%nproc=20
%Mem=40000MB
%Chk=IE9_NFA_B-TSInt1b-2b_2
#p SCRF=(PCM,Solvent=Dichloromethane) BP86/genecp opt=(modredundant) EmpiricalDispersion=GD3 freq=noraman nosymm 
# scf(maxcyc=100) gfinput gfprint

opt freq

1 1
 Au                -0.87351700    7.19440900    6.57481500
 C                 -1.31007000    3.75519800    6.71523400
 C                 -1.65725500    2.52850100    7.33044800
 C                 -2.13415100    1.43661500    6.59533600
 C                 -2.27887500    1.55475500    5.20474700
 C                 -1.90275500    2.74402300    4.56893200
 C                 -1.40203000    3.84815500    5.29267600
 C                 -1.60222300    5.43181900    3.33569100
 C                 -0.68746000    6.59798700    2.86288400
 C                  0.71160300    6.28961500    3.45640400
 C                  0.54305200    4.99039900    4.26976800
 C                 -3.06346900    5.82847000    3.45633400
 C                 -3.67779000    6.45026900    2.34528900
 C                 -5.79289200    6.60219600    3.54654100
 C                 -3.84144400    5.59602800    4.60471400
 C                  0.95339100    3.70898500    3.55310800
 C                  1.32354400    2.59163600    4.32853800
 C                  1.53816400    1.21847900    2.33342700
 C                  0.88410000    3.55779400    2.15091000
 C                  0.67252900    4.88203900    8.74030500
 C                 -2.47754300    5.37047100    9.00446600
 P                 -0.96288400    5.21713000    7.79839500
 N                 -0.93938600    5.01516000    4.59537200
 H                 -1.53522100    4.62492600    2.57008000
 H                 -1.07099300    7.54633600    3.27126900
 H                 -0.68294300    6.67717000    1.76314600
 H                  1.01018600    7.09173700    4.14752200
 H                  1.50106400    6.19582700    2.69461600
 H                  1.08638800    5.04949500    5.22289700
 H                 -1.57174400    2.42316700    8.41446900
 H                 -2.39991400    0.50823200    7.11077300
 H                 -2.65622000    0.71562100    4.61083700
 H                 -1.96136700    2.81254000    3.47944800
 H                 -3.09588500    6.62897100    1.43345500
 H                 -3.38483500    5.12235700    5.47438800
 H                 -6.84708100    6.90114400    3.57478700
 H                  1.76490500    0.25615900    1.86154000
 H                  0.61193400    4.40872100    1.51762600
 H                  1.35931500    2.68433700    5.42110600
 C                 -0.84501300    9.13251100    5.70876600
 C                  0.34080700    9.98665300    5.87725500
 C                  1.62535700    9.57223500    5.46269200
 C                  0.20227500   11.24567500    6.51212400
 C                  2.73009200   10.42117200    5.61421900
 H                  1.75090900    8.58485400    5.00767400
 C                  1.31361200   12.08678700    6.67385000
 H                 -0.77813200   11.55363600    6.88926100
 C                  2.57910500   11.68397100    6.21380300
 H                  3.71520700   10.09060000    5.26755800
 H                  1.18792800   13.05888700    7.16278200
 H                  3.44515700   12.34260800    6.33669000
 C                 -2.03278600    9.28335200    5.19683700
 C                 -4.11070800   11.19741000    4.77524900
 H                 -4.72094900   11.09229000    3.86066500
 H                 -4.45436300   12.10544700    5.29877500
 C                 -2.64204100   11.32253600    4.43082000
 H                 -2.03099700   11.94538000    5.09419500
 C                 -2.00032872   11.14311406    3.21610688
 C                 -2.63907401   10.50660379    2.00977466
 H                 -3.70642066   10.27576438    2.13317200
 H                 -2.52257702   11.17398043    1.13603951
 H                 -2.11579117    9.56592807    1.75807237
 C                 -2.49716600    6.80741400    9.58353400
 H                 -1.61523200    7.03842000   10.19912300
 H                 -2.56856200    7.56928500    8.78595000
 H                 -3.39073500    6.90862700   10.22828100
 C                 -2.48352600    4.36310200   10.17239300
 H                 -2.54797100    3.31587400    9.83655000
 H                 -1.60205300    4.47339700   10.82393800
 H                 -3.37816800    4.55978500   10.79349400
 C                 -3.75967600    5.19184100    8.16164100
 H                 -3.85113900    5.97152100    7.38458300
 H                 -3.81458000    4.20074700    7.68080400
 H                 -4.63508800    5.29623400    8.83017200
 C                  0.82718400    5.95198000    9.84396400
 H                  0.72337800    6.97584600    9.44123700
 H                  0.10276000    5.81798900   10.66420000
 H                  1.83888200    5.86217900   10.28054000
 C                  0.76210600    3.46240900    9.34139400
 H                  1.72391900    3.37346200    9.88038700
 H                 -0.04163400    3.24367000   10.06384800
 H                  0.74829100    2.68958600    8.55465900
 C                  1.82829600    5.04979400    7.72261900
 H                  2.79043100    4.92598800    8.25380000
 H                  1.78982800    4.27840000    6.93261100
 H                  1.82735100    6.04791300    7.24910000
 C                 -3.44339600    8.84215300    5.18094800
 H                 -3.54658500    7.95190000    5.82542400
 H                 -3.76084900    8.53413400    4.16872400
 C                 -4.35812900    9.96954400    5.70463100
 C                 -0.57999273   11.60669530    3.01402290
 H                 -0.54568095   12.31732176    2.16541949
 H                 -0.16002980   12.09735619    3.90479683
 H                  0.07254213   10.75586043    2.74334111
 C                 -5.82773700    9.53458000    5.63542400
 H                 -6.47277900   10.38739700    5.94064400
 H                 -6.10279200    9.25479400    4.59403800
 C                 -3.96865800   10.31363900    7.16508800
 H                 -4.06445000    9.40623700    7.79209000
 H                 -2.91063400   10.63168400    7.20078700
 O                 -6.01780400    8.42601700    6.51530300
 O                 -4.76323500   11.38546000    7.67578100
 C                 -7.38672700    8.03449300    6.59506600
 H                 -7.78858500    7.72691000    5.60784100
 H                 -7.43322800    7.17802800    7.28553600
 H                 -8.02126600    8.85559300    6.99183900
 C                 -5.68192900   10.97308800    8.69109700
 H                 -6.34738900   10.15496100    8.34949200
 H                 -5.14880600   10.63050300    9.60287800
 H                 -6.28853800   11.85779200    8.94434500
 C                 -5.19658100    5.97097300    4.65058900
 H                 -5.77866300    5.78653600    5.55869000
 C                 -5.02518400    6.84286800    2.39187700
 H                 -5.47690000    7.33336800    1.52280700
 C                  1.17078300    2.32243400    1.54579500
 H                  1.11025700    2.22502000    0.45613500
 C                  1.61787600    1.35828600    3.73011000
 H                  1.90468900    0.50485000    4.35429700

52 56 F
52 58 F

C H P N O 0
6-31G*
****
Au 0
SDD 
****

Au 0
SDD

--link1-- 
%nproc=20
%Mem=40000MB
%Chk=IE9_NFA_B-TSInt1b-2b_2
#p geom=checkpoint guess=read SCRF=(PCM,Solvent=Dichloromethane) BP86/genecp opt=(ts,noeigentest,calcfc,modredundant) EmpiricalDispersion=GD3 freq=noraman nosymm
# scf(maxcyc=100) gfinput gfprint

opt freq

1 1

52 56 A
52 58 A

C H P N O 0
6-31G*
****
Au 0
SDD
****

Au 0
SDD



