%nprocshared=20
%mem=41GB
#p opt=maxstep=17 freq=noraman nosymm b3lyp genecp scrf=(pcm,solvent=dichloromethane) empiricaldispersion=gd3 scf=(xqc,maxcyc=1024)

opt freq

1 1
 C                 -0.49632299    0.75430762   -1.42244799
 C                  0.73009331    0.33510640   -1.04731763
 C                  2.93152357   -0.73501110   -1.42842887
 H                  3.92029318   -0.38571728   -1.13374356
 H                  3.08877911   -1.46815404   -2.22123523
 C                  2.01512243    0.39355473   -1.94390223
 H                  1.75660487    0.27063884   -2.99568898
 C                  2.24156823    1.81812701   -1.65397930
 C                  1.14944757   -0.33934546    0.23506814
 H                  0.30120962   -0.79069183    0.75017121
 H                  1.61728169    0.38014136    0.92027344
 C                  2.19721220   -1.39062785   -0.21477390
 O                  2.55420710   -2.54408016    1.81286484
 O                  2.37761648   -3.59045680   -1.05975592
 C                  3.33052736   -2.89956090    2.97994056
 H                  3.58764387   -2.00164929    3.54666412
 H                  2.68835991   -3.55629492    3.56486835
 H                  4.24391787   -3.41749188    2.67852923
 C                  1.83961147   -4.85544733   -1.50319099
 H                  1.27686637   -5.32847367   -0.69475559
 H                  1.18524904   -4.70540585   -2.36530003
 H                  2.70450346   -5.45884400   -1.77567534
 H                 -0.53824789    1.25320105   -2.39547043
 C                  3.14759187   -1.72741839    0.93512588
 C                  1.48138254   -2.67569802   -0.66124934
 O                  0.28057314   -2.84671712   -0.67320539
 O                  4.26625300   -1.27250558    1.07576907
 H                  1.68878550    2.46371430   -2.33362199
 C                  2.92253269    2.51036919   -0.63475226
 C                  2.74986986    3.92938826   -0.60239471
 C                  3.77205977    1.92840331    0.36008246
 C                  3.36382598    4.72313430    0.34073088
 H                  2.11031519    4.39611488   -1.34584536
 C                  4.38430984    2.71284734    1.30562637
 H                  3.95511617    0.86417529    0.39077769
 C                  4.19060921    4.11691025    1.31491927
 H                  3.20688619    5.79411130    0.33017194
 H                  5.02922818    2.27915232    2.06196872
 Au                -2.24037670    0.44780715   -0.38438614
 P                 -4.25107494    0.07928241    0.78913885
 C                 -5.55589677    1.33499204    0.47656555
 C                 -5.06115047   -1.52445047    0.40299772
 C                 -4.06569831    0.06624053    2.61761596
 H                 -5.79983202    1.34907168   -0.58958941
 H                 -6.45700293    1.10102458    1.05307704
 H                 -5.18650611    2.32350624    0.76444898
 H                 -5.29443719   -1.56572613   -0.66475802
 H                 -5.98389553   -1.63721605    0.98162033
 H                 -4.37767152   -2.34378082    0.64378537
 H                 -5.03426446   -0.10331059    3.09931055
 H                 -3.37135070   -0.72775769    2.90738198
 H                 -3.65890866    1.02587896    2.94944963
 Cl                 4.65844656    4.59893060    2.01981378

C H P O Cl 0
6-31G*
****
Au 0
SDD
****

Au 0
SDD


