        
2      3.1831000             15.3439560        


