%nproc=20
%Mem=40000MB
%Chk=IE9_NFA_A-TSInt1c-2c
#p SCRF=(PCM,Solvent=Dichloromethane) BP86/genecp opt=(modredundant) EmpiricalDispersion=GD3 freq=noraman nosymm 
# scf(maxcyc=100) gfinput gfprint

opt freq

1 1
 Au                 0.06262963    8.08547614    6.64412584
 C                 -2.73865137    5.92889414    6.52621684
 C                 -3.89436437    5.31381714    7.06918984
 C                 -4.75561937    4.53300914    6.28949384
 C                 -4.47772537    4.35578414    4.92621284
 C                 -3.34237437    4.95755914    4.37156084
 C                 -2.45118737    5.74581114    5.14119184
 C                 -1.74563763    6.78418186    2.96707816
 C                 -0.58679763    6.33936786    2.03010416
 C                  0.57211237    6.01183686    2.98591716
 C                 -0.15134363    5.38585186    4.19982816
 C                 -1.91403063    8.30208986    3.03088316
 C                 -3.09958263    8.88911986    2.55755816
 C                 -2.21146463   11.12023386    2.97033216
 C                 -0.88514963    9.14280286    3.49490716
 C                 -0.35537863    3.87889986    4.02725916
 C                  0.68883037    3.00497086    4.37692716
 C                 -0.64769663    1.07998586    3.70165116
 C                 -1.54747363    3.34034186    3.51544616
 C                 -1.05969237    5.93594514    9.03118984
 C                 -2.96221437    8.41831114    8.21841184
 P                 -1.76194637    7.03989214    7.63137984
 N                 -1.40060863    6.16696686    4.27247416
 H                 -2.69952363    6.35958586    2.59586216
 H                 -0.33396463    7.11295586    1.28845016
 H                 -0.89274563    5.43019386    1.48380116
 H                  1.10316137    6.92573686    3.30358116
 H                  1.31335337    5.32442386    2.54856716
 H                  0.44289437    5.54809886    5.11561916
 H                 -4.14056737    5.45769414    8.12218184
 H                 -5.63840537    4.07463714    6.74678484
 H                 -5.13855537    3.75043714    4.29682484
 H                 -3.11409937    4.81253414    3.31014584
 H                 -3.91609463    8.25654286    2.19268716
 H                  0.03492137    8.71178886    3.89387416
 H                 -2.33073363   12.20572686    2.95857516
 H                 -0.76411763    0.00063586    3.58289416
 H                 -2.38193363    3.99712686    3.25602016
 H                  1.62027437    3.40493786    4.79163316
 C                  2.63051283    8.24492114    5.66630365
 C                  1.75764563    9.16556714    5.94094784
 C                  1.63534088   10.62699203    5.93646911
 C                  0.44481827   11.24753760    5.48642610
 H                 -0.36190668   10.62681605    5.08580067
 C                  1.34035504   13.43530157    6.05603098
 H                  1.23225210   14.52353949    6.09163211
 C                 -2.11895437    9.61463114    8.72642184
 H                 -1.45971737    9.34404114    9.56704784
 H                 -1.49143737   10.04171214    7.92395584
 H                 -2.80830737   10.40554714    9.07705284
 C                 -3.94825137    8.00088414    9.32794984
 H                 -4.60001237    7.16328414    9.03247384
 H                 -3.42982037    7.73679314   10.26502184
 H                 -4.60891337    8.86006014    9.54914584
 C                 -3.73303637    8.85533714    6.94971684
 H                 -3.04332437    9.09359214    6.11816184
 H                 -4.43587437    8.07842414    6.60504884
 H                 -4.31279437    9.76770214    7.18245184
 C                 -0.34983337    6.84657714   10.05916184
 H                  0.35810163    7.54639514    9.57811384
 H                 -1.06966037    7.43209214   10.65650884
 H                  0.22549863    6.21268614   10.75909684
 C                 -2.09371237    5.04532714    9.75444484
 H                 -1.57618737    4.51862314   10.57798284
 H                 -2.92162437    5.61896814   10.19998384
 H                 -2.51176637    4.27539814    9.08582584
 C                 -0.02123437    5.01043214    8.34922884
 H                  0.41051463    4.33592714    9.11203484
 H                 -0.48518537    4.38319114    7.56691184
 H                  0.80735263    5.58019714    7.89302684
 C                  3.07934948    6.84857777    5.89491699
 H                  3.12997613    6.27876885    4.94884951
 H                  2.34584544    6.33362996    6.53721624
 C                  4.46389394    6.83797816    6.58891596
 C                  5.43676979    7.66044606    5.68764485
 H                  6.29008826    7.99398803    6.30207117
 H                  5.84068605    7.00501510    4.89502988
 C                  4.72953996    8.84815958    5.08137801
 H                  4.79886009    9.79673677    5.62540139
 C                  4.13786915    8.88818154    3.83306619
 C                  4.06768005    7.70940705    2.89538684
 H                  3.01880533    7.36800121    2.80046225
 H                  4.39547999    8.01269081    1.88444899
 H                  4.67274834    6.84632113    3.21176497
 C                  3.53418725   10.16274017    3.31005506
 H                  3.97862688   10.41083519    2.32740805
 H                  2.44479035   10.04209752    3.15816610
 H                  3.68015062   11.01307130    3.98932402
 C                  0.30184196   12.63810200    5.54353431
 H                 -0.61830145   13.10580713    5.17871804
 C                  2.52237533   12.83014520    6.51401894
 H                  3.33417338   13.44451741    6.91729196
 C                  2.66820317   11.43541919    6.46698384
 H                  3.57123316   10.96560665    6.86830263
 C                  4.33747803    7.50033322    7.98643112
 H                  3.98407341    8.54300384    7.86984129
 H                  3.57837902    6.95602892    8.58098373
 C                  4.97310483    5.39783420    6.71774091
 H                  5.04939908    4.93391944    5.70800746
 H                  5.99192654    5.40638939    7.16269768
 O                  5.59766766    7.53709287    8.65886682
 C                  5.67898285    6.63415503    9.76685610
 H                  6.71698039    6.67820556   10.13494285
 H                  4.99364766    6.93682315   10.58632615
 H                  5.43539580    5.59399603    9.47381270
 O                  4.06485994    4.66256057    7.53692019
 C                  4.47768086    3.30642835    7.70715199
 H                  3.72423934    2.81998690    8.34674037
 H                  4.53250276    2.77149270    6.73541978
 H                  5.47058970    3.24245740    8.20062795
 C                  0.54482137    1.61860386    4.20793416
 H                  1.37014336    0.96748637    4.40740755
 C                 -1.69089463    1.95231986    3.36030616
 H                 -2.58058895    1.55302346    2.91995812
 C                 -1.02864563   10.53729486    3.44760216
 H                 -0.20852595   11.16851856    3.71937478
 C                 -3.25127763   10.28521586    2.54335316
 H                 -4.18900530   10.71771082    2.26314802

40 78 F
40 80 F

C H P N O 0
6-31G*
****
Au 0
SDD 
****

Au 0
SDD

--link1-- 
%nproc=20
%Mem=40000MB
%Chk=IE9_NFA_A-TSInt1c-2c
#p geom=checkpoint guess=read SCRF=(PCM,Solvent=Dichloromethane) BP86/genecp opt=(ts,noeigentest,calcfc,modredundant) EmpiricalDispersion=GD3 freq=noraman nosymm
# scf(maxcyc=100) gfinput gfprint

opt freq

1 1

40 78 A
40 80 A

C H P N O 0
6-31G*
****
Au 0
SDD
****

Au 0
SDD



