%nprocshared=20
%mem=41GB
#p opt=(maxstep=17,calcfc) freq=noraman nosymm b3lyp genecp scrf=(pcm,solvent=dichloromethane) empiricaldispersion=gd3 scf=(xqc,maxcyc=1024)

opt freq

1 1
 C                 -0.28277663    1.71707846    0.27635102
 C                 -1.30343187    0.80721074    0.05882696
 C                 -2.71690000    0.24104934    1.85462303
 H                 -2.98461519    1.22281193    2.25636110
 H                 -2.99303802   -0.51305381    2.59355613
 C                 -1.24744757    0.20371475    1.41780870
 H                 -0.84902892   -0.81774515    1.39135889
 C                 -0.07606305    1.24291745    1.74283964
 C                 -2.49760989    0.34642723   -0.69805859
 H                 -2.27464170   -0.59700840   -1.21035789
 H                 -2.89770817    1.04573654   -1.43412081
 C                 -3.50329772    0.02945270    0.49299227
 O                 -5.52607156    0.55143373   -0.59592690
 O                 -4.93747450   -1.64999482    1.32145496
 C                 -6.69680192    1.35729859   -0.85958852
 H                 -6.40141386    2.31040363   -1.30480486
 H                 -7.29259858    0.77809604   -1.56337792
 H                 -7.24935391    1.53444136    0.06542577
 C                 -5.47058881   -2.99273929    1.36693117
 H                 -5.92128827   -3.24929201    0.40527191
 H                 -4.67633012   -3.70522291    1.60180108
 H                 -6.22244099   -2.97871899    2.15473449
 H                  0.01790487    2.62732536   -0.24247013
 C                 -4.70528514    0.97260176    0.37132557
 C                 -3.98441258   -1.42657062    0.40772907
 O                 -3.54223838   -2.27074523   -0.34262328
 O                 -4.86678905    1.99643604    1.00835975
 H                 -0.39370443    1.98086753    2.48578667
 C                  1.26742795    0.68129492    2.11771098
 C                  2.43445374    1.42132102    1.90733979
 C                  1.38829472   -0.58923704    2.70801684
 C                  3.69143604    0.92916640    2.27013375
 H                  2.36955958    2.40653468    1.45094882
 C                  2.62806020   -1.09427240    3.07583345
 H                  0.49953834   -1.19203731    2.88018901
 C                  3.79236815   -0.33760051    2.85969839
 H                  4.57170910    1.53408993    2.08792154
 H                  2.72350196   -2.07543788    3.53046463
 O                  4.95826645   -0.92231785    3.25205062
 C                  6.17431885   -0.20526888    3.05362981
 H                  6.96706349   -0.85056523    3.43498591
 H                  6.35019177   -0.00218175    1.98963171
 H                  6.17651120    0.74128162    3.60885759
 Au                 1.04339415    0.44129865   -1.11982193
 P                  2.48021957   -0.63562105   -2.57059811
 C                  4.24581143   -0.18330645   -2.39091129
 C                  2.40156741   -2.45724027   -2.41177390
 C                  2.03123758   -0.29206931   -4.31136806
 H                  4.58661796   -0.42985978   -1.38157375
 H                  4.84464619   -0.73480335   -3.12293698
 H                  4.36742515    0.89108960   -2.55400372
 H                  2.69442282   -2.75965468   -1.40294099
 H                  3.07051655   -2.92097159   -3.14378837
 H                  1.37166139   -2.76724882   -2.60194827
 H                  2.68000983   -0.86192305   -4.98470423
 H                  0.98925087   -0.58761544   -4.45597706
 H                  2.13649070    0.77651768   -4.51644761

C H P O 0
6-31G*
****
Au 0
SDD
****

Au 0
SDD


