%nprocshared=20
%mem=41GB
#p opt=(calcfc,ts,noeigentest,maxstep=7) freq=noraman nosymm b3lyp genecp scrf=(pcm,solvent=dichloromethane) empiricaldispersion=gd3 scf=(xqc,maxcyc=1024)

opt freq

1 1
 C                 -1.09253528    0.85770424   -1.71774044
 C                 -1.57688782   -0.42180962   -1.29711345
 C                 -1.44387601   -2.82960608   -1.55324182
 H                 -0.56373440   -3.41990639   -1.81994905
 H                 -2.32383372   -3.41039768   -1.84221339
 C                 -1.47695178   -1.48996520   -2.25148161
 H                 -1.87736733   -1.41885868   -3.25690898
 C                 -0.11737654   -0.46789543   -2.17899958
 C                 -1.57430943   -0.96818663    0.10102189
 H                 -2.55697475   -0.71456249    0.51812900
 H                 -0.82782954   -0.50444128    0.74447883
 C                 -1.43350443   -2.50801508   -0.02051491
 O                 -0.02827251   -2.53960978    1.88512777
 O                 -2.46537073   -4.53501290    0.63073436
 C                  1.09210207   -3.03341454    2.65439839
 H                  2.02791918   -2.80992696    2.13806707
 H                  1.04052171   -2.50947022    3.60789819
 H                  0.99921019   -4.11235894    2.79912394
 C                 -3.52840949   -5.31938808    1.21976642
 H                 -3.63870457   -5.06714995    2.27691362
 H                 -4.46851055   -5.12923278    0.69668539
 H                 -3.22116482   -6.35710016    1.09902870
 H                 -1.47579448    1.17763775   -2.68692231
 C                 -0.16251820   -3.05824308    0.65563958
 C                 -2.62370619   -3.20792555    0.66743848
 O                 -3.58073244   -2.64201539    1.15090197
 O                  0.58063349   -3.88453455    0.17642167
 H                 -0.01262637   -0.24688371   -3.23493567
 C                  1.13121745   -0.93684122   -1.51112045
 C                  1.83085856   -1.99031795   -2.11635345
 C                  1.64457572   -0.39818479   -0.32052379
 C                  2.98097675   -2.52741472   -1.54248096
 H                  1.46448503   -2.41370535   -3.04804230
 C                  2.78659092   -0.92598376    0.26548743
 H                  1.15450735    0.44827910    0.14955968
 C                  3.45143937   -2.01129472   -0.32692843
 H                  3.48210242   -3.35225590   -2.03364698
 H                  3.17891678   -0.51679720    1.19095582
 Au                -0.51959055    2.40090489   -0.44033957
 P                  0.11602322    4.17399586    0.95620225
 C                 -0.35411149    5.83435239    0.32678536
 C                 -0.59689336    4.10239836    2.64674940
 C                  1.92947959    4.27820744    1.22863487
 H                 -1.44138751    5.89035180    0.22087612
 H                 -0.01551665    6.61207927    1.01900290
 H                  0.10275311    5.99600116   -0.65368457
 H                 -1.68849969    4.12685464    2.58546616
 H                 -0.24631731    4.95299208    3.24026578
 H                 -0.29301213    3.17036705    3.13186825
 H                  2.16840006    5.12559295    1.87969624
 H                  2.28055108    3.35273334    1.69362927
 H                  2.43723300    4.40238337    0.26789000
 Cl                 4.84558555   -2.62431316    0.55520807

C H P O Cl 0
6-31G*
****
Au 0
SDD
****

Au 0
SDD


