%nprocshared=20
%mem=41GB
#p opt=maxstep=17 freq=noraman nosymm b3lyp genecp scrf=(pcm,solvent=dichloromethane) empiricaldispersion=gd3 scf=(xqc,maxcyc=1024)

opt freq

1 1
 C                  2.38111779    0.53759399   -0.71178907
 C                  1.78582200   -0.78166551   -0.86803746
 C                  0.84830768   -2.70796086   -1.87787878
 H                  1.55005091   -3.54109439   -2.01409764
 H                  0.02102152   -2.87628600   -2.57434299
 C                  1.51796975   -1.37236926   -2.04965389
 H                  1.75802995   -0.95211708   -3.02155382
 C                  2.76020137    1.09730482    0.50273202
 C                  1.35218973   -1.66526766    0.28759370
 H                  0.85876922   -1.12315824    1.09784244
 H                  2.21692708   -2.18965499    0.71418660
 C                  0.37724577   -2.66435411   -0.39293149
 O                 -0.14707968   -3.95647286    1.50462159
 O                 -1.91846137   -3.00231880   -0.84408897
 C                 -0.15683356   -5.17896063    2.27419339
 H                  0.86590595   -5.51684715    2.45825439
 H                 -0.65468294   -4.92890610    3.21018773
 H                 -0.70715951   -5.95626081    1.73853426
 C                 -3.30840677   -2.60953379   -0.86273607
 H                 -3.64045850   -2.35016897    0.14522806
 H                 -3.44748021   -1.75344789   -1.52784319
 H                 -3.84928335   -3.47715245   -1.23765025
 H                  2.66326632    1.03596205   -1.63784383
 C                  0.41583430   -4.03189845    0.28723236
 C                 -1.05639945   -2.11459311   -0.33608057
 O                 -1.37993746   -1.01759260    0.08008032
 O                  0.91502335   -5.03550089   -0.17398269
 H                  2.61537969    0.49430953    1.39888919
 Au                 0.48034125    1.73285915    0.05510763
 P                 -1.72037895    2.42492807    0.17600716
 C                 -2.67974777    1.83052437   -1.26705699
 C                 -2.58021907    1.73013634    1.63620188
 C                 -1.97340933    4.23794243    0.24629780
 H                 -2.61069949    0.74028503   -1.29105090
 H                 -3.72662624    2.13688233   -1.17367615
 H                 -2.25744992    2.24151519   -2.18775965
 H                 -2.51359842    0.64076141    1.58474146
 H                 -3.63023802    2.04080438    1.63290607
 H                 -2.09791605    2.08107423    2.55236684
 H                 -3.04349586    4.46454499    0.29592573
 H                 -1.47304293    4.64176976    1.13077405
 H                 -1.54351609    4.70098980   -0.64616416
 C                  3.56525284    2.39226103    0.71855729
 H                  3.63890341    2.59599246    1.76639749
 H                  4.54643966    2.27482268    0.30821516
 H                  3.06976914    3.20570988    0.23101564

C H P O 0
6-31G*
****
Au 0
SDD
****

Au 0
SDD




