%nprocshared=20
%mem=41GB
#p opt freq=noraman nosymm b3lyp 6-31G(d) scrf=(pcm,solvent=dichloromethane) empiricaldispersion=gd3 scf=(xqc,maxcyc=1024)

opt freq

0 1
 C                  2.34085457   -2.65510414    0.08634191
 C                  1.37537313   -2.07867747   -0.35382829
 C                  0.86018923    1.04069224   -0.42851041
 H                  1.18610994    1.09534798   -1.46869561
 H                  0.34715062    1.98640202   -0.21721504
 C                  2.02528837    0.94197239    0.51892488
 H                  1.75652155    0.92423161    1.57470323
 C                  3.33326480    1.01442640    0.22303163
 C                  0.20337543   -1.43488611   -0.94504340
 H                 -0.65044112   -2.11655056   -0.87517586
 H                  0.38633336   -1.26158886   -2.01354106
 C                 -0.21761850   -0.07301948   -0.31581704
 O                 -2.51938629   -0.38557224   -0.83017831
 O                 -0.98303183    0.88773152    1.70768887
 C                 -3.74022902   -0.06322980   -1.53135381
 H                 -3.59004185   -0.15342473   -2.60989659
 H                 -4.47498366   -0.78732440   -1.18176762
 H                 -4.05456769    0.95519770   -1.29055615
 C                 -1.44670345    0.81784436    3.07261606
 H                 -2.35102894    0.20702531    3.13244750
 H                 -0.67329435    0.38638178    3.71285335
 H                 -1.65621183    1.84705349    3.36162416
 H                  3.20079093   -3.13881426    0.49312175
 C                 -1.46035306    0.39376054   -1.10305063
 C                 -0.65757643   -0.28688933    1.13948504
 O                 -0.72224911   -1.35578685    1.70609124
 O                 -1.48097062    1.31719886   -1.88771192
 H                  4.02388539    1.08095130    1.06450908
 C                  4.00375863    1.05933356   -1.16261673
 H                  3.58824793    1.86291202   -1.73402946
 H                  5.05618332    1.21237532   -1.04480129
 H                  3.83270702    0.13391501   -1.67177471


