%nprocshared=20
%mem=41GB
#p opt freq=noraman nosymm b3lyp 6-31G(d) scrf=(pcm,solvent=dichloromethane) empiricaldispersion=gd3 scf=(xqc,maxcyc=1024)

opt freq

0 1
 C                 -0.00278083   -2.54542649   -1.72257987
 C                 -0.02707231   -2.02264617   -0.35792105
 C                 -0.28599199   -2.01313069    2.01262428
 H                  0.52494735   -2.47233381    2.59341577
 H                 -1.16894305   -2.00756503    2.66128598
 C                 -0.49747347   -2.71359612    0.69933868
 H                 -0.94938848   -3.69964467    0.63654903
 C                  0.10504353   -1.90532556   -2.91044705
 C                  0.64446424   -0.74091554    0.11779876
 H                  0.42802912    0.14603498   -0.47406741
 H                  1.73376818   -0.88162592    0.10087614
 C                  0.13434924   -0.57770392    1.57776991
 O                  1.42654393    1.31055725    2.14055954
 O                 -1.46533610    0.57493831    2.88217932
 C                  2.45417065    1.99430596    2.88672212
 H                  3.41816009    1.49908276    2.74544307
 H                  2.47979367    3.00728299    2.48642550
 H                  2.20445565    2.00604357    3.95079728
 C                 -2.62888419    1.40921838    3.05626145
 H                 -2.45962922    2.39250707    2.60986950
 H                 -3.50139539    0.94422088    2.59033329
 H                 -2.76768321    1.49444391    4.13350874
 H                 -0.05209902   -3.63321816   -1.77409184
 C                  1.21868924    0.02244748    2.46888623
 C                 -1.09642209    0.33660815    1.61094960
 O                 -1.69083642    0.77148571    0.64630683
 O                  1.84707073   -0.56728571    3.32281726
 H                  0.22772850   -2.54566632   -3.78476613
 C                  0.04232310   -0.47042536   -3.21908757
 C                 -0.79717590    0.41701415   -2.52647669
 C                  0.79066039    0.04882060   -4.29670137
 C                 -0.85623129    1.77401056   -2.84763195
 H                 -1.42114729    0.04932827   -1.71968843
 C                  0.74269730    1.39520518   -4.62877754
 H                  1.42985906   -0.61761465   -4.87113702
 C                 -0.07757853    2.27343743   -3.90022660
 H                 -1.51342736    2.41982667   -2.27733335
 H                  1.32979999    1.79396181   -5.45052791
 H                 -0.05908827    3.29598283   -4.21480410


