%nprocshared=20
%mem=41GB
#p opt freq=noraman nosymm b3lyp 6-31G(d) scrf=(pcm,solvent=dichloromethane) empiricaldispersion=gd3 scf=(xqc,maxcyc=1024)

opt freq

0 1
 C                  0.85391607    0.05880948    2.69787358
 C                 -0.13142293   -0.35734619    2.13650196
 C                 -0.61655742   -0.84426240   -0.97435611
 H                 -0.58071564   -1.93808542   -0.96256163
 H                 -1.00795666   -0.55239149   -1.95591945
 C                  0.75283230   -0.26709792   -0.76980746
 H                  0.80659879    0.81670797   -0.67485204
 C                  1.87583496   -0.99752970   -0.70679567
 C                 -1.35004667   -0.89009604    1.52487769
 H                 -2.20375339   -0.63546385    2.16136153
 H                 -1.29074351   -1.98535481    1.48889793
 C                 -1.66348926   -0.39094658    0.08036425
 O                 -4.02398328   -0.43487154    0.38221615
 O                 -1.99269049    1.59955988   -1.16545240
 C                 -5.34825443   -0.94964559    0.12289793
 H                 -5.39556931   -2.01141707    0.37673968
 H                 -6.01433390   -0.37020618    0.76083925
 H                 -5.60523503   -0.81434935   -0.93049507
 C                 -2.20396805    3.02195218   -1.28584892
 H                 -3.11744297    3.31340958   -0.76125435
 H                 -1.35455411    3.56680607   -0.86652492
 H                 -2.29494427    3.21311835   -2.35444750
 H                  1.74500062    0.42762626    3.15460811
 C                 -3.02462690   -1.00334566   -0.31122733
 C                 -1.84104113    1.13559020    0.08730735
 O                 -1.86248454    1.83626340    1.07559564
 O                 -3.17855119   -1.89874654   -1.11366846
 H                  1.79763882   -2.07752205   -0.84111460
 C                  3.23025784   -0.49277914   -0.45040547
 C                  4.34333746   -1.30062577   -0.72989471
 C                  3.47750883    0.78123817    0.10558205
 C                  5.65122336   -0.86848238   -0.49865194
 H                  4.18696483   -2.29342153   -1.14583963
 C                  4.76990035    1.22535384    0.34195309
 H                  2.64360712    1.42164570    0.37672120
 C                  5.87118313    0.40626115    0.03827951
 H                  6.47835199   -1.52740898   -0.73580207
 H                  4.95615859    2.20347092    0.77531880
 Cl                 6.83307906    0.82290843    0.25289837



