%nprocshared=20
%mem=41GB
#p opt=(maxstep=3,calcfc,ts,noeigentest) freq=noraman nosymm b3lyp genecp scrf=(pcm,solvent=dichloromethane) empiricaldispersion=gd3 scf=(xqc,maxcyc=1024)

opt freq ts

1 1
 C                 -0.76935372   -1.54449524   -0.40538178
 C                 -0.42177680   -0.20090474   -0.27874183
 C                  1.12563629    1.21394654   -1.39026135
 H                  0.80799256    1.09987471   -2.43741907
 H                  2.11951142    1.66373861   -1.37760101
 C                  0.99463062   -0.07582444   -0.63349961
 H                  1.78387980   -0.42548171    0.02073522
 C                  0.33531713   -2.06983607   -1.27082539
 C                 -1.13124374    1.13235015   -0.37619129
 H                 -1.67844743    1.41137347    0.52523752
 H                 -1.83576214    1.11521044   -1.21530901
 C                  0.05207792    2.10238644   -0.66650700
 O                 -1.12712622    4.13768265   -0.79696640
 O                  1.60031017    3.50152441    0.45056381
 C                 -1.64070337    5.29205752   -1.49927550
 H                 -2.30652734    4.97616220   -2.30595174
 H                 -2.18536441    5.86718821   -0.75180932
 H                 -0.81587567    5.87681747   -1.91324537
 C                  2.25220154    4.02960092    1.62786403
 H                  1.51914478    4.51579837    2.27575583
 H                  2.74947902    3.22466152    2.17461456
 H                  2.97911389    4.75041876    1.25678199
 H                 -1.75420715   -2.00152725   -0.31132955
 C                 -0.39900728    3.28022468   -1.52767553
 C                  0.63790173    2.59926539    0.66361729
 O                  0.30866011    2.19575572    1.76336341
 O                 -0.17152912    3.40382570   -2.71163573
 H                  0.95387851   -2.89187458   -0.91118792
 C                  0.28869277   -1.93642419   -2.72759907
 C                 -0.70528543   -1.21127092   -3.41208288
 C                  1.29393838   -2.55815295   -3.50273229
 C                 -0.69702307   -1.09105021   -4.80091004
 H                 -1.51408724   -0.74567071   -2.85779244
 C                  1.31059143   -2.44876133   -4.88291732
 H                  2.07333427   -3.12955070   -3.00489016
 C                  0.31732047   -1.70823658   -5.54832465
 H                 -1.48490022   -0.52780663   -5.28640346
 H                  2.08423715   -2.92791438   -5.47458284
 O                  0.42343646   -1.66060319   -6.90175335
 C                 -0.54367051   -0.90965869   -7.63451877
 H                 -0.25540903   -0.99658613   -8.68292146
 H                 -1.55275433   -1.31810604   -7.49865974
 H                 -0.53478751    0.14683876   -7.33934173
 Au                -0.34150234   -1.25077294    1.85667020
 P                  0.01202099   -0.96468633    4.13258757
 C                  0.44769882   -2.47680412    5.07171627
 C                  1.37612189    0.22333636    4.43293093
 C                 -1.44887629   -0.25922964    4.98475439
 H                  1.35876170   -2.91536188    4.65547810
 H                  0.61179153   -2.22414624    6.12446984
 H                 -0.36422842   -3.20500182    4.99373524
 H                  2.31506566   -0.20941655    4.07541175
 H                  1.45801937    0.44069159    5.50290499
 H                  1.17379707    1.14080826    3.87344266
 H                 -1.22312445   -0.10590027    6.04493675
 H                 -1.70837758    0.69775252    4.52376774
 H                 -2.29692776   -0.94222843    4.88620750

C H P O 0
6-31G*
****
Au 0
SDD
****

Au 0
SDD




