%nprocshared=20
%mem=41GB
#p opt freq=noraman nosymm b3lyp 6-31G(d) scrf=(pcm,solvent=dichloromethane) empiricaldispersion=gd3 scf=(xqc,maxcyc=1024)

opt freq

0 1
 C                  0.66114089   -3.41436913   -0.17127759
 C                  0.84368624   -1.96737695   -0.07602083
 C                  1.95695638    0.11281684    0.27044491
 H                  2.62151286    0.45029239   -0.53595685
 H                  2.27307941    0.64189069    1.17628299
 C                  1.95940309   -1.38446274    0.40551229
 H                  2.80717819   -1.92628720    0.81559165
 C                 -0.46498950   -4.15481435   -0.29759050
 C                 -0.07404070   -0.91148799   -0.67849894
 H                 -1.13133865   -1.02730534   -0.44928652
 H                  0.02314381   -0.93682037   -1.77238298
 C                  0.47893561    0.42567519   -0.10877713
 O                 -0.94338898    1.87506356   -1.30389037
 O                  0.10502823    2.03500807    1.58216998
 C                 -1.21253846    2.90646581   -2.27551557
 H                 -0.85916648    2.59854064   -3.26283099
 H                 -2.29489283    3.03106597   -2.27596665
 H                 -0.71708609    3.83689194   -1.98640406
 C                 -0.52840500    2.52097084    2.78332547
 H                 -1.60879784    2.59834445    2.63657975
 H                 -0.32278313    1.84724785    3.61903146
 H                 -0.09347467    3.50321141    2.96506528
 H                  1.59695660   -3.97348039   -0.16680034
 C                  0.35083082    1.54842759   -1.13497372
 C                 -0.29030655    0.82164492    1.15745348
 O                 -1.11807045    0.14555467    1.73251127
 O                  1.26238432    2.05592117   -1.75414027
 H                 -0.31449525   -5.21992580   -0.47762060
 C                 -1.94274924   -3.73641057   -0.18461078
 H                 -2.09759097   -3.22012024    0.73970970
 H                 -2.19402348   -3.09090651   -1.00013868
 H                 -2.56338800   -4.60749600   -0.21490448


