%nprocshared=20
%mem=41GB
#p opt=maxstep=17 freq=noraman nosymm b3lyp genecp scrf=(pcm,solvent=dichloromethane) empiricaldispersion=gd3 scf=(xqc,maxcyc=1024)

opt freq

1 1
 Au                -0.42045017   -1.54629931    0.64516666
 C                  0.55211438    0.05831567    1.88376077
 C                 -0.18395416    0.78816430    1.22302850
 C                  0.86588333    2.29518648   -1.17634751
 H                  0.55390009    1.30836067   -1.52319197
 H                  0.91252979    2.93815353   -2.06092707
 C                  2.22277538    2.25758291   -0.52236235
 H                  2.58813878    3.22882194   -0.19389190
 C                  3.03292638    1.20933956   -0.29841929
 C                 -1.04404239    1.71801684    0.48435035
 H                 -1.75711524    2.16250630    1.18437798
 H                 -1.62422228    1.15127523   -0.25136634
 C                 -0.27563465    2.84858677   -0.26242668
 O                 -2.24766805    4.15509932   -0.33607449
 O                  0.71349137    4.95098803    0.16694123
 C                 -3.30684866    4.87050686   -1.01250247
 H                 -3.86631536    4.18995272   -1.65858933
 H                 -3.94242522    5.26260928   -0.21996915
 H                 -2.88618650    5.68203439   -1.61062098
 C                  1.27140030    5.96686671    1.03248595
 H                  0.51664546    6.30540176    1.74588184
 H                  2.13403491    5.56770526    1.57119931
 H                  1.57049872    6.77770126    0.37010971
 P                 -1.38357048   -3.46334606   -0.23050880
 C                 -3.20967708   -3.41112616   -0.07395612
 C                 -1.05300268   -3.81038893   -1.99615301
 H                  1.29166003   -0.28739898    2.57937183
 C                 -1.32725662    3.58056105   -1.12360710
 C                  0.26914006    3.84230276    0.77127187
 O                  0.31248406    3.64007419    1.96621864
 O                 -1.34467769    3.61200999   -2.33417858
 H                  3.95605285    1.42213376    0.24100442
 C                  2.83561323   -0.21388163   -0.62027046
 C                  3.30656032   -1.18245369    0.28087894
 C                  2.21851940   -0.67318650   -1.80072886
 C                  3.13080341   -2.54959666    0.05975341
 H                  3.81562416   -0.86105175    1.18641847
 C                  2.04359808   -2.03067083   -2.04191537
 H                  1.91094539    0.03715463   -2.56064646
 C                  2.48571849   -2.97935118   -1.10692900
 H                  3.50621038   -3.25958064    0.78719194
 H                  1.58937140   -2.37653291   -2.96465981
 C                 -0.85749922   -4.97438956    0.66092934
 H                 -1.10734746   -4.88326942    1.72124475
 H                 -1.36202954   -5.84925949    0.23831204
 H                  0.22296590   -5.09263296    0.55642407
 H                 -3.48229500   -3.27092945    0.97535536
 H                 -3.64231951   -4.34625963   -0.44382821
 H                 -3.60028364   -2.57291187   -0.65759691
 H                 -1.29123517   -2.93165657   -2.60067038
 H                 -1.67143755   -4.65507964   -2.31766766
 H                  0.00225184   -4.06387423   -2.11622770
 Cl                 2.29964213   -4.00321789   -1.35587187

C H P O Cl 0
6-31G*
****
Au 0
SDD
****

Au 0
SDD


