%nprocshared=20
%mem=41GB
#p opt freq=noraman b3lyp gen scrf=(solvent=dichloromethane,pcm) nosymm empiricaldispersion=gd3
scf=(xqc,maxcyc=1024)

opt freq

0 1
 C                 -1.80636483   -0.39512813   -0.72523871
 C                 -0.05128041    1.38101323   -0.25014803
 C                 -1.03661239    2.27340466    0.04240060
 C                 -2.52426531    1.86801858    0.00122842
 H                  0.94618072    1.73448889   -0.40834491
 H                 -2.00970591   -0.05284398   -1.71648332
 H                 -1.98897217   -1.44757263   -0.66798139
 H                 -0.77468639    3.27994800    0.29372761
 H                 -3.07722886    2.42364732    0.72925946
 H                 -2.90166200    2.08487896   -0.97850261
 C                 -0.33966284   -0.13155094   -0.34031150
 C                  0.57873974   -1.10072125   -0.10833590
 H                  0.27080594   -2.12369717   -0.04836055
 N                 -2.69667984    0.36150491    0.26494496
 S                 -4.26528720   -0.31288173    0.17127728
 O                 -4.44865992   -1.46397213    1.36721430
 O                 -5.40262483    0.89213008    0.37938700
 C                 -4.49040260   -1.07234769   -1.42275361
 H                 -3.93068164   -1.98324549   -1.46608530
 H                 -5.52835575   -1.28399988   -1.57360655
 H                 -4.14749251   -0.40633037   -2.18677822
 C                  2.06405231   -0.73478402    0.06924934
 C                  2.87532992   -0.54888989   -1.05045751
 C                  2.59827879   -0.58907541    1.34945214
 C                  4.22068143   -0.21802589   -0.88989573
 H                  2.45403875   -0.66459112   -2.05960009
 C                  3.94378433   -0.25714595    1.51022391
 H                  1.95896493   -0.73537813    2.23206322
 C                  4.75504164   -0.07174635    0.39083766
 H                  4.86035197   -0.07210220   -1.77240600
 H                  4.36462396   -0.14192386    2.51972483
 O                  6.13445112    0.26756891    0.55513809
 C                  6.79363224    0.21342938   -0.71271409
 H                  6.35492732    0.93139620   -1.37374483
 H                  7.83254893    0.43492893   -0.58430046
 H                  6.68665368   -0.76654701   -1.12876921

C H N S O 0
6-31G*
****





