%nprocshared=20
%mem=41GB
#p opt=(maxstep=5,calcfc,ts,noeigentest) freq=noraman nosymm b3lyp genecp scrf=(pcm,solvent=dichloromethane) empiricaldispersion=gd3 scf=(xqc,maxcyc=1024)

opt freq ts

1 1
 C                 -0.24707017    0.56643958   -0.10955621
 C                  0.93845522    0.09565960    0.23719852
 C                  3.52049485   -0.13956378    0.16762701
 H                  3.93771133    0.06903877    1.15662622
 H                  4.35172046   -0.17133845   -0.54000329
 C                  2.49524648    0.92144438   -0.22719012
 H                  2.40752848    1.09664703   -1.29688319
 C                  2.30797402    2.04680015    0.62647301
 C                  1.42616907   -1.16651146    0.88823830
 H                  0.69515909   -1.96553010    0.74863315
 H                  1.56679852   -1.01335311    1.96592931
 C                  2.78754667   -1.50166280    0.24587181
 O                  3.04726238   -3.73122590    0.97828513
 O                  3.76546048   -2.35198122   -1.73083095
 C                  3.67323838   -4.76886360    1.76585273
 H                  3.58337116   -4.53859288    2.83017952
 H                  3.13407586   -5.68305697    1.52152336
 H                  4.72883068   -4.85785350    1.49839152
 C                  3.71495019   -2.94154243   -3.04860303
 H                  3.20499269   -3.90709493   -3.00837112
 H                  3.18745015   -2.27802632   -3.73816095
 H                  4.75389606   -3.06593148   -3.35090261
 H                 -0.30142580    1.58575434   -0.49943068
 C                  3.56454464   -2.50082354    1.10784828
 C                  2.58154181   -2.10560944   -1.15086023
 O                  1.50772155   -2.32483940   -1.67118438
 O                  4.48804288   -2.21846093    1.84120005
 H                  2.59142523    1.91020250    1.66945041
 C                  1.71764320    3.28397675    0.29399998
 C                  1.47332450    4.22813950    1.32998621
 C                  1.33052974    3.63343621   -1.03544709
 C                  0.87760316    5.44618668    1.07557755
 H                  1.76047626    3.97909449    2.34750099
 C                  0.73170002    4.84203637   -1.29808612
 H                  1.51658365    2.94842228   -1.85492945
 C                  0.49614339    5.76384829   -0.24824912
 H                  0.70614643    6.14243997    1.88656235
 H                  0.43502707    5.12201084   -2.30281133
 O                 -0.08633308    6.90725440   -0.61311935
 C                 -0.36071369    7.91621104    0.37386062
 H                 -0.82557959    8.73543804   -0.17317426
 H                 -1.05136951    7.53667069    1.13356922
 H                  0.56631607    8.26055953    0.84315679
 Au                -1.98106912   -0.55397137   -0.02095767
 P                 -3.95758825   -1.81954083    0.07989129
 C                 -5.49575792   -0.81653810    0.13680014
 C                 -4.20663611   -2.95480474   -1.34296032
 C                 -4.06802622   -2.90710299    1.55659348
 H                 -5.55860384   -0.19398167   -0.76032863
 H                 -6.37401171   -1.46848074    0.18935740
 H                 -5.47338637   -0.16481981    1.01492539
 H                 -4.24155150   -2.37472000   -2.26951399
 H                 -5.14219013   -3.51200321   -1.22632213
 H                 -3.36964411   -3.65647210   -1.40056025
 H                 -5.00459986   -3.47422674    1.54414845
 H                 -3.22244922   -3.60088728    1.56142061
 H                 -4.02505410   -2.29596826    2.46264738

C H P O 0
6-31G*
****
Au 0
SDD
****

Au 0
SDD


