%nprocshared=20
%mem=41GB
#p opt freq=noraman nosymm b3lyp 6-31G(d) scrf=(pcm,solvent=dichloromethane) empiricaldispersion=gd3 scf=(xqc,maxcyc=1024)

opt freq

0 1
 C                  2.32446726   -0.56285712    2.47419216
 C                  1.32053862   -0.85040116    1.86701648
 C                  0.66774333   -0.47501802   -1.22859762
 H                  0.73657063   -1.52629275   -1.52517272
 H                  0.21077651    0.06023399   -2.06915409
 C                  2.02911875    0.08339655   -0.93702036
 H                  2.05628540    1.09941682   -0.54522020
 C                  3.17500598   -0.58464883   -1.13524719
 C                  0.08432429   -1.24632584    1.19028297
 H                 -0.73759539   -1.21712764    1.91302767
 H                  0.17379220   -2.28465161    0.84636691
 C                 -0.32824125   -0.38004419   -0.03990454
 O                 -2.66453762   -0.61193372    0.35114854
 O                 -0.78896788    1.86139003   -0.66139642
 C                 -3.98596288   -1.09323831    0.02234236
 H                 -3.98681167   -2.18474133   -0.02916919
 H                 -4.63018910   -0.74435314    0.82834034
 H                 -4.30839800   -0.68224433   -0.93739742
 C                 -1.04896597    3.25025910   -0.36851918
 H                 -1.93820023    3.34320246    0.26013595
 H                 -0.19283737    3.69467139    0.14504089
 H                 -1.20830585    3.72653477   -1.33521272
 H                  3.22958755   -0.29589147    2.97233924
 C                 -1.69135034   -0.91992768   -0.52108197
 C                 -0.55017287    1.07488969    0.40258974
 O                 -0.53412779    1.47167340    1.54732628
 O                 -1.86567946   -1.56307140   -1.53366416
 H                  3.12103274   -1.58716797   -1.56254330
 C                  4.59295212   -0.08754976   -0.79772493
 H                  5.06848698   -0.78528259   -0.14050694
 H                  5.16393943    0.00021245   -1.69837541
 H                  4.53162585    0.86780778   -0.31978031



