%nprocshared=20
%mem=41GB
#p opt=maxstep=17 freq=noraman nosymm b3lyp genecp scrf=(pcm,solvent=dichloromethane) empiricaldispersion=gd3 scf=(xqc,maxcyc=1024)

opt freq

1 1
 C                  1.53062446    0.81815005   -1.06482124
 C                  1.56527409   -0.63640566   -1.11281430
 C                  1.47399381   -2.85026514   -1.94936706
 H                  2.45283096   -3.30327896   -2.15373665
 H                  0.73845759   -3.41465721   -2.53095643
 C                  1.46446828   -1.37404208   -2.23647966
 H                  1.39255669   -0.96761215   -3.24070758
 C                  1.74767412    1.57886802    0.07808719
 C                  1.68789895   -1.52855004    0.10919824
 H                  1.09291865   -1.19409233    0.96241914
 H                  2.73425060   -1.59025223    0.43489032
 C                  1.18860322   -2.90131260   -0.41808796
 O                  1.48731612   -4.14217563    1.56085754
 O                 -0.75595813   -4.23729611   -0.56595160
 C                  2.09726950   -5.18392668    2.35428293
 H                  3.17715133   -5.02832163    2.41498021
 H                  1.64011798   -5.10374178    3.33970139
 H                  1.89378936   -6.16193082    1.91146395
 C                 -2.17030177   -4.49049883   -0.41730284
 H                 -2.47627978   -4.32433551    0.61821025
 H                 -2.74059862   -3.83414066   -1.07953197
 H                 -2.30888887   -5.53303069   -0.69977619
 H                  1.46655009    1.31650405   -2.03078899
 C                  1.89634402   -4.05910368    0.28398913
 C                 -0.32608412   -3.02683570   -0.19275711
 O                 -1.05504533   -2.15105736    0.23491649
 O                  2.73607156   -4.77820184   -0.21288347
 H                  1.97721453    1.04402302    0.99945917
 C                  1.90869853    3.03309949    0.15516586
 C                  2.23802001    3.61059114    1.39295218
 C                  1.74173693    3.89410311   -0.95297526
 C                  2.40630946    4.98617624    1.53997651
 H                  2.37046178    2.96980341    2.26124920
 C                  1.90168205    5.26100987   -0.82096103
 H                  1.48034686    3.48988282   -1.92598473
 C                  2.23723814    5.82361348    0.42746388
 H                  2.66621430    5.38925772    2.51116320
 H                  1.77577733    5.92529135   -1.66979359
 Au                -0.61156541    1.12355248   -0.09142884
 P                 -2.86626623    0.79721953    0.29142423
 C                 -3.60906963   -0.26450850   -1.00361057
 C                 -3.17532867   -0.08727729    1.86507443
 C                 -3.88384511    2.31941222    0.35015106
 H                 -3.06936383   -1.21458151   -1.01025166
 H                 -4.66783407   -0.43748615   -0.78537603
 H                 -3.50911461    0.21677944   -1.97998818
 H                 -2.64101362   -1.03974953    1.83148463
 H                 -4.24880788   -0.26521324    1.98773856
 H                 -2.80511973    0.50796025    2.70398412
 H                 -4.93267389    2.06140795    0.52984198
 H                 -3.52412992    2.96751232    1.15408671
 H                 -3.79714170    2.85288976   -0.60042437
 Cl                 2.34367782    6.88823634    0.43966056

C H P O Cl 0
6-31G*
****
Au 0
SDD
****

Au 0
SDD


