%nprocshared=20
%mem=41GB
#p opt=(calcfc,ts,noeigentest,maxstep=7) freq=noraman nosymm b3lyp genecp scrf=(pcm,solvent=dichloromethane) empiricaldispersion=gd3 scf=(xqc,maxcyc=1024)

opt freq

1 1
 C                 -0.54105523    0.58299337   -1.82968831
 C                 -0.94363589   -0.74195161   -1.46756984
 C                 -0.48048310   -3.11786550   -1.61351424
 H                  0.49804120   -3.59885953   -1.68680756
 H                 -1.21278191   -3.80449861   -2.04643706
 C                 -0.53492401   -1.79909416   -2.34914134
 H                 -0.73784765   -1.78712055   -3.41448220
 C                  0.65449021   -0.61804755   -2.05123181
 C                 -1.14842582   -1.27038767   -0.07755845
 H                 -2.21632884   -1.13459818    0.13475996
 H                 -0.60120278   -0.71278754    0.68136092
 C                 -0.80616221   -2.78261420   -0.11874980
 O                  0.19567301   -2.62401045    2.02095073
 O                 -1.69862563   -4.91402514    0.38937267
 C                  1.19543607   -2.96989510    3.00669836
 H                  2.18075527   -2.63884247    2.67225967
 H                  0.89813818   -2.44697419    3.91472150
 H                  1.20404311   -4.05066013    3.16659929
 C                 -2.75584414   -5.81657158    0.78931541
 H                 -3.09843236   -5.56947815    1.79675053
 H                 -3.59209952   -5.74766501    0.08967855
 H                 -2.31084454   -6.81013524    0.76418056
 H                 -0.76364879    0.84436509   -2.86443218
 C                  0.36501802   -3.16701231    0.80640832
 C                 -2.01639647   -3.61589872    0.35104153
 O                 -3.10904139   -3.16640239    0.62301611
 O                  1.27925679   -3.90099810    0.50621925
 H                  0.93565281   -0.39611945   -3.07422486
 C                  1.79588988   -0.92458916   -1.14117830
 C                  2.71902940   -1.89057980   -1.56578815
 C                  2.00093198   -0.31581066    0.10724333
 C                  3.79083364   -2.27768850   -0.76456656
 H                  2.59322015   -2.36451059   -2.53588727
 C                  3.06139100   -0.69456439    0.91850876
 H                  1.33254859    0.46900236    0.44632902
 C                  3.95190979   -1.69627330    0.50085485
 H                  4.47153263   -3.03989642   -1.12292882
 H                  3.21535553   -0.23161888    1.88795317
 Au                -0.41327785    2.19686825   -0.51798363
 P                 -0.27472708    4.04770516    0.91498202
 C                 -0.80596969    5.63209083    0.15243481
 C                 -1.28908063    3.90595934    2.43889825
 C                  1.42603328    4.37514011    1.52645994
 H                 -1.85080616    5.55391793   -0.16177572
 H                 -0.70244553    6.45198854    0.87057237
 H                 -0.18957669    5.83881749   -0.72705382
 H                 -2.34308800    3.79638305    2.16867519
 H                 -1.16329832    4.79868448    3.06010300
 H                 -0.97755737    3.02272717    3.00389389
 H                  1.43227832    5.25160686    2.18280833
 H                  1.78665003    3.50398230    2.08054676
 H                  2.09256691    4.55107823    0.67731837
 H                  4.71701336   -1.95750544    1.20176448

C H P O 0
6-31G*
****
Au 0
SDD
****

Au 0
SDD


