%nprocshared=20
%mem=41GB
#p opt=(maxstep=17,calcfc) freq=noraman nosymm b3lyp genecp scrf=(pcm,solvent=dichloromethane) empiricaldispersion=gd3 scf=(xqc,maxcyc=1024)

opt freq

1 1
 C                  1.87967081   -0.38063811    1.13595908
 C                  1.42886736    0.97082991    1.46604550
 C                  1.43821307    3.06337432    0.27009059
 H                  1.32271441    3.08587093   -0.81740741
 H                  1.89974472    4.00721117    0.56599696
 C                  2.27373185    1.87236510    0.71926852
 H                  3.29000650    2.06174450    1.05872578
 C                  2.40240986    0.41998311   -0.13949045
 C                  0.11043832    1.55529149    1.77508141
 H                  0.17280451    1.82463104    2.84682302
 H                 -0.73547782    0.87781652    1.66672737
 C                  0.02667179    2.86838386    0.94316983
 O                 -2.20876775    2.29125420    0.40712441
 O                 -0.51469930    5.16309492    1.15100154
 C                 -3.35175989    2.23515759   -0.47664133
 H                 -3.10781592    1.65280103   -1.36985634
 H                 -4.13944758    1.75283192    0.09955540
 H                 -3.64777775    3.24524870   -0.77078282
 C                 -0.76354234    6.37699700    1.89659253
 H                 -1.63080286    6.24556110    2.54777239
 H                  0.11449397    6.63258530    2.49790033
 H                 -0.95279426    7.14221072    1.14620570
 H                  2.76620124   -0.71278355    1.69140762
 C                 -1.09323133    2.82630636   -0.11297823
 C                 -0.26728418    4.06648393    1.86965318
 O                 -0.24034864    4.02184214    3.08174013
 O                 -0.99476498    3.23906125   -1.24589481
 H                  3.47412000    0.27372859   -0.27699793
 C                  1.66998944    0.36570255   -1.44471414
 C                  0.27990149    0.26524356   -1.56098922
 C                  2.42341259    0.44177377   -2.62864536
 C                 -0.35270625    0.23054166   -2.80415418
 H                 -0.34276946    0.20128283   -0.67498089
 C                  1.81177893    0.40539021   -3.87597638
 H                  3.50614400    0.53091842   -2.57459472
 C                  0.41482965    0.30006499   -3.97571560
 H                 -1.43117872    0.15717443   -2.84235343
 H                  2.39543531    0.46089725   -4.78974300
 O                 -0.09343677    0.27651597   -5.23592172
 C                 -1.50750379    0.19961957   -5.39276367
 H                 -1.68934463    0.20427646   -6.46755280
 H                 -1.90791094   -0.72789047   -4.96021330
 H                 -2.00929434    1.06015474   -4.93268188
 Au                 0.49330374   -1.97008856    0.99122445
 P                 -1.02058078   -3.73411576    0.71265624
 C                 -0.24793164   -5.29738622    0.13591216
 C                 -1.96095742   -4.20328674    2.21752017
 C                 -2.31234302   -3.36628467   -0.54166958
 H                  0.48514694   -5.63537450    0.87193422
 H                 -1.01155990   -6.07153608   -0.00266433
 H                  0.26544449   -5.11822678   -0.81318332
 H                 -1.26483819   -4.53076733    2.99476223
 H                 -2.66132285   -5.01378770    1.99047279
 H                 -2.51586993   -3.33557655    2.58528627
 H                 -2.98706273   -4.21881310   -0.66015494
 H                 -2.88559884   -2.49014166   -0.22517932
 H                 -1.83346517   -3.14294232   -1.49952414

C H P O 0
6-31G*
****
Au 0
SDD
****

Au 0
SDD


