%nprocshared=20
%mem=41GB
#p opt=(calcfc,ts,noeigentest,maxstep=7) freq=noraman nosymm b3lyp genecp scrf=(pcm,solvent=dichloromethane) empiricaldispersion=gd3 scf=(xqc,maxcyc=1024)

opt freq

1 1
 C                  0.82311285    0.35286656   -1.19548964
 C                  0.32252184   -0.98406485   -1.40800378
 C                  0.76047767   -3.29181378   -0.81647672
 H                  1.34080804   -3.75282852   -0.01486544
 H                  0.73581654   -3.98792952   -1.66065971
 C                  1.35162852   -1.97773207   -1.27438833
 H                  2.24343688   -1.97348999   -1.89394395
 C                  1.55334267   -0.71507381   -0.17915810
 C                 -0.99325564   -1.54371635   -0.96557450
 H                 -1.58733025   -1.68153037   -1.88123667
 H                 -1.55393019   -0.86882827   -0.31552293
 C                 -0.68442260   -2.93370335   -0.33992587
 O                 -2.02096102   -2.68408866    1.58871371
 O                 -1.47438405   -5.14061284   -0.15126864
 C                 -2.23264206   -2.54055018    3.01327023
 H                 -1.71742935   -1.64939555    3.37938415
 H                 -3.31013689   -2.44372171    3.13585090
 H                 -1.85906090   -3.42323753    3.53684630
 C                 -2.33438779   -6.24818330   -0.50694041
 H                 -3.37772572   -5.98676336   -0.31582802
 H                 -2.20501001   -6.49941966   -1.56215396
 H                 -2.01928273   -7.07388882    0.12915714
 H                  1.62751109    0.63048352   -1.87875128
 C                 -0.75295110   -2.82909418    1.19224064
 C                 -1.68399101   -3.99646518   -0.81104139
 O                 -2.51362189   -3.83689036   -1.68011042
 O                  0.20642296   -2.82741100    1.93674529
 H                  1.00961539   -0.88341498    0.74303722
 C                  3.02028046   -0.46962808    0.08842431
 C                  3.47067348   -0.73855181    1.38462239
 C                  3.94230534   -0.02644013   -0.86987671
 C                  4.80973492   -0.55325280    1.73663827
 H                  2.77328030   -1.10433938    2.13312675
 C                  5.27595127    0.15801570   -0.53206283
 H                  3.63257375    0.17409671   -1.89146228
 C                  5.72249062   -0.09998172    0.77530565
 H                  5.12151147   -0.76643113    2.75192484
 H                  5.99425426    0.50371060   -1.26824623
 Au                -0.31505194    1.93994198   -0.46629008
 P                 -1.55217873    3.74825818    0.37326400
 C                 -0.98704954    5.38873895   -0.22880778
 C                 -3.34024408    3.69528098   -0.04367863
 C                 -1.51260108    3.89010797    2.20408732
 H                 -1.06041746    5.42146917   -1.31955588
 H                 -1.60262138    6.18583210    0.20099053
 H                  0.05754617    5.54106600    0.05745930
 H                 -3.46166262    3.68843282   -1.13062011
 H                 -3.85276622    4.56776182    0.37440326
 H                 -3.78383000    2.78289005    0.36523597
 H                 -2.11531464    4.74259320    2.53378080
 H                 -1.90782220    2.97248378    2.64910152
 H                 -0.47945353    4.02513666    2.53655007
 H                  6.76372811    0.07144424    0.95233004

C H P O 0
6-31G*
****
Au 0
SDD
****

Au 0
SDD


