%nprocshared=20
%mem=41GB
#p opt=(maxstep=5,calcfc,ts,noeigentest) freq=noraman nosymm b3lyp genecp scrf=(pcm,solvent=dichloromethane) empiricaldispersion=gd3 scf=(xqc,maxcyc=1024)

opt freq ts

1 1
 C                  1.89850994   -0.33561197    1.08699025
 C                  1.42751244    1.00992770    1.38964539
 C                  1.41619410    3.04308567    0.09265017
 H                  1.23690954    2.99147141   -0.98475224
 H                  1.89731514    4.00058606    0.29881418
 C                  2.25933487    1.87028084    0.57633369
 H                  3.26446664    2.09324228    0.93238951
 C                  2.42772394    0.40133745   -0.21347821
 C                  0.12414383    1.61306314    1.71779919
 H                  0.18761421    1.90674430    2.78231527
 H                 -0.72564691    0.93599310    1.62768383
 C                  0.04054031    2.90819131    0.85151748
 O                 -2.25496780    2.47021216    0.47222858
 O                 -0.39279162    5.22617832    1.03886453
 C                 -3.44555484    2.43489700   -0.34866102
 H                 -3.30286390    1.74723297   -1.18584396
 H                 -4.24016507    2.08610574    0.30915624
 H                 -3.66660047    3.43439114   -0.72998706
 C                 -0.58332024    6.45558807    1.77892369
 H                 -1.44913200    6.36432469    2.43863415
 H                  0.30839070    6.67749499    2.36950973
 H                 -0.74944385    7.22237624    1.02400108
 H                  2.75126119   -0.68328591    1.67830132
 C                 -1.13455198    2.87630133   -0.14292170
 C                 -0.17690245    4.12882886    1.76724298
 O                 -0.13126179    4.09999493    2.97906105
 O                 -1.06967624    3.19213117   -1.30935454
 H                  3.49655554    0.25010683   -0.36663752
 C                  1.67114923    0.27824249   -1.50558826
 C                  0.27522773    0.23041372   -1.59347997
 C                  2.40167983    0.23535045   -2.70515728
 C                 -0.38309240    0.13002413   -2.81947582
 H                 -0.33400103    0.25791583   -0.69659055
 C                  1.76453754    0.13223861   -3.93573732
 H                  3.48744983    0.28025736   -2.67558194
 C                  0.36355996    0.07884155   -4.00479466
 H                 -1.46580664    0.10294231   -2.83468493
 H                  2.33346935    0.09483778   -4.85920829
 O                 -0.16707625   -0.01875496   -5.25262320
 C                 -1.58664171   -0.06311209   -5.38312304
 H                 -1.78535956   -0.13305383   -6.45337581
 H                 -2.00670827   -0.94124441   -4.87630879
 H                 -2.05289733    0.84618112   -4.98383548
 Au                 0.50534731   -1.93706294    1.02108040
 P                 -1.03126525   -3.69087105    0.84459899
 C                 -0.29003576   -5.30496310    0.38014046
 C                 -1.97868089   -4.03484139    2.37920524
 C                 -2.31043116   -3.38381401   -0.43746570
 H                  0.42565991   -5.61178917    1.14800015
 H                 -1.07064587   -6.06676352    0.28374709
 H                  0.23752551   -5.20231084   -0.57244153
 H                 -1.28627647   -4.31899677    3.17664224
 H                 -2.69365159   -4.84676183    2.21117154
 H                 -2.51687617   -3.13328166    2.68574491
 H                 -2.99832441   -4.23320177   -0.50140391
 H                 -2.87089093   -2.47966763   -0.18294305
 H                 -1.82400976   -3.23452026   -1.40565734

C H P O 0
6-31G*
****
Au 0
SDD
****

Au 0
SDD


