%nproc=20
%Mem=40000MB
%Chk=IE9_Cy_OMe_4+2_TS100_200
#p SCRF=(PCM,Solvent=Dichloromethane) BP86/genecp opt=(modredundant) EmpiricalDispersion=GD3 freq=noraman nosymm 
# scf(maxcyc=100) gfinput gfprint

opt freq

1 1
 Au                -1.13451300    6.56907800    7.36879800
 C                 -2.21161500    3.16950400    7.50403100
 C                 -2.79427100    2.14522900    8.28932400
 C                 -3.57954200    1.12964100    7.73031300
 C                 -3.80084200    1.11225400    6.34627800
 C                 -3.20578200    2.09353700    5.54530000
 C                 -2.40172600    3.12358400    6.09024700
 C                 -1.74567100    4.00942400    5.08151000
 C                 -0.78855300    3.43154100    4.21797400
 C                 -0.19893900    4.17651900    3.19286200
 C                 -0.57213500    5.52109200    2.98417000
 C                 -1.52778100    6.10603900    3.83629700
 C                 -2.11242200    5.35393600    4.86803600
 C                  0.10491900    7.65286500    1.85580300
 C                  0.51833300    7.98051700    0.38891300
 C                  0.05832700    6.75601200   -0.45468300
 C                 -0.65341200    5.81017400    0.53536800
 C                  0.54453600    3.69066300    8.54938000
 C                 -2.02705900    4.82007200   10.08244800
 P                 -1.19171600    4.45752000    8.37094100
 N                 -0.01877800    6.18723600    1.84732000
 H                 -0.87137400    8.15289900    2.05868400
 H                  1.61073600    8.11130300    0.32477200
 H                  0.05220000    8.92346900    0.05973900
 H                  0.93163600    6.23691800   -0.88003500
 H                 -0.59619000    7.03363700   -1.29646000
 H                 -0.41616400    4.75137700    0.33414300
 H                 -2.62794200    2.12844500    9.36650300
 H                 -4.01294200    0.36102700    8.37836300
 H                 -4.42276500    0.33508600    5.88969500
 H                 -3.36480200    2.08628400    4.46316900
 H                 -0.50814900    2.38175100    4.35713500
 H                  0.54326400    3.72223500    2.52778900
 H                 -2.93598500    5.78693800    5.44460100
 H                 -1.86528100    7.13087100    3.66588400
 C                 -1.41231400    8.63104400    6.92539500
 C                 -2.08873300    8.99375800    5.67251200
 C                 -3.38736900    8.52092700    5.37409200
 C                 -1.41780000    9.80888800    4.73687400
 C                 -4.00439100    8.87032200    4.16429500
 H                 -3.90363000    7.88423300    6.10101500
 C                 -2.04250600   10.15824600    3.53047900
 H                 -0.40822200   10.16057300    4.95937100
 C                 -3.33424000    9.69174500    3.23947000
 H                 -5.00532200    8.49463900    3.92936600
 H                 -1.51784100   10.80076600    2.81534000
 H                 -3.81184600    9.96399400    2.29705100
 C                 -0.93294000    9.30764100    7.92592300
 C                  0.40641100   11.72768300    8.63720600
 H                  0.11826100   12.28239100    9.54780700
 H                  1.18091700   12.32276200    8.12399900
 C                 -0.78963800   11.55618100    7.72647400
 H                 -0.60127100   11.61375100    6.64905900
 C                 -2.11411700   11.56420600    8.13237900
 C                 -2.55432700   11.59831900    9.57277100
 H                 -1.72824500   11.66117100   10.29650500
 H                 -3.22393200   12.46340800    9.73536200
 H                 -3.15192300   10.69594900    9.80278700
 C                 -1.51581800    6.19619000   10.59122900
 H                 -0.41862800    6.24440600   10.67746400
 H                 -1.84721600    7.02014100    9.93578800
 H                 -1.94015700    6.37295100   11.59752300
 C                 -1.74965400    3.79144900   11.20280700
 H                 -2.03801800    2.75939700   10.95350300
 H                 -0.68834500    3.78752600   11.50151000
 H                 -2.33908300    4.08409300   12.09150300
 C                 -3.54596000    4.95716800    9.81772500
 H                 -3.74304900    5.66009200    8.98656600
 H                 -4.03040500    3.99738700    9.57851100
 H                 -4.02770500    5.36488300   10.72591100
 C                  1.41245900    4.62188100    9.42256200
 H                  1.41315400    5.65671600    9.03697700
 H                  1.08708900    4.63462900   10.47607100
 H                  2.45577800    4.25542100    9.40340900
 C                  0.51193000    2.26026000    9.12763800
 H                  1.54210600    1.85752700    9.11888200
 H                  0.15183200    2.22479900   10.16733300
 H                 -0.11536000    1.58871100    8.51679100
 C                  1.13269100    3.63827900    7.12013300
 H                  2.16541900    3.24610300    7.17723200
 H                  0.55292200    2.96625400    6.46708700
 H                  1.17500500    4.63409500    6.65032800
 C                 -0.12969000    9.33567000    9.16623600
 H                  0.27632900    8.32471000    9.34356600
 H                 -0.76312500    9.58489400   10.03781800
 C                  1.02962700   10.35504000    9.04194100
 C                 -3.23751100   11.60257300    7.13046900
 H                 -3.84083300   12.51441300    7.30482000
 H                 -2.88298400   11.60349400    6.08921200
 H                 -3.91795400   10.74295400    7.26711300
 C                  1.75507200   10.49194500   10.38443200
 H                  2.53948200   11.27628300   10.30237300
 H                  1.03773100   10.81979800   11.17111800
 C                  1.98704400    9.86177000    7.93264500
 H                  2.34247200    8.84366000    8.16982200
 H                  1.42498900    9.80561400    6.98223700
 O                  2.32665900    9.23078400   10.72733500
 O                  3.08700100   10.75192700    7.71799200
 C                  3.03523600    9.28537800   11.96598800
 H                  2.36762100    9.57121500   12.80620500
 H                  3.43848700    8.27695700   12.14974600
 H                  3.87508100   10.01105200   11.92172100
 C                  4.32535800   10.27408200    8.26565000
 H                  4.25515700   10.07986800    9.35241800
 H                  4.64662500    9.33844100    7.76550000
 H                  5.07335800   11.06069900    8.07761200
 C                  1.10015666    8.16666369    2.91273862
 C                  2.39568176    7.38743023    2.81184818
 C                  1.33463164    9.65019049    2.71096429
 H                  0.63957067    7.99571816    3.92110736
 C                  3.43458515    7.91622074    3.77963252
 H                  2.79199326    7.45770491    1.76477486
 H                  2.20006878    6.30459693    3.02595040
 C                  2.37295818   10.17913214    3.67931503
 H                  1.67797785    9.83366346    1.65891965
 H                  0.37138315   10.20558257    2.85285680
 C                  3.66835734    9.39969315    3.58003255
 H                  4.39808945    7.36158048    3.63638770
 H                  3.09227038    7.73105856    4.83173243
 H                  2.56893597   11.26180731    3.46494830
 H                  1.97562069   10.10943314    4.72608871
 H                  4.39127018    9.77296143    4.35117693
 H                  4.13104565    9.57197838    2.57276732
 C                 -2.18235124    5.95771509    0.64571483
 C                 -2.65821841    7.03877343   -0.30330164
 C                 -2.84426400    4.62904679    0.34066534
 H                 -2.41707386    6.25770873    1.70074016
 C                 -4.16832543    7.16082020   -0.28821649
 H                 -2.31421945    6.79885612   -1.34371900
 H                 -2.19949081    8.02008068   -0.01479301
 C                 -4.35439451    4.75093894    0.35655792
 H                 -2.50969572    4.26863660   -0.66755857
 H                 -2.52111274    3.86613763    1.09563843
 C                 -4.83107176    5.83260465   -0.59118636
 H                 -4.49114087    7.92274077   -1.04435977
 H                 -4.50290282    7.52309820    0.71935052
 H                 -4.81313795    3.76981297    0.06760777
 H                 -4.69776741    4.98992896    1.39744648
 H                 -5.94376048    5.94069886   -0.50851059
 H                 -4.59899736    5.53236890   -1.64681218

48 52 F

C H P O N 0
6-31G*
****
Au 0
SDD 
****

Au 0
SDD

--link--
%nproc=20
%Mem=40000MB
%Chk=IE9_Cy_OMe_4+2_TS100_200
#p SCRF=(PCM,Solvent=Dichloromethane) BP86/genecp opt=(ts, noeigentest,calcfc,modredundant) EmpiricalDispersion=GD3 freq=noraman nosymm 
# scf(maxcyc=100) gfinput gfprint

opt freq

1 1

48 52 A

C H P O N 0
6-31G*
****
Au 0
SDD 
****

Au 0
SDD


