%mem=100GB
%nprocshared=24
%chk=ts1-OCOR-COOEt-Int-c1.chk
#P B3LYP/GenECP OPT=(MaxCycle=100) Freq=NoRaman SCRF=(PCM,Solvent=Dichloromethane) EmpiricalDispersion=GD3BJ 

Opt of Geom

1 1
 C                 -2.78748600   -1.19052200    0.97304600
 C                 -3.95520100   -1.35298300    1.94921100
 C                 -5.27012800   -0.99577800    1.18474900
 H                 -5.45068400   -1.77656400    0.43975100
 H                 -6.08651000   -1.04461000    1.91424300
 C                 -5.24866000    0.35257300    0.50318300
 C                 -5.61121700    1.52664900    1.17624100
 H                 -5.96268800    1.47223500    2.20287800
 C                 -5.54470400    2.76081000    0.52723900
 H                 -5.84432100    3.66394600    1.05160200
 C                 -4.83106100    0.44867300   -0.82938100
 H                 -4.56528600   -0.45743300   -1.36423300
 C                 -4.01594400   -2.83064000    2.38523500
 H                 -4.86586800   -2.97950400    3.05953400
 H                 -4.13255000   -3.49159100    1.52290000
 H                 -3.10323100   -3.11628200    2.92061800
 C                 -3.77629800   -0.45916700    3.18215500
 H                 -4.64394000   -0.56932800    3.84098700
 H                 -2.88690100   -0.75756200    3.74381600
 H                 -3.67756900    0.59415800    2.91129600
 C                  0.51201800   -2.76469200    0.73112300
 C                  1.22611000   -3.82756700    1.56987400
 C                  2.19043300   -4.61727700    0.62823400
 H                  2.73088300   -5.33506300    1.25571500
 H                  1.58242400   -5.19183500   -0.07700800
 C                  3.16190900   -3.74764800   -0.13626200
 C                  4.40666200   -3.38563300    0.39564800
 H                  4.71102900   -3.77104800    1.36474900
 C                  5.26431000   -2.54927900   -0.32142500
 H                  6.23311200   -2.28534000    0.09324700
 C                  2.81008400   -3.26101600   -1.40062800
 H                  1.85699200   -3.55209300   -1.82949500
 C                  0.15872600   -4.79435400    2.12137200
 H                 -0.41708300   -5.24970900    1.31171800
 H                  0.64603400   -5.58891900    2.69620200
 H                 -0.53474400   -4.26927300    2.78837800
 C                  2.00112100   -3.19271600    2.72935400
 H                  2.48511900   -3.98061900    3.31631900
 H                  2.77115700   -2.51025700    2.36657800
 H                  1.33236900   -2.63332300    3.38793100
 O                 -1.90700600   -0.30372600    1.24488900
 O                 -2.77261800   -1.94277200   -0.04742000
 O                  0.68100800   -1.54108100    1.05404500
 O                 -0.20260700   -3.17181200   -0.23627600
 Rh                -1.21771000   -1.80891500   -1.39091700
 C                 -2.00063700    0.86948800   -2.16987300
 C                 -2.68163200    1.93755900   -3.02737000
 C                 -4.22604800    1.72959100   -2.91081300
 H                 -4.48189600    0.79747800   -3.42388600
 H                 -4.70050400    2.54834700   -3.46348300
 C                 -4.74145500    1.67916600   -1.49118800
 C                 -5.10952800    2.83903700   -0.79701200
 H                 -5.07138600    3.80188300   -1.29893700
 C                 -2.25720300    1.72073200   -4.49365400
 H                 -2.76613100    2.44956800   -5.13318700
 H                 -2.51569500    0.71485200   -4.83403000
 H                 -1.17674700    1.86035300   -4.61276500
 C                 -2.28128100    3.34719200   -2.57192600
 H                 -2.77763400    4.08706100   -3.20891500
 H                 -1.19992700    3.49187800   -2.65616600
 H                 -2.56960000    3.53449700   -1.53526800
 O                 -1.29518600    1.27592100   -1.18431800
 O                 -2.18047100   -0.34649300   -2.48065300
 C                  1.26805400   -0.68560500   -2.38034000
 C                  2.41872400   -0.50905900   -3.37372000
 C                  3.19071900   -1.86429900   -3.46083500
 H                  4.04870700   -1.70102500   -4.12267400
 H                  2.53783300   -2.59602100   -3.94623800
 C                  3.64831200   -2.40605200   -2.12620400
 C                  4.88695200   -2.05704400   -1.57240100
 H                  5.56311700   -1.41292000   -2.12774400
 C                  1.81287700   -0.18701200   -4.75460700
 H                  1.13190200   -0.97729600   -5.08041500
 H                  2.61571900   -0.08843600   -5.49284000
 H                  1.25925300    0.75846800   -4.72677000
 C                  3.35643000    0.62331300   -2.93878400
 H                  4.15972900    0.73207800   -3.67530100
 H                  3.80424600    0.41555800   -1.96593800
 H                  2.81930100    1.57410200   -2.87105500
 O                  1.26912100    0.05629600   -1.34016400
 O                  0.38949800   -1.56033800   -2.65333600
 Rh                -0.27743700   -0.05474500    0.00437800
 C                  0.28744438    1.51889393    1.02311912
 C                  1.72172124    1.70288761    1.41627494
 O                  2.45670039    0.68591855    1.18961320
 C                  3.87599162    0.68890760    1.61447748
 O                  2.20041340    2.69355423    2.08226304
 H                  3.87174132    0.76440075    2.70248957
 H                  4.33430385    1.58260312    1.18742678
 C                  4.47878600   -0.59425626    1.09951703
 H                  4.44393193   -0.63006120    0.00730409
 H                  5.52511008   -0.63989047    1.41649819
 H                  3.95416635   -1.46474095    1.50356008
 C                 -0.74748580    3.57680254    2.00012327
 O                 -0.69851425    2.35816130    1.30862536
 O                  0.24314747    4.07843820    2.48721921
 H                  1.46440249    3.35644899    2.31633189
 C                 -2.13842702    4.11323989    2.02246031
 H                 -2.15361782    5.09202932    1.53913627
 H                 -2.79542056    3.42319414    1.48987105
 C                 -2.60546433    4.24654775    3.52086661
 C                 -4.10508667    4.37287903    3.56707520
 C                 -4.90608779    3.45846673    4.11311926
 H                 -5.98446350    3.58678932    4.13180969
 H                 -4.51235087    2.55077468    4.56517954
 H                 -4.53132938    5.26807942    3.11669377
 C                 -1.85474532    5.40017854    4.17137077
 C                 -0.74197731    5.11970062    4.97567700
 C                  0.07750706    6.15260017    5.43729225
 C                 -0.20386390    7.47722326    5.09155074
 C                 -1.32283757    7.76723885    4.30712513
 C                 -2.14558865    6.73427947    3.85899475
 H                 -2.99493266    6.97040729    3.22729529
 H                 -1.54420742    8.79332701    4.03157357
 H                  0.44599543    8.27557309    5.43112208
 H                  0.93283942    5.92301547    6.06664940
 H                 -0.51053151    4.08918199    5.23248138
 H                 -2.31464945    3.32062977    4.02655065

H C O 0
6-31G*
****
Rh 0
SDD
****

Rh 0
SDD


