%nprocshared=20
%mem=41GB
#p opt freq=noraman b3lyp genecp scrf=(solvent=dichloromethane,pcm) nosymm empiricaldispersion=gd3
scf=(xqc,maxcyc=1024)

opt freq

1 1
 Au                -1.13704488   -0.63556644    0.09261461
 C                 -0.34376417   -2.45972715   -0.96083906
 C                 -0.27359592   -1.63476900   -1.87063956
 C                  2.08694406    0.23683050   -2.42702463
 H                  2.45884016   -0.77789891   -2.60312611
 H                  2.78793207    0.92084209   -2.91494430
 C                  2.02859411    0.54240049   -0.95602245
 H                  1.78933039    1.57309522   -0.69853141
 C                  2.24013582   -0.35117090    0.02301426
 C                 -0.17141530   -0.88666026   -3.12958361
 H                 -1.17696278   -0.62797989   -3.47098545
 H                  0.23829309   -1.60566450   -3.85079524
 P                 -2.02921880    0.87884472    1.60143863
 C                 -1.27576669    2.53753242    1.41692364
 C                 -3.83169255    1.13382782    1.39361843
 H                 -0.27911279   -3.34074512   -0.35198311
 H                  2.43686049   -1.38609718   -0.25691845
 C                  2.15198282   -0.09794847    1.46646129
 C                  1.95909796   -1.17612214    2.34401818
 C                  2.21801587    1.19484281    2.02818071
 C                  1.80991769   -0.99306644    3.72102999
 H                  1.91614645   -2.18563680    1.94207242
 C                  2.07402393    1.39436765    3.39253450
 H                  2.40287720    2.05342423    1.38925017
 C                  1.86334524    0.30184700    4.25430765
 H                  1.65858219   -1.85607569    4.35841272
 H                  2.13124041    2.38917339    3.82317014
 O                  1.72729412    0.60899136    5.57199236
 C                  1.49348792   -0.45384971    6.49440008
 H                  2.32762168   -1.16618446    6.50312856
 H                  1.40737069    0.01615427    7.47493034
 H                  0.56239428   -0.98558765    6.26095354
 C                 -1.79074841    0.41194850    3.35503984
 H                 -0.72258613    0.30069814    3.55579156
 H                 -2.21069823    1.18584037    4.00593773
 H                 -2.29090373   -0.54061143    3.55034793
 H                 -0.20511005    2.46751674    1.62537115
 H                 -1.74135791    3.24265129    2.11317476
 H                 -1.42170720    2.87554546    0.38815843
 H                 -4.03460097    1.47943240    0.37617581
 H                 -4.18845276    1.87905164    2.11177819
 H                 -4.35512344    0.18797336    1.55783743
 N                  0.71785334    0.39183094   -3.16205587
 S                  0.66540931    0.63616855   -4.85369672
 O                 -0.92470453    0.75558691   -5.34985923
 O                  1.47576972    2.04488614   -5.23805433
 C                  1.44193294   -0.73828349   -5.67606685
 H                  0.79990516   -1.59280374   -5.62611215
 H                  1.62103386   -0.48612284   -6.70038997
 H                  2.37164633   -0.96213911   -5.19604427

C H N P S O 0
6-31G*
****
Au 0
SDD
****

Au 0
SDD


