%nprocshared=20
%mem=41GB
%chk=cm
#p opt=(calcfc,modredundant,maxstep=7) freq=noraman b3lyp/genecp scrf=(solvent=dichloromethane,pcm) nosymm empiricaldispersion=gd3 scf=(xqc,maxcyc=1024)

opt freq

1 1
 C                 -1.05549561   -0.31854929   -1.33224336
 C                 -1.55342239   -1.46250192   -0.63072965
 C                 -1.48602825   -3.87209196   -0.36594488
 H                 -0.63039468   -4.53261803   -0.52667285
 H                 -2.38940414   -4.47405902   -0.49515942
 C                 -1.51398421   -2.71312442   -1.33511029
 H                 -1.94984985   -2.84716389   -2.31914641
 C                 -0.12927349   -1.74155709   -1.52736150
 C                 -1.51140826   -1.69594300    0.85151706
 H                 -2.47167996   -1.32866525    1.23481858
 H                 -0.73088262   -1.12807134    1.35612688
 C                 -1.41104506   -3.22956183    1.06034878
 H                 -1.46708920   -0.20242838   -2.33507166
 H                 -0.05886279   -1.75560987   -2.60887161
 C                  1.13212281   -2.09437917   -0.81367087
 C                  1.78404709   -3.27416816   -1.19930112
 C                  1.70189350   -1.32880820    0.21612160
 C                  2.94197412   -3.71066801   -0.55957744
 H                  1.37345111   -3.87616567   -2.00586209
 C                  2.85239433   -1.75337899    0.86594219
 H                  1.24949108   -0.38654697    0.50787967
 C                  3.46929710   -2.96042646    0.50077561
 H                  3.40513877   -4.63668521   -0.87691981
 H                  3.28835520   -1.16737562    1.66867767
 Au                -0.39962123    1.44447607   -0.43610793
 P                  0.32864415    3.45556695    0.52479121
 C                 -0.12593129    4.95581534   -0.43259630
 C                 -0.32221196    3.77033783    2.21258009
 C                  2.15292918    3.56006840    0.71125371
 H                 -1.21480590    5.02114778   -0.51387525
 H                  0.25621585    5.85319214    0.06474614
 H                  0.29768934    4.88919307   -1.43871932
 H                 -1.41448165    3.81458589    2.18178974
 H                  0.06991650    4.71730119    2.59750912
 H                 -0.02218972    2.95523691    2.87738309
 H                  2.43558180    4.51967695    1.15654587
 H                  2.49949865    2.74560134    1.35351968
 H                  2.62725396    3.45953382   -0.26913984
 H                  4.32739472   -3.23519827    1.07789688
 C                 -2.58868927   -3.72779669    1.91855397
 H                 -2.52062186   -4.78917471    2.03578682
 H                 -2.55244902   -3.25970723    2.88005222
 H                 -3.51122994   -3.48068415    1.43610800
 C                 -0.12986771   -3.66030504    1.79834938
 H                 -0.03195082   -3.09586056    2.70207208
 H                 -0.18690551   -4.70264125    2.03325769
 H                  0.71942153   -3.48169577    1.17248477

1 8 F
2 8 F
6 8 F

C H P 0
6-31G*
****
Au 0
SDD
****

Au 0
SDD


--link1--
%nprocshared=20
%mem=41GB
%chk=cm
#p opt=(calcfc,ts,noeigentest,maxstep=7,modredundant) geom=checkpoint guess=read freq=noraman nosymm b3lyp genecp scrf=(pcm,solvent=dichloromethane) empiricaldispersion=gd3 scf=(xqc,maxcyc=1024)

opt freq

1 1

1 8 A
2 8 A
6 8 A

C H P 0
6-31G*
****
Au 0
SDD
****

Au 0
SDD





