%nprocshared=20
%mem=41GB
#p opt=modredundant b3lyp genecp scrf=(solvent=dichloromethane,pcm) nosymm empiricaldispersion=gd3 scf=(xqc,maxcyc=1024)

opt freq

1 1
 C                 -0.16024900    2.14873300    0.22700500
 C                  1.11955431    1.98571094    0.73389474
 C                  3.21164361    1.25381043   -0.51573284
 H                  4.16548689    1.50497533   -0.04299021
 H                  3.40814743    0.99283589   -1.55559186
 C                  2.27191199    2.44053317   -0.42180194
 H                  1.86467994    2.85826068   -1.33747354
 C                  2.14005483    3.20129381    0.80360432
 C                  1.64787057    0.68681191    1.33117483
 H                  0.83179677    0.00895052    1.58061334
 H                  2.21147975    0.89118316    2.24665416
 C                  2.58483172    0.05844048    0.26179076
 O                  3.16316173   -1.93745390    1.38856693
 O                  2.55297007   -1.25345739   -1.71038575
 C                  4.07448911   -2.80757986    2.09975804
 H                  4.44620285   -2.30675307    2.99661554
 H                  3.48797826   -3.68671835    2.36208361
 H                  4.91377101   -3.07779539    1.45488505
 C                  1.95491255   -2.19809705   -2.62732136
 H                  1.71144610   -3.12455338   -2.10179577
 H                  1.04793432   -1.77478094   -3.06520382
 H                  2.70893142   -2.37377791   -3.39296373
 H                 -0.33448962    3.12457747   -0.23216584
 C                  3.67574916   -0.78156885    0.94919009
 C                  1.79824325   -0.88560817   -0.66929973
 O                  0.66526935   -1.28066879   -0.47997533
 O                  4.82320195   -0.42943936    1.11527534
 H                  2.87777587    2.98258054    1.57430033
 C                  1.64338667    4.63062234    0.80430869
 H                  1.12274951    4.86186054    1.73800519
 H                  2.50599800    5.29922515    0.71406624
 H                  0.97415067    4.84132398   -0.03436273
 Au                -1.66585050    0.67666457    0.09180644
 P                 -3.38420220   -0.93824561   -0.08366096
 C                 -5.10563563   -0.29598839    0.13161146
 C                 -3.31984943   -1.74646188   -1.80898128
 C                 -3.10420701   -2.17907908    1.35807539
 C                 -6.16551564   -1.22142093    0.21913583
 C                 -5.39876493    1.07900398    0.30743158
 C                 -4.45262660   -2.74156288   -2.12003841
 C                 -1.95442173   -2.44452961   -1.96694464
 C                 -3.41108194   -0.58316650   -2.82092299
 C                 -1.58185686   -2.39237556    1.53858998
 C                 -3.64322406   -1.48490235    2.62811961
 C                 -3.76282650   -3.56142346    1.19849064
 C                 -7.47287334   -0.82675382    0.48863805
 H                 -5.97231682   -2.27622361    0.08217703
 C                 -6.72395971    1.45634312    0.59313200
 C                 -4.43116204    2.21512292    0.18818751
 H                 -5.43052272   -2.25307331   -2.12690349
 H                 -4.28594092   -3.15372766   -3.12302775
 H                 -4.48614172   -3.58203328   -1.42352685
 H                 -1.83453033   -2.75898292   -3.01096928
 H                 -1.12355410   -1.77431418   -1.71909527
 H                 -1.87687455   -3.34050222   -1.34423485
 H                 -4.35847159   -0.04190434   -2.72848700
 H                 -2.59081660    0.13072018   -2.69847553
 H                 -3.35772938   -0.99096043   -3.83786216
 H                 -1.10363023   -2.80089170    0.64503389
 H                 -1.06879567   -1.46229609    1.80303037
 H                 -1.42622112   -3.10732542    2.35633721
 H                 -3.35319861   -2.07673934    3.50488616
 H                 -3.21881658   -0.48082093    2.74770921
 H                 -4.73333673   -1.39956683    2.62148203
 H                 -3.56111005   -4.14778011    2.10366193
 H                 -4.84777355   -3.51149693    1.08823727
 H                 -3.34880799   -4.11882465    0.35359402
 C                 -7.75371729    0.52469385    0.68755341
 H                 -8.26012888   -1.57230029    0.54864599
 H                 -6.93806030    2.51230596    0.73029598
 C                 -4.03937148    2.67497491   -1.07534920
 C                 -4.05328702    2.93003023    1.33443886
 H                 -8.76559117    0.85288560    0.90703911
 C                 -3.27071190    3.83933978   -1.21552009
 H                 -4.36816442    2.12464060   -1.94740832
 C                 -3.28718603    4.09849878    1.23541786
 H                 -4.38718900    2.56369078    2.29856889
 C                 -2.91167219    4.52511676   -0.04762459
 H                 -3.02672118    4.24624872   -2.17457881
 H                 -3.02534157    4.69581142    2.08368379
 H                 -2.34481130    5.44450839   -0.13990550

1 F
2 F
3 F
4 F
5 F
6 F
7 F
8 F
9 F
10 F
11 F
12 F
13 F
14 F
15 F
16 F
17 F
18 F
19 F
20 F
21 F
22 F
23 F
24 F
25 F
26 F
27 F
28 F
29 F
30 F
31 F
32 F

C H P O 0
6-31G*
****
Au 0
SDD
****

Au 0
SDD



