%nprocshared=20
%mem=41GB
#p opt=modredundant b3lyp genecp scrf=(solvent=dichloromethane,pcm) nosymm empiricaldispersion=gd3 scf=(xqc,maxcyc=1024)

opt freq

1 1
 C                  1.17456241    1.48760306    0.04172058
 C                  2.43609988    1.12429778    0.33478963
 C                  4.90655590    1.20831111    0.64202078
 H                  5.10928199    1.25852624    1.71338473
 H                  5.79878150    1.52043046    0.10028911
 C                  3.63044298    2.06031974    0.28462993
 H                  3.77150231    2.38420869   -0.77433850
 C                  3.55416388    3.33692381    0.95127119
 C                  2.94983393   -0.25523645    0.68572074
 H                  2.40326752   -1.05249160    0.18099023
 H                  2.87704592   -0.42110068    1.76976497
 C                  4.44923699   -0.22774290    0.29376922
 O                  4.98890445   -2.49538838    0.62886924
 O                  5.92001117   -0.48992049   -1.53636663
 C                  5.65831761   -3.57986612    1.31153160
 H                  5.36518357   -3.59878752    2.36385393
 H                  5.33280577   -4.48617832    0.80297129
 H                  6.74146716   -3.45935785    1.23470427
 C                  6.22591906   -0.73401027   -2.92765808
 H                  5.84421322   -1.71233585   -3.22912043
 H                  5.77837615    0.04171232   -3.55352499
 H                  7.31255167   -0.70581295   -2.99465834
 H                  1.04648918    2.54271470   -0.23185410
 C                  5.24945159   -1.26349093    1.08493725
 C                  4.61916983   -0.48839948   -1.21045907
 O                  3.71424308   -0.64614365   -2.00190700
 O                  5.97868435   -1.01338066    2.02123015
 H                  2.63491130    3.58209152    1.48832156
 C                  4.59595406    4.34971710    0.92944438
 H                  4.16570880    5.30308774    0.57962857
 H                  4.85882013    4.56391888    1.98192343
 H                  5.48323159    4.08199372    0.35557302
 Au                -0.51537558    0.22454794    0.01169806
 P                 -2.43495879   -1.15488804   -0.05005075
 C                 -4.05573646   -0.26922147    0.05408418
 C                 -2.45792382   -2.13523435   -1.68482252
 C                 -2.34586488   -2.26935569    1.51414005
 C                 -5.23276257   -1.03056279    0.20375201
 C                 -4.16139191    1.14332938    0.08536578
 C                 -3.71126896   -2.99591221   -1.92674448
 C                 -1.19817477   -3.02239168   -1.73608650
 C                 -2.37637211   -1.07890504   -2.80871009
 C                 -0.86926874   -2.66533686    1.75599459
 C                 -2.80248575   -1.38399060    2.69441927
 C                 -3.18423857   -3.55995141    1.47395093
 C                 -6.47777338   -0.43895878    0.39747999
 H                 -5.18305572   -2.11014439    0.17682650
 C                 -5.42664840    1.72188552    0.29643353
 C                 -3.04668121    2.12150958   -0.11914413
 H                 -4.61342083   -2.38400839   -2.00826574
 H                 -3.58871003   -3.52628860   -2.87928412
 H                 -3.86821874   -3.74928506   -1.15186499
 H                 -1.10812217   -3.45433750   -2.74035519
 H                 -0.28725771   -2.44792605   -1.53316188
 H                 -1.25166250   -3.85284787   -1.02613612
 H                 -3.24246205   -0.40899560   -2.79583230
 H                 -1.46832507   -0.47268833   -2.73512554
 H                 -2.36529909   -1.59119854   -3.77862783
 H                 -0.43907362   -3.22276992    0.92039349
 H                 -0.23803803   -1.79042806    1.94117210
 H                 -0.82339930   -3.30802812    2.64421204
 H                 -2.60753283   -1.91734522    3.63283899
 H                 -2.24705424   -0.43894361    2.72580267
 H                 -3.87065920   -1.15444274    2.64986480
 H                 -3.07640246   -4.07318711    2.43769322
 H                 -4.25071612   -3.37651111    1.32995839
 H                 -2.83856280   -4.25061044    0.69970544
 C                 -6.57477386    0.95107841    0.45439164
 H                 -7.35988808   -1.06230205    0.50941136
 H                 -5.49690562    2.80543289    0.32288243
 C                 -2.57896673    2.39414718   -1.41080997
 C                 -2.59053198    2.89186956    0.96078528
 H                 -7.53544689    1.43247799    0.61292969
 C                 -1.65720542    3.42471168   -1.64431338
 H                 -2.96779816    1.80725278   -2.23289564
 C                 -1.67130157    3.93099620    0.76774153
 H                 -2.98414149    2.67328623    1.94695705
 C                 -1.22397004    4.17107552   -0.54048930
 H                 -1.34721092    3.69585186   -2.63187929
 H                 -1.34207691    4.57075979    1.55970975
 H                 -0.53609043    4.99205506   -0.70764863

1 F
2 F
3 F
4 F
5 F
6 F
7 F
8 F
9 F
10 F
11 F
12 F
13 F
14 F
15 F
16 F
17 F
18 F
19 F
20 F
21 F
22 F
23 F
24 F
25 F
26 F
27 F
28 F
29 F
30 F
31 F
32 F

C H P O 0
6-31G*
****
Au 0
SDD
****

Au 0
SDD


