%nprocshared=20
%mem=41GB
#p opt=(calcfc,ts,noeigentest,maxstep=7) freq=noraman nosymm b3lyp genecp scrf=(pcm,solvent=dichloromethane) empiricaldispersion=gd3 scf=(xqc,maxcyc=1024)

opt freq

1 1
 C                 -0.02108327    1.18091555    0.16938783
 C                  0.88666009    0.36222174    0.51683736
 C                  3.62901652   -0.41599257    0.07796507
 H                  4.15094210   -0.33115049    1.03512906
 H                  4.35913295   -0.74533159   -0.66682734
 C                  3.01133968    0.89574169   -0.31136396
 H                  2.65617690    0.97782791   -1.33602357
 C                  3.03200740    1.99902430    0.49393416
 C                  1.39431397   -0.89514596    1.08518217
 H                  0.54964917   -1.58835594    1.14275026
 H                  1.75736961   -0.72047516    2.10498808
 C                  2.52972854   -1.49964151    0.23332522
 O                  2.18372388   -3.71428873    0.98816344
 O                  2.95349107   -2.40954650   -1.90873565
 C                  2.59339876   -4.94071330    1.63725637
 H                  2.85156698   -4.74401626    2.68037391
 H                  1.73299242   -5.60474695    1.56952137
 H                  3.45569142   -5.36723387    1.11977804
 C                  2.55572370   -2.89863146   -3.21009943
 H                  1.85929633   -3.73297625   -3.09895241
 H                  2.08158582   -2.09794420   -3.78249304
 H                  3.47721713   -3.22425043   -3.69020483
 H                  0.07146991    2.20604682   -0.17869624
 C                  3.10259995   -2.73951922    0.94049246
 C                  1.96944815   -1.95453313   -1.12513611
 O                  0.79868814   -1.91713185   -1.44299244
 O                  4.21723521   -2.81844483    1.40719727
 H                  3.45443821    1.88081666    1.49162566
 C                  2.51041969    3.31467311    0.18666947
 C                  2.49698726    4.29887279    1.19512091
 C                  1.97182230    3.66170438   -1.07719564
 C                  1.97395185    5.56811478    0.97640947
 H                  2.90327819    4.05967531    2.17444599
 C                  1.44488238    4.92017270   -1.30755800
 H                  1.97814632    2.94242931   -1.88983222
 C                  1.43822532    5.88725096   -0.28333999
 H                  1.98452058    6.29464089    1.77962873
 H                  1.03562662    5.18916320   -2.27584193
 Au                -1.92660539    0.26396120    0.13014692
 P                 -4.05323972   -0.67119458   -0.00302210
 C                 -5.39910312    0.57352063   -0.06734799
 C                 -4.29716256   -1.71369519   -1.49291662
 C                 -4.47527527   -1.75880853    1.41309489
 H                 -5.26479098    1.20913348   -0.94698712
 H                 -6.37203264    0.07460525   -0.12283976
 H                 -5.36053728    1.19870375    0.82896075
 H                 -4.14352099   -1.10671750   -2.38944380
 H                 -5.31032422   -2.12886413   -1.50141609
 H                 -3.56821313   -2.52876374   -1.49032525
 H                 -5.47960093   -2.17481036    1.28186696
 H                 -3.74846415   -2.57356291    1.47428719
 H                 -4.43775764   -1.18112720    2.34086521
 H                  1.01404810    6.83437322   -0.54397978

C H P O 0
6-31G*
****
Au 0
SDD
****

Au 0
SDD


