%nprocshared=20
%mem=41GB
#p opt=(calcfc,ts,noeigentest,maxstep=7) freq=noraman nosymm b3lyp genecp scrf=(pcm,solvent=dichloromethane) empiricaldispersion=gd3 scf=(xqc,maxcyc=1024)

opt freq

1 1
 C                 -0.27750747    1.36137481   -1.17402689
 C                  0.62709136    0.66300239   -0.62643734
 C                  2.79890603   -1.13288232   -1.42709137
 H                  3.80718527   -1.17464799   -1.01663554
 H                  2.75286639   -1.89454429   -2.20813688
 C                  2.49801572    0.21745283   -2.01817501
 H                  1.89047340    0.21280894   -2.91881066
 C                  2.98618118    1.43849536   -1.63799500
 C                  1.21648634   -0.24144676    0.36398696
 H                  0.43422616   -0.50439205    1.08228681
 H                  2.00400175    0.28532771    0.91398147
 C                  1.79230232   -1.52050912   -0.28986281
 O                  1.61743454   -2.92397856    1.60834421
 O                  1.09810593   -3.48864272   -1.40539758
 C                  2.15754762   -3.68132587    2.71772985
 H                  2.73727595   -3.02497641    3.37053828
 H                  1.29119836   -4.08309780    3.24070218
 H                  2.79461807   -4.48602467    2.34421981
 C                  0.10462594   -4.40447294   -1.91954977
 H                 -0.54976463   -4.73828604   -1.11084424
 H                 -0.48899233   -3.91691748   -2.69634586
 H                  0.66840809   -5.24005047   -2.33153240
 H                 -0.26644446    2.03761590   -2.01809895
 C                  2.50966354   -2.32513365    0.81254846
 C                  0.63227128   -2.37800604   -0.82479886
 O                 -0.54481654   -2.09568504   -0.72623399
 O                  3.71101450   -2.36797277    0.97308989
 H                  2.64019441    2.26667348   -2.25490765
 C                  3.87403340    1.86974981   -0.56629528
 C                  4.15214170    3.25182365   -0.49166328
 C                  4.47760051    1.04011220    0.41302439
 C                  4.97806762    3.79682012    0.48505682
 H                  3.70743104    3.91922073   -1.22543685
 C                  5.29843766    1.57079998    1.39333953
 H                  4.31228141   -0.02860958    0.42964972
 C                  5.56042432    2.95226691    1.44314921
 H                  5.15949204    4.86470075    0.49411513
 H                  5.75499683    0.93035854    2.14108631
 Au                -2.13214995    0.88366407   -0.24396195
 P                 -4.21284439    0.42563377    0.68533012
 C                 -5.48099662    1.70082680    0.32563091
 C                 -4.94526798   -1.15241171    0.10317266
 C                 -4.17880774    0.28564732    2.51451708
 H                 -5.60999717    1.79190848   -0.75646418
 H                 -6.43481621    1.42068481    0.78442092
 H                 -5.15366016    2.66503662    0.72427313
 H                 -5.07139277   -1.11713431   -0.98232833
 H                 -5.91823235   -1.31220573    0.57943175
 H                 -4.27424117   -1.97882357    0.35327493
 H                 -5.18435213    0.07882097    2.89522397
 H                 -3.50572697   -0.52639949    2.80358560
 H                 -3.80987979    1.22030712    2.94556758
 H                  6.20415535    3.27580778    2.23424444

C H P O 0
6-31G*
****
Au 0
SDD
****

Au 0
SDD


