%nprocshared=20
%mem=41GB
#p opt=(calcfc,ts,noeigentest,maxstep=7) freq=noraman nosymm b3lyp genecp scrf=(pcm,solvent=dichloromethane) empiricaldispersion=gd3 scf=(xqc,maxcyc=1024)

opt freq

1 1
 C                 -0.57261893    1.08765499   -1.42553761
 C                  0.25347052    0.31321338   -0.85659666
 C                  2.00243525   -1.92902575   -1.56123400
 H                  3.02593237   -2.09866188   -1.22878459
 H                  1.75093004   -2.76238819   -2.22042507
 C                  1.87286778   -0.63208028   -2.31254258
 H                  1.18494374   -0.64129515   -3.15334542
 C                  2.59403972    0.51978234   -2.14849763
 C                  0.78091710   -0.55002187    0.20311084
 H                  0.04264739   -0.57591726    1.01015059
 H                  1.69697360   -0.10778943    0.60985006
 C                  1.06579889   -1.98358546   -0.30563457
 O                  0.85242163   -3.08240015    1.78016780
 O                 -0.05672265   -3.92017448   -1.07338757
 C                  1.36815651   -3.77828357    2.94025288
 H                  2.11248599   -3.15944189    3.44626373
 H                  0.50443599   -3.94919026    3.58076794
 H                  1.82073460   -4.72464121    2.63613292
 C                 -1.23609947   -4.70060229   -1.37355870
 H                 -1.85162922   -4.80715587   -0.47721485
 H                 -1.81563452   -4.21645524   -2.16301796
 H                 -0.86445395   -5.66880940   -1.70555930
 H                 -0.53443808    1.63910664   -2.35522860
 C                  1.74676710   -2.75822854    0.84046697
 C                 -0.26928853   -2.67988086   -0.62161537
 O                 -1.36657312   -2.18113420   -0.47270531
 O                  2.93410052   -2.99499721    0.91140933
 H                  2.33044618    1.31207299   -2.84775512
 C                  3.64544431    0.91659605   -1.22119535
 C                  4.15651383    2.22469714   -1.36514584
 C                  4.19815479    0.12241736   -0.18415621
 C                  5.15654609    2.73161288   -0.54287531
 H                  3.75740626    2.86306672   -2.14924246
 C                  5.19117179    0.61673656    0.64408692
 H                  3.85927125   -0.88864314   -0.00335888
 C                  5.68381232    1.92400483    0.47698255
 H                  5.51368816    3.74220478   -0.69946221
 H                  5.60781682    0.00430676    1.43722841
 Au                -2.37700190    1.07100166   -0.29555892
 P                 -4.39987495    1.11394735    0.84847130
 C                 -5.46715953    2.54000982    0.41148124
 C                 -5.44068250   -0.36795122    0.55474449
 C                 -4.20441741    1.20181356    2.67076532
 H                 -5.68817435    2.51560118   -0.65923042
 H                 -6.40286506    2.49535907    0.97822730
 H                 -4.94472778    3.47241344    0.64268228
 H                 -5.66853937   -0.44775350   -0.51164062
 H                 -6.37329958   -0.28954505    1.12315840
 H                 -4.89520357   -1.26297741    0.86645838
 H                 -5.18652686    1.22812230    3.15409054
 H                 -3.65057517    0.32534696    3.01873578
 H                 -3.64284337    2.10201893    2.93489822
 Cl                 6.94304025    2.41759282    1.60317788

C H P O Cl 0
6-31G*
****
Au 0
SDD
****

Au 0
SDD


