%nproc=20
%Mem=40000MB
%Chk=IE9_NFA_A-TSInt1a-2a_2
#p SCRF=(PCM,Solvent=Dichloromethane) BP86/genecp opt=(modredundant) EmpiricalDispersion=GD3 freq=noraman nosymm 
# scf(maxcyc=100) gfinput gfprint

opt freq

1 1
 Au                -0.87617902    7.56054941    6.57440441
 C                 -1.42112102    3.96324641    6.60488141
 C                 -1.44930902    2.71892441    7.28525241
 C                 -1.88537502    1.54422441    6.66349441
 C                 -2.30257202    1.58910641    5.32456941
 C                 -2.29095902    2.80822541    4.64109841
 C                 -1.86561302    4.00969741    5.25684341
 C                 -3.20327402    5.54780441    3.85315541
 C                 -2.83580002    6.64552241    2.81474941
 C                 -1.29859702    6.79551041    2.89007041
 C                 -0.78280602    5.52191041    3.58352941
 C                 -4.25255702    5.91262341    4.89462541
 C                 -5.16077702    4.93783141    5.34892841
 C                 -6.17723702    6.54243941    6.87425241
 C                 -4.31439202    7.20383241    5.45459541
 C                 -0.41693702    4.36820441    2.65567241
 C                  0.70597398    3.57316041    2.96428241
 C                  0.25738198    2.11120341    1.07393641
 C                 -1.19196602    4.01731341    1.52829041
 C                  1.00362198    5.09612441    7.94209341
 C                 -1.96168000    5.50457300    9.13776000
 P                 -0.85193902    5.43581941    7.56183941
 N                 -1.90627702    5.24207541    4.52905141
 H                 -3.58048302    4.66162441    3.29974641
 H                 -3.33538502    7.60366141    3.02573741
 H                 -3.17081602    6.33435041    1.81143541
 H                 -1.04776002    7.64360041    3.54532341
 H                 -0.82294502    6.95928141    1.90943341
 H                  0.10579098    5.75028641    4.19859541
 H                 -1.14189802    2.66310541    8.33027041
 H                 -1.89828202    0.60448741    7.22483741
 H                 -2.63433602    0.67909541    4.81320741
 H                 -2.60332202    2.83656341    3.59367941
 H                 -5.11525202    3.92540941    4.92968141
 H                 -3.62279402    7.97771141    5.11352341
 H                 -6.92413002    6.78643541    7.63770641
 H                  0.51450998    1.23904941    0.46300741
 H                 -2.06326802    4.61862541    1.25110641
 H                  1.32532298    3.83565941    3.82989641
 C                 -0.88338002    9.48880441    5.66783841
 C                 -2.17017502   10.10628441    5.31407641
 C                 -3.12183102   10.35711441    6.33012041
 C                 -2.49330902   10.42050941    3.97586641
 C                 -4.36000502   10.93119641    6.01473541
 H                 -2.87778202   10.08663041    7.36333141
 C                 -3.74276502   10.98102841    3.66362741
 H                 -1.77090802   10.21482041    3.18010341
 C                 -4.67731602   11.24038641    4.67957541
 H                 -5.08539902   11.12567541    6.81170441
 H                 -3.98345402   11.21326641    2.62083241
 H                 -5.65174802   11.67410941    4.43228541
 C                  0.36105598    9.87578841    5.60841841
 C                  2.34387800   11.03183400    3.93474700
 H                  3.11654000   11.66962900    4.40051800
 H                  2.50237500   11.06756800    2.84320700
 C                  0.95724002   11.54736159    4.26423859
 H                  0.19576202   11.44601259    3.48148559
 C                  0.45481454   12.40308970    5.23625334
 C                  1.23840547   12.88715662    6.42966490
 H                  2.32826026   12.77570246    6.32188394
 H                  1.00660317   13.94767088    6.62974439
 H                  0.92339349   12.32747468    7.33175326
 C                 -1.93115600    6.96102700    9.66681000
 H                 -0.91228200    7.30679900    9.90978800
 H                 -2.37001500    7.66276100    8.93459200
 H                 -2.53685800    7.01436900   10.59131400
 C                 -1.56485000    4.56186900   10.29137600
 H                 -1.55776400    3.49873200   10.00444600
 H                 -0.58287000    4.82041600   10.72246400
 H                 -2.31507600    4.66999900   11.09728700
 C                 -3.39133800    5.19430400    8.64477700
 H                 -3.65985100    5.81904500    7.77573900
 H                 -3.51512900    4.13713700    8.35904500
 H                 -4.10718400    5.42012400    9.45680600
 C                  1.52717798    6.23081341    8.85098941
 H                  1.31110198    7.23165841    8.43386841
 H                  1.09645098    6.17834641    9.86554741
 H                  2.62447298    6.13305741    8.94937541
 C                  1.30973898    3.73010941    8.59414941
 H                  2.40023798    3.67266841    8.77094241
 H                  0.81295398    3.59157841    9.56654141
 H                  1.04230398    2.89008041    7.93304541
 C                  1.72726798    5.13619841    6.57617641
 H                  2.81341898    5.00015641    6.73254841
 H                  1.37248798    4.32540141    5.91625341
 H                  1.59013298    6.09629441    6.05020241
 C                  1.77667100    9.46800700    5.77194200
 H                  1.80759600    8.43629500    6.15854300
 H                  2.28989100   10.09980700    6.52066300
 C                  2.51492600    9.56032500    4.41895500
 C                 -0.92788857   12.98369671    5.11289114
 H                 -0.82692473   14.07249847    4.93473570
 H                 -1.50827329   12.54662412    4.28800859
 H                 -1.49820329   12.86737128    6.05139059
 C                  3.99176700    9.19876700    4.60555900
 H                  4.52341800    9.29279400    3.63429500
 H                  4.47140400    9.89632300    5.32882700
 C                  1.84934700    8.59462000    3.40681200
 H                  1.81546500    7.57887800    3.84248800
 H                  0.80841000    8.91647700    3.22887200
 O                  4.04940100    7.85670000    5.09283600
 O                  2.52817900    8.59472400    2.15076300
 C                  5.38811500    7.40004700    5.27693800
 H                  5.93882200    8.02937100    6.00758600
 H                  5.32029700    6.37061200    5.66364500
 H                  5.95214400    7.39409100    4.32025600
 C                  3.18046500    7.35061300    1.86819900
 H                  3.91283900    7.08444200    2.65605000
 H                  2.44668600    6.52279400    1.77293200
 H                  3.70421200    7.47885000    0.90694600
 C                 -5.26918502    7.52151141    6.43226341
 H                 -5.30146202    8.53741341    6.84288641
 C                 -6.11689702    5.24744241    6.33263441
 H                 -6.81676802    4.47612041    6.67286941
 C                  1.04550898    2.45613941    2.18366041
 H                  1.92435998    1.85575641    2.44398341
 C                 -0.86091202    2.89850641    0.74765541
 H                 -1.47701402    2.64368441   -0.12194659

52 56 F
52 58 F

C H P N O 0
6-31G*
****
Au 0
SDD 
****

Au 0
SDD

--link1-- 
%nproc=20
%Mem=40000MB
%Chk=IE9_NFA_A-TSInt1a-2a_2
#p geom=checkpoint guess=read SCRF=(PCM,Solvent=Dichloromethane) BP86/genecp opt=(ts,noeigentest,calcfc,modredundant) EmpiricalDispersion=GD3 freq=noraman nosymm
# scf(maxcyc=100) gfinput gfprint

opt freq

1 1

52 56 A
52 58 A

C H P N O 0
6-31G*
****
Au 0
SDD
****

Au 0
SDD



