%nprocshared=20
%mem=41GB
#p opt freq=noraman b3lyp gen scrf=(solvent=dichloromethane,pcm) nosymm empiricaldispersion=gd3
scf=(xqc,maxcyc=1024)

opt freq

0 1
 C                 -0.89868472   -2.23881762    2.48985403
 C                 -1.48914725   -1.73398590    1.56536993
 C                 -1.17603220    1.21047598    0.45471138
 H                 -0.51610669    0.86642811   -0.34361573
 H                 -1.48453031    2.22662695    0.18178743
 C                 -0.45880202    1.29965355    1.77473542
 H                 -1.06301869    1.67644612    2.59945831
 C                  0.84845239    1.10636648    2.01417379
 C                 -2.20032841   -1.19272212    0.40828907
 H                 -3.16606715   -1.69982999    0.31479644
 H                 -1.63216862   -1.41840814   -0.50355141
 H                 -0.37052281   -2.65575234    3.31819351
 H                  1.20972308    1.37132133    3.00853242
 C                  1.89105051    0.61430832    1.09154650
 C                  3.16212742    1.20934374    1.10339221
 C                  1.69072214   -0.46755805    0.21061758
 C                  4.18455447    0.79021133    0.24963133
 H                  3.35690259    2.03118177    1.78860421
 C                  2.69806970   -0.90017729   -0.64225982
 H                  0.74800566   -1.00237871    0.23135433
 C                  3.95163295   -0.26843183   -0.63882806
 H                  5.14621969    1.28851333    0.28816174
 H                  2.54124494   -1.73896723   -1.31384237
 O                  4.86977291   -0.76452140   -1.51785493
 C                  6.16050328   -0.16347569   -1.55473853
 H                  6.67656388   -0.25943105   -0.59073871
 H                  6.72072982   -0.70380371   -2.31962490
 H                  6.10141191    0.89768516   -1.82895626
 N                 -2.46479749    0.34271556    0.42644552
 S                 -3.63148133    0.10805335   -0.80151314
 O                 -3.71644704   -1.51490123   -1.18582976
 O                 -5.01315418    0.96869114   -0.42844109
 C                 -3.16631229    1.03656262   -2.24715773
 H                 -2.34023236    0.55649133   -2.72884593
 H                 -3.99480106    1.08366374   -2.92264853
 H                 -2.88427944    2.02768143   -1.95898942

C H N S O 0
6-31G*
****






