%nproc=8
%Mem=8000MB
%Chk=TS2_3_c
#p SCRF=(SMD,Solvent=Dichloromethane) M06/genecp opt=(ts, noeigentest, calcfc) freq=noraman nosymm
# scf(maxcyc=100) gfinput gfprint pop=full

opt freq

1 1
 Au                 0.32073400    1.06165400   -0.78625700
 P                  2.55415800    0.38177100   -0.84604800
 C                  3.65568800    1.50309500    0.06829800
 H                  3.58920500    2.51504400   -0.34821000
 H                  4.69251200    1.14761500   -0.00258800
 H                  3.35729600    1.53778200    1.12278200
 C                  2.85563300   -1.25806900   -0.12064700
 H                  3.92696500   -1.49648700   -0.16366300
 H                  2.29290100   -2.02113900   -0.67112100
 H                  2.52649700   -1.26470500    0.92524100
 C                  3.25407500    0.29945900   -2.52290800
 H                  4.31719300    0.02756000   -2.47544800
 H                  3.15229700    1.27406600   -3.01492700
 H                  2.71571400   -0.45046000   -3.11438800
 C                 -1.66497400    1.93797200   -0.63498400
 C                 -2.34377000    0.93982300   -1.00493000
 C                 -4.86507600    1.20593400   -1.83018900
 C                 -4.52096400    1.22245800   -0.51326700
 H                 -4.39210100    2.17447700    0.00158400
 H                 -4.55811100    0.34237000    0.12605400
 C                 -5.14623300   -0.04043100   -2.56332400
 C                 -5.43151500   -0.00677300   -3.93825700
 C                 -5.13121100   -1.29575700   -1.92823100
 C                 -5.69536800   -1.17322300   -4.64634700
 H                 -5.45213300    0.94303100   -4.46806100
 C                 -5.39099600   -2.45998600   -2.63657600
 H                 -4.92397500   -1.37227400   -0.86245900
 C                 -5.67603400   -2.40490100   -3.99964800
 H                 -5.91752200   -1.11725100   -5.71062200
 H                 -5.37587000   -3.41806600   -2.11978200
 H                 -5.88453100   -3.31876700   -4.55337900
 C                 -4.89438000    2.49736800   -2.58685600
 H                 -5.87904300    2.66655600   -3.04467000
 H                 -4.16092000    2.49822500   -3.40610100
 H                 -4.67316300    3.34480300   -1.92841100
 H                 -2.44748700   -0.06350100   -1.39169400
 C                 -1.75371500    3.30641300   -0.16334700
 C                 -1.87761800    4.35424700   -1.08748800
 C                 -1.70678500    3.62521800    1.20144400
 C                 -1.96498700    5.67094700   -0.65716800
 C                 -1.79673100    4.94213700    1.63726100
 C                 -1.92479700    5.96522400    0.70352600
 H                 -2.06581600    6.46989700   -1.38873800
 H                 -1.76866900    5.16703100    2.70118100
 H                 -1.99240200    6.99572000    1.04595200
 Br                -1.53213900    2.23370100    2.50173500
 H                 -1.90233600    4.11329800   -2.14961300

C H P 0
6-31G*
****
Br 0
LANL2DZ
D 1 1.0
0.428 1.0
****
Au 0
SDD 
****

Br 0
LANL2DZ
Au 0
SDD


