%nproc=20
%Mem=40000MB
%Chk=IE14_TSInt1b-2b_F_A
#p SCRF=(PCM,Solvent=dichloroethane) BP86/genecp opt=(modredundant) temperature=294.15 EmpiricalDispersion=GD3 freq=noraman nosymm
# scf(maxcyc=100) gfinput gfprint

opt freq

1 1
 Au                 0.37444700    7.00984700    7.31968300
 C                 -2.00709100    4.50595400    7.44511600
 C                 -2.94934600    4.01662700    8.37297600
 C                 -4.28362700    3.77429900    8.01867500
 C                 -4.70351100    3.94132300    6.69320900
 C                 -3.77561900    4.38247000    5.74727300
 C                 -2.44425700    4.70299800    6.09482300
 C                 -1.62089100    5.28147000    4.99490100
 C                 -1.20513100    4.51838200    3.88358800
 C                 -0.40683100    5.08858900    2.88760800
 C                 -0.05582400    6.45904700    2.94246900
 C                 -0.56218500    7.24585300    3.99444500
 C                 -1.32435700    6.65408600    5.00739900
 C                  1.39286400    8.31904500    2.14341800
 C                  2.20727300    8.51049100    0.83430600
 C                  1.44648400    7.66592400   -0.23375300
 C                  0.27801900    6.99441900    0.52501700
 C                  2.19258500    8.44632400    3.42731700
 C                  2.36819400    9.72605200    3.97288800
 C                  3.06425800    9.90672000    5.17835300
 C                  3.59822300    8.80966100    5.85817500
 C                  3.41247800    7.52443300    5.32004500
 C                  2.72766200    7.33635600    4.11037300
 C                  3.15651000   11.30207900    5.74321800
 C                  3.99663100    6.35437900    6.06894800
 C                 -1.06264800    7.73647500    0.50058200
 C                 -2.21480900    7.05385100    0.94149600
 C                 -3.40989100    7.74250500    1.20139900
 C                 -3.50678400    9.11932000    0.96544300
 C                 -2.37348500    9.80200500    0.49517000
 C                 -1.16193900    9.12455500    0.27468100
 C                 -4.54171600    6.97868700    1.84588900
 C                 -2.46843700   11.28640600    0.23594000
 C                  0.74321300    3.30856400    7.55941600
 C                 -0.28036800    5.08774100    9.97383200
 P                 -0.26542000    4.86658700    8.04264700
 N                  0.78671400    6.99602500    1.93921600
 F                  3.84715000   11.35239200    6.91367000
 F                  1.90984000   11.80822300    5.97708000
 F                  3.76450100   12.15678700    4.86591900
 F                  5.35794900    6.34620900    6.01621200
 F                  3.56208300    5.15461100    5.59511100
 F                  3.66729000    6.39886800    7.40888000
 F                 -4.19501200    6.58615200    3.11629400
 F                 -4.85238200    5.84536300    1.16072200
 F                 -5.67923600    7.72494500    1.96061200
 F                 -1.24858200   11.89613700    0.29138700
 F                 -3.01054700   11.56938400   -0.97724600
 F                 -3.26381700   11.90524800    1.17604200
 H                  0.60739400    9.10989400    2.17831900
 H                  3.23076900    8.12745300    0.97850700
 H                  2.28109400    9.57925900    0.57466100
 H                  2.10480500    6.88488100   -0.64466800
 H                  1.08832600    8.26776400   -1.08445400
 H                  0.12111000    5.95208500    0.20278400
 H                 -2.66003900    3.82014000    9.40378200
 H                 -5.74297400    3.75159700    6.41116700
 H                 -4.09091000    4.55374000    4.71345800
 H                 -1.47536700    3.45877500    3.81926700
 H                 -0.04363400    4.47159600    2.05897000
 H                 -1.76463100    7.27620200    5.78571600
 H                 -0.35230700    8.31569300    4.05074200
 H                  1.95054100   10.59552600    3.45852600
 H                  2.58180300    6.33012000    3.71045500
 H                  4.12902400    8.95121500    6.80113800
 H                 -4.43628600    9.65643100    1.16863300
 H                 -0.29372700    9.69609600   -0.06479400
 H                 -2.17213500    5.97768800    1.12963900
 C                 -0.60244500    9.77514600    7.04729500
 C                  0.43728300    9.08964100    7.49380700
 C                  1.06381300    5.76328400   10.36820700
 H                  1.95070300    5.19998700   10.04488300
 H                  1.14114000    6.78484300    9.95699100
 H                  1.09738600    5.83897700   11.47146500
 C                 -0.41601700    3.78333000   10.79291500
 H                 -1.29822900    3.17535200   10.53694100
 H                  0.47546600    3.14379200   10.69389500
 H                 -0.50591500    4.05421600   11.86121000
 C                 -1.39720600    6.08732700   10.35979600
 H                 -1.30551300    7.02187800    9.78217300
 H                 -2.41441100    5.69404200   10.21911100
 H                 -1.28168600    6.34078400   11.42997900
 C                  2.13893200    3.36193200    8.21471300
 H                  2.66727400    4.30079500    7.98356100
 H                  2.09972200    3.22855300    9.30742600
 H                  2.74271900    2.52948000    7.80745800
 C                  0.00979400    2.00275800    7.93725500
 H                  0.59181400    1.15034100    7.53926100
 H                 -0.08522200    1.85954500    9.02388200
 H                 -0.99853100    1.95724900    7.49085100
 C                  0.91065200    3.34767300    6.02597100
 H                  1.64223700    2.57302100    5.72896000
 H                 -0.03819100    3.11848600    5.52208500
 H                  1.27314700    4.32239600    5.66141700
 C                 -5.29446800    3.48707900    9.09661900
 F                 -4.75088900    2.84751200   10.17008400
 F                 -6.33516000    2.73433500    8.64599700
 F                 -5.83090800    4.66402000    9.56736700
 C                  1.30735000    9.77513200    8.45643500
 C                  2.50787200    9.29289800    9.00466700
 C                  3.23641300   10.09823200    9.89424800
 H                  2.86644100    8.30195400    8.71115100
 C                  2.75901100   11.36856200   10.26186700
 H                  4.18339200    9.73294100   10.30464100
 H                  3.32998000   11.98843400   10.96017100
 C                  0.82993000   11.04720200    8.85862700
 C                  1.53471200   11.84937200    9.76072900
 H                  1.13888700   12.81589200   10.08400200
 C                 -1.79052400    9.75728600    6.26418800
 C                 -1.82457604   10.37202261    4.95261996
 C                 -2.99009615    9.28116566    6.84598339
 C                 -0.65953442   10.88723121    4.32218708
 C                 -3.09820942   10.57412770    4.31011791
 C                 -4.22964272    9.44517605    6.17396855
 C                 -0.75407123   11.61333462    3.13944131
 H                  0.31149590   10.72976366    4.80028145
 C                 -3.16351961   11.31756939    3.09616039
 C                 -4.27383706   10.08477991    4.94842171
 H                 -5.14943393    9.07374411    6.62210059
 C                 -2.01201922   11.84071528    2.52408451
 H                  0.14694477   12.02904078    2.67869765
 H                 -4.14548917   11.49494142    2.64384465
 H                 -5.23924581   10.23610175    4.45547071
 H                 -2.06094308   12.44005377    1.61046045
 O                 -2.87280429    8.70838954    8.07011862
 C                 -4.06935632    8.26407068    8.73742900
 H                 -4.63192958    7.53976931    8.12575435
 H                 -3.71777300    7.77104048    9.65383652
 H                 -4.72219337    9.11868418    8.98884172
 N                 -0.45945200   11.35020300    8.26801500
 H                 -1.21863100   11.04804800    8.90379500
 O                 -1.25842100   13.62060900    9.30832600
 O                  0.34907900   13.69585500    7.28960300
 C                 -5.49875500   12.63140900    4.11941700
 H                 -6.18087900   11.81992100    4.42189400
 H                 -6.09286400   13.56001600    4.02996300
 H                 -5.10278500   12.39771600    3.11568400
 S                 -0.82037500   13.12476700    7.98041300
 C                 -2.21621100   13.01424400    6.88224400
 C                 -3.38710700   12.36209200    7.30696000
 H                 -3.46989300   11.93117200    8.30911600
 C                 -4.45275300   12.25144900    6.40623500
 H                 -5.35098600   11.70302900    6.70683500
 C                 -4.37254200   12.80415500    5.11030900
 C                 -3.20326300   13.50594400    4.74250300
 H                 -3.13777600   13.95569400    3.74551100
 C                 -2.11005700   13.60038900    5.61106400
 H                 -1.18472000   14.09780300    5.30957600

69 130 F

C H P N S O F 0
6-31G*
****
Au 0
SDD 
****

Au 0
SDD


--link1--
%nproc=20
%Mem=40000MB
%Chk=IE14_TSInt1b-2b_F_A
#p geom=checkpoint guess=read SCRF=(PCM,Solvent=dichloroethane) BP86/genecp opt=(ts, noeigentest,calcfc,modredundant) temperature=294.15 EmpiricalDispersion=GD3 freq=noraman nosymm
# scf(maxcyc=100) gfinput gfprint

opt freq

1 1

69 130 A

C H P N S O F 0
6-31G*
****
Au 0
SDD 
****

Au 0
SDD



