%nprocshared=20
%mem=41GB
#p opt freq=noraman nosymm b3lyp 6-31G(d) scrf=(pcm,solvent=dichloromethane) empiricaldispersion=gd3 scf=(xqc,maxcyc=1024)

opt freq

0 1
 C                 -0.24392388   -0.40902261   -3.29703950
 C                 -0.22279681   -0.70333403   -1.87888702
 C                 -0.53348233   -1.83304340    0.19298258
 H                  0.21822099   -2.58816690    0.45763059
 H                 -1.42762392   -2.06707461    0.78135245
 C                 -0.77883117   -1.78029528   -1.28895739
 H                 -1.31764312   -2.56208015   -1.81671684
 C                  0.35907750    0.65949865   -3.86720390
 C                  0.49000563    0.16246995   -0.85712430
 H                  0.23501014    1.22217209   -0.93952687
 H                  1.57845284    0.07807369   -0.97269661
 C                  0.02059577   -0.41022435    0.51332381
 O                  1.50664203    0.81628103    1.87131773
 O                 -1.44980382    0.00993861    2.31611541
 C                  2.60834507    0.93984853    2.79425612
 H                  3.51672681    0.51554505    2.35907344
 H                  2.72695332    2.00935381    2.96481692
 H                  2.37801024    0.42325117    3.72953888
 C                 -2.51487226    0.72762129    2.97210238
 H                 -2.23940778    1.77716798    3.10352469
 H                 -3.43326543    0.66438631    2.38289264
 H                 -2.64348348    0.23977338    3.93777936
 H                 -0.78764132   -1.12231349   -3.91515704
 C                  1.17491584   -0.43755112    1.51387832
 C                 -1.10783180    0.45354348    1.09278343
 O                 -1.64735980    1.38764137    0.53900864
 O                  1.75224328   -1.42818463    1.91003107
 H                  0.89460661    1.35161690   -3.21822445
 C                  0.38676283    1.03292847   -5.36098558
 H                  0.92370949    1.94946756   -5.48961054
 H                  0.87082030    0.25533811   -5.91410545
 H                 -0.61500546    1.15344062   -5.71712759



