%nprocshared=20
%mem=41GB
#p opt freq=noraman b3lyp gen scrf=(solvent=dichloromethane,pcm) nosymm empiricaldispersion=gd3
scf=(xqc,maxcyc=1024)

opt freq

0 1
 C                  0.65296757    1.28071260   -0.60383664
 C                  2.82123505    2.27187392    0.27759742
 C                  2.18088891    3.44727278    0.52502541
 C                  0.67315350    3.61378753    0.24547043
 H                  3.89081862    2.24476751    0.29009626
 H                  0.74550346    1.71888984   -1.57363545
 H                  0.10406777    0.36557770   -0.67800121
 H                  2.73714885    4.27658827    0.90935689
 H                  0.24258721    4.29839360    0.94579063
 H                  0.55913963    3.99814368   -0.74881362
 C                  2.03614446    0.97405354   -0.00247275
 C                  2.50346632   -0.27259763    0.25058493
 H                  3.51457959   -0.40759257    0.57358080
 N                 -0.05973615    2.26303792    0.33035201
 S                 -1.72858679    2.21122837   -0.03890848
 O                 -2.49586898    1.15206810    0.99953150
 O                 -2.38517365    3.73667438    0.13661412
 C                 -1.94809539    1.66029878   -1.71720897
 H                 -1.74662515    0.61116508   -1.77744357
 H                 -2.95532606    1.84833512   -2.02547624
 H                 -1.27428665    2.19021954   -2.35757275
 C                  1.58426152   -1.49562176    0.07487348
 C                  0.70746976   -1.86171438    1.09648193
 C                  1.62816020   -2.23729656   -1.10560928
 C                 -0.12471750   -2.96964695    0.93782647
 H                  0.67364973   -1.27724271    2.02733683
 C                  0.79508159   -3.34500932   -1.26486493
 H                  2.31902227   -1.94879284   -1.91096896
 C                 -0.08118680   -3.71135501   -0.24335548
 H                 -0.81539248   -3.25863855    1.74327568
 H                  0.82961880   -3.92935476   -2.19589759
 O                 -0.93460748   -4.84722390   -0.40575921
 C                 -1.58962452   -5.13312719    0.83283353
 H                 -2.20024276   -4.30062099    1.11386520
 H                 -2.20250207   -6.00289166    0.71973673
 H                 -0.85624616   -5.30979647    1.59167748

C H N S O 0
6-31G*
****





