%mem=24GB
%nprocshared=12
%chk=D3BJ-PF5.chk
#B3LYP/Gen OPT=(MaxCycle=100) Freq=NoRaman SCRF=(PCM,Solvent=Dichloromethane) EmpiricalDispersion=GD3BJ 

PF5

0 1
 P                  0.26741700    0.00276200    0.00000700
 F                  0.02389900   -0.00944900   -1.57564100
 F                 -0.18068900    1.54172200    0.00394700
 F                  1.82401200    0.16672100    0.00060200
 F                  0.02359700   -0.01763400    1.57552400
 F                  0.13160000   -1.58237800   -0.00410000

F P 0
6-31G*
****


